Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 14-15, Pages 2469-2481Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900402
Keywords
alkynes; arenes; cobalt; furans; gold; stereoselectivity
Categories
Funding
- Umicore AG Co. KG
- Deutsche Forschungsgemeinschaft [HA 1932/10-1]
Ask authors/readers for more resources
Furans with diastereotopic alkynyl groups were prepared and then converted to anellated phenols in gold-catalyzed reactions. In all cases a highly diastereoselective reaction was observed. The stereochemical outcome of the 1,3-induction could be assigned by two independent crystal structure analyses, showing a cis-arrangement of the two alkyl substituents on the benzoanellated cyclohexene ring.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
