Mild Metal-Free Intramolecular Oxidative Alkylation of a Csp3H Bond Adjacent to a Nitrogen Atom: A Versatile Approach to Ring-Fused Tetrahydroquinolines

Enantioselective Metal/Organo-Catalyzed Aerobic Oxidative sp3C–H Olefination of Tertiary Amines Using Molecular Oxygen as the Sole Oxidant

(2012) Gen Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal-Free TEMPO-Catalyzed Oxidative Cross- Coupling of Nitrones with Alkynyl-Grignard Reagents

(2011) Sandip Murarka et al.   ADVANCED SYNTHESIS & CATALYSIS

Oxidative and Enantioselective Cross-Coupling of Aldehydes and Nitromethane Catalyzed by Diphenylprolinol Silyl Ether

(2011) Yujiro Hayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Activation of a C sp 3H Bond Adjacent to a Nitrogen Atom: A Versatile Approach to Optically Active α-Alkyl α-Amino Acids and C1-Alkylated Tetrahydroisoquinoline Derivatives

(2011) Gen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Highly Efficient Gold-Catalyzed Oxidative CC Coupling from CH Bonds Using Air as Oxidant

(2011) Jin Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mizoroki-Heck-Type Reaction Mediated by Potassium tert-Butoxide

(2011) Eiji Shirakawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights

(2011) Alison E. Wendlandt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C1-Substituted N-Alkyl Tetrahydroisoquinoline Derivatives through V-Catalyzed Oxidative Coupling

(2011) Kevin M. Jones et al.   ChemCatChem

Transition-metal catalyzed oxidative cross-coupling reactions to form C–C bonds involving organometallic reagents as nucleophiles

(2011) Wei Shi et al.   CHEMICAL SOCIETY REVIEWS

One-Pot Enantioselective Synthesis of Functionalized Pyranocoumarins and 2-Amino-4H-chromenes: Discovery of a Type of Potent Antibacterial Agent

(2011) Gen Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Studies on a Cu-Catalyzed Aerobic Oxidative Coupling Reaction withN-Phenyl Tetrahydroisoquinoline: Structure of Intermediates and the Role of Methanol As a Solvent

(2011) Esther Boess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemically Promoted Transition Metal-Free Cross-Coupling of Acylsilanes with Organoboronic Esters

(2011) Kazuta Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tropylium Ion Mediated α-Cyanation of Amines

(2011) Julia M. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Concise Synthesis of Tetrabenazine: An Intramolecular Aza-Prins-Type Cyclization via Oxidative C–H Activation∥

(2011) Young Wook Son et al.   ORGANIC LETTERS

Highly Enantioslective Synthesis of Multisubstituted Polyfunctional Dihydropyrrole via an Organocatalytic Tandem Michael/Cyclization Sequence

(2011) Gen Zhang et al.   ORGANIC LETTERS

New Ligands That Promote Cross-Coupling Reactions between Aryl Halides and Unactivated Arenes

(2011) Yatao Qiu et al.   ORGANIC LETTERS

Direct C2-Alkylation of Azoles with Alcohols and Ethers through Dehydrogenative Cross-Coupling under Metal-Free Conditions

(2011) Tao He et al.   ORGANIC LETTERS

Organocatalytic enantioselective β-functionalization of aldehydes by oxidation of enamines and their application in cascade reactions

(2011) Shi-Lei Zhang et al.   Nature Communications

Dimethyl Sulfoxide/Potassium Hydroxide: A Superbase for the Transition Metal-Free Preparation of Cross-Coupling Products

(2010) Yu Yuan et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Oxidative Cross-Coupling Reaction of 3-Indolylmethyl CH Bonds with 1,3-Dicarbonyls Using a Chiral Lewis Acid-Bonded Nucleophile to Control Stereochemistry

(2010) Chang Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Autoxidative Carbon-Carbon Bond Formation from Carbon-Hydrogen Bonds

(2010) Áron Pintér et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Synthesis of Tertiary Ethers through Geometric Control of Highly Substituted Oxocarbenium Ions

(2010) Lei Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aerobic and Electrochemical Oxidative Cross-Dehydrogenative-Coupling (CDC) Reaction in an Imidazolium-Based Ionic Liquid

(2010) Olivier Baslé et al.   CHEMISTRY-A EUROPEAN JOURNAL

Beyond Traditional Cross Couplings: The Scope of the Cross Dehydrogenative Coupling Reaction

(2010) Caroline J. Scheuermann   Chemistry-An Asian Journal

tert-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic 1,10-Phenanthroline Derivative

(2010) Eiji Shirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C−H Arylation of Unactivated Benzene

(2010) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An efficient organocatalytic method for constructing biaryls through aromatic C–H activation

