Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 14-15, Pages 2918-2927Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300344
Keywords
aerobic oxidation; azide-alkene cycloaddition; copper catalysis; 1,2,3-triazoles
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Funding
- National Science Council of the Republic of China [NSC 99-2119M-003-003-MY2]
- National Taiwan Normal University [99T3030-2, 99-D, 100-D-06]
- Instrumentation Centre at National Taiwan Normal University
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A novel, copper(I)-promoted azide-alkene aerobic oxidative cycloaddition protocol was developed for the regioselective synthesis of 1,4-disubstituted/1,4,5-trisubstituted 1,2,3-triazoles by using azides and electron-deficient olefins under an oxygen atmosphere.
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