Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 3, Pages 353-356Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800689
Keywords
amination; cycloalkanes; nitroarenes; peroxides
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Funding
- Canada Research Chair (Tier 1) Foundation
- (US) NSF-EPA Joint Program for a Sustainable Environment
- NSERC GCI-Pharmaceutical Green Chemistry Roundtable
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A direct amination of simple cycloalkanes with nitroarenes mediated by peroxides has been discovered. Various secondary arylamines were obtained efficiently from cycloalkanes. The reaction tolerates a wide range of functionalities as well as aqueous conditions. No metal was required for this novel amination reaction.
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