Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 3, Pages 448-452Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200700432
Keywords
dynamic kinetic resolution; enzyme catalysis; nitroaldol (Henry) reaction; secondary alcohols
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The asymmetric synthesis of beta-nitroalkanol derivatives was simply achieved by a combined nitroaldol (Henry) reaction with lipase-catalyzed transesterification in high yield and enantiomeric purity (up to 92% and 99% ee) through a direct one-pot procedure.
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