(2010) Chang-Liang Sun et al.   Nature Chemistry

Expeditious Synthesis of Benzopyrans via Lewis Acid-Catalyzed C−H Functionalization: Remarkable Enhancement of Reactivity by anOrthoSubstituent

(2010) Keiji Mori et al.   ORGANIC LETTERS

N-Heterocyclic Carbene-Catalyzed Cross-Coupling of Aromatic Aldehydes with Activated Alkyl Halides

(2010) Mohan Padmanaban et al.   ORGANIC LETTERS

Oxidative Carbocation Formation in Macrocycles: Synthesis of the Neopeltolide Macrocycle

(2009) Wangyang Tu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed aerobic phosphonation of sp3 C–H bonds

(2009) Olivier Baslé et al.   CHEMICAL COMMUNICATIONS

Organocatalytic asymmetric Povarov reactions with 2- and 3-vinylindoles

(2009) Giulia Bergonzini et al.   CHEMICAL COMMUNICATIONS

Metal-Free Oxidative Cross-Coupling of Unfunctionalized Aromatic Compounds

(2009) Yasuyuki Kita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Brønsted Acid-Catalyzed Enantioselective Three-Component Povarov Reaction

(2009) Hua Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Isomerization and Intramolecular Redox Reaction of Alkynyl Ethers Affording Dihydropyrans and Ketoolefins

(2009) Daisuke Shikanai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Functionalization via Hydride Transfer: Synthesis of Dihydrobenzopyrans fromortho-Vinylaryl Akyl Ethers

(2009) Kevin M. McQuaid et al.   ORGANIC LETTERS

Mechanistic analysis of oxidative C–H cleavages using inter- and intramolecular kinetic isotope effects

(2009) Hyung Hoon Jung et al.   TETRAHEDRON

Facile synthesis of vicinal diamines via oxidation of N-phenyltetrahydroisoquinolines with DDQ

(2009) Althea S.-K. Tsang et al.   TETRAHEDRON LETTERS

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Hydrogenation of Quinolines Catalyzed by Iridium Complexes of Monodentate BINOL-Derived Phosphoramidites

(2008) Nataša Mršić et al.   ADVANCED SYNTHESIS & CATALYSIS

Functionalizing Glycine Derivatives by Direct CC Bond Formation

(2008) Liang Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Development of Double Axially Chiral Phosphoric Acids and Their Catalytic Transfer Hydrogenation of Quinolines

(2008) Qun-Sheng Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium catalyzed biomimetic oxidation in organic synthesis inspired by cytochrome P-450

(2008) Shun-Ichi Murahashi et al.   CHEMICAL SOCIETY REVIEWS

Coupling of Nitrogen Heteroaromatics and Alkanes without Transition Metals: A New Oxidative Cross-Coupling at CH/CH Bonds

(2008) Guojun Deng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Tunable Bisphosphine Ligands and Their Application in Asymmetric Hydrogenation of Quinolines

(2008) Xiao-Bing Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Facile Formation of Cyclic Aminals through a Brønsted Acid-Promoted Redox Process

(2008) Chen Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Molecular Oxygen or Hydrogen Peroxide and Sodium Cyanide: sp3C−H Bond Activation and Carbon−Carbon Bond Formation

(2008) Shun-Ichi Murahashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Functionalization via Hydride Transfer: Lewis Acid Catalyzed Alkylation Reactions by Direct Intramolecular Coupling of sp3C−H Bonds and Reactive Alkenyl Oxocarbenium Intermediates

(2008) Kevin M. McQuaid et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Potassiumt-Butoxide Alone Can Promote the Biaryl Coupling of Electron-Deficient Nitrogen Heterocycles and Haloarenes

(2008) Shuichi Yanagisawa et al.   ORGANIC LETTERS

Copper-Catalyzed Oxidative sp3C−H Bond Arylation with Aryl Boronic Acids

(2008) Olivier Baslé et al.   ORGANIC LETTERS

Lewis Acid Catalyzed Formation of Tetrahydroquinolines via an Intramolecular Redox Process

(2008) Sandip Murarka et al.   ORGANIC LETTERS

Synthesis of substituted 1,2,3,4-tetrahydroquinones by the Povarov reaction. New potentials of the classical reaction

(2008) V A Glushkov et al.   RUSSIAN CHEMICAL REVIEWS

Rapid synthesis of the tetrahydroquinoline alkaloids: angustureine, cuspareine and galipinine

(2008) Aisling O'Byrne et al.   TETRAHEDRON

Recent synthetic developments in a powerful imino Diels–Alder reaction (Povarov reaction): application to the synthesis of N-polyheterocycles and related alkaloids

(2008) Vladimir V. Kouznetsov   TETRAHEDRON

α-Amination of Nitrogen Heterocycles:  Ring-Fused Aminals

(2007) Chen Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY