Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 3, Pages 363-366Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800634
Keywords
aldehydes; beta-aryloxy primary alcohols; asymmetric catalysis; dynamic kinetic resolution; ruthenium
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Funding
- National Natural Science Foundation of China [20532010, 20572049, 20721062]
- Major Basic Research Development program [2006CB806106]
- Ministry of Education of China [B06005]
- Merck Research Laboratories
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A catalytic enantioselective hydrogenation of racemic alpha-aryloxy aldehydes via dynamic kinetic resolution has been developed by using (diamine)(spirodiphosphine)ruthenium(II) chloride [RuCl2(SDPs)(diamine)] catalysts. Employing this new reaction system a variety of optically active beta-aryloxy primary alcohols were synthesized in high yields and moderate to good enantioselectivities.
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