Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 14-15, Pages 2992-3001Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300633
Keywords
bromoarenes; catalysis; click chemistry; green chemistry; 4-nitrophenol; palladium nanoparticles; polymers; Suzuki-Miyaura reaction
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Funding
- Univ. Bordeaux 1
- CNRS
- Ministere de l'Enseignement Superieur et de la Recherche
- Univ. Toulouse 3
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Palladium nanoparticles (size=1.60.3nm) stabilized by a polyethylene glycol containing triazolyl rings, synthesized by click reaction in water, are efficient catalysts for the Suzuki-Miyaura coupling of bromoarenes in aqueous ethanol and the borohydride reduction of 4-nitrophenol in water. Turnover numbers (TONs) reach 99,000 and turnover frequencies (TOFs) are up to 198,000h(-1) for the CC cross coupling reactions in water/ethanol.
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