Article
Chemistry, Physical
Sushmita Dwivedi, Manish Badole, Tanvi Pareek, Sunil Kumar
Summary: This study aims to experimentally verify proposed models for the behavior of polymer-ceramic composites and design a new composite material with excellent piezoelectric performance. By adding ceramic fillers, the thermodynamic stability of the composite was improved, leading to enhanced dielectric and piezoelectric properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Polymer Science
Mengmeng Li, Ruihu Wang, Haijie Wang, Xinhua Cao, Yu Cheng, Erqi Guan, Ke Bian
Summary: The industrial application of plywood made from soybean meal-based adhesive (SMA) was enhanced by improving the wet shear strength and water resistance through microwave-chemical treatment. The wet shear strength of SMA was improved to 0.93 MPa by optimizing microwave conditions and using PEG-PEI treatment, which was 32.86% higher than the China National Standard. The modified mechanism was characterized using various techniques, showing that the formation of crosslinking improved the bonding performance and water resistance of SMA, providing favorable conditions for further application.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Walther-Dario Bejarano-Pena, Brenda Alcantar-Vazquez, Rosa-Maria Ramirez-Zamora
Summary: Lithium silicate-based CO2 sorbents were synthesized using steel metallurgical slags, with K2CO3 addition improving CO2 capture efficiency by facilitating CO2 diffusion. The best capture capacity value of 104 mg(CO2)/g(material) was achieved with 20 wt% K2CO3 at 600 degrees C. Thermal stability was excellent, with only a 10% reduction in CO2 capture capacity after 20 adsorption-desorption cycles using 20 vol% CO2.
MATERIALS RESEARCH BULLETIN
(2021)
Article
Chemistry, Physical
K. P. Safna Hussan, Mohamed Shahin Thayyil, C. M. Pareeth, K. Manoj, Thekkekara Babu
Summary: In this study, a dual-active pharmaceutical ingredient, metforminium ibuprofenate (MtHIb), was prepared by chemical structural modification. The properties of MtHIb in the glassy state were investigated using experimental and computational methods. The results demonstrate that chemical structural modification can effectively control the secondary relaxations of amorphous pharmaceuticals, which is of great significance for understanding these materials.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
J. A. Ocadiz-Flores, A. E. Gheribi, J. Vlieland, K. Dardenne, J. Rothe, R. J. M. Konings, A. L. Smith
Summary: This study investigates the phase diagram equilibria in the LiF-UF4 system, proposing a CALPHAD-type assessment that links structural and thermodynamic properties with a rigorous physical description of the melt.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Engineering, Civil
Kunal Bisht, P. V. Ramana
Summary: This study investigates the use of waste glass in concrete mixes to achieve optimal performance. The results show that waste glass with lower water absorption can reduce drying shrinkage and increase the apparent density of the concrete. Additionally, when waste glass is incorporated up to 21%, the compressive strength of the concrete increases up to 400°C due to reduced pore pressure caused by low water absorption.
Article
Polymer Science
Amina Benarab, Enrique Blazquez-Blazquez, Rachida Krache, Rosario Benavente, Maria L. Cerrada, Ernesto Perez
Summary: The composites prepared with silanized DSF demonstrated excellent performance, including enhanced PPR crystallization, reduced hydrophilicity of the date stone flour, improved interfacial adhesion with the polymer, and enhanced mechanical properties.
Article
Polymer Science
Kazuki Matsuura, Keiichi Kuboyama, Toshiaki Ougizawa
Summary: Poly(n-butyl acrylate) (PnBA) and silica nanoparticle composites were studied using various analytical techniques, revealing the presence of amorphous bulk and interfacial regions in the composites. The mobility of side chains at the interfaces differed from that in the bulk polymer, attributed to interactions between the carbonyl groups in PnBA and the silica surfaces. This indicated a closer proximity of PnBA main chains near interfaces with silicon oxide compared to those in the bulk polymer.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Polymer Science
Alasseri Nihmath, Manammel Thankappan Ramesan
Summary: The polymer blend composites reinforced with hydroxyapatite nanoparticles showed enhanced mechanical properties, oil resistance, hardness, and AC conductivity. The addition of nanoparticles also decreased the diffusion rate of the blend composites with an anomalous trend in the diffusion mechanism. Among the blend composites, the sample with 7 phr of HA exhibited good oil and solvent resistance, increased AC conductivity, and improved mechanical properties.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Thermodynamics
W. Gierlotka, A. Debski, M. Zabrocki, A. Goral, W. Gasior
Summary: The limiting enthalpy of solution of liquid germanium in liquid tin and the thermodynamic properties of intermetallic phases in the Ge-Li system were studied. Based on experimental measurements and calculations, the Ge-Li phase diagram was determined.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2022)
Article
Engineering, Environmental
Vikram Kumar, Nishant Garg
Summary: MSWI ashes are byproducts of municipal solid waste incineration, which can either accelerate or retard cement hydration. A new parameter - Incineration Ash Coefficient (IAC) - correlates reasonably well with the 7-day compressive strength of mortars incorporating MSWI ashes, based on the ashes' elemental composition.
RESOURCES CONSERVATION AND RECYCLING
(2022)
Article
Materials Science, Composites
Linconl A. Teixeira, L. Vilson Dalla Junior, Sandra M. Luz
Summary: The study investigated the influence of different surface treatments on the properties of curaua fiber composites, with silane treatment showing the most effective improvement in performance.
PLASTICS RUBBER AND COMPOSITES
(2021)
Article
Thermodynamics
Kwang-Sei Lee, In-Hwan Oh, Jae-Hyeon Ko
Summary: The powder X-ray diffraction (PXRD) and differential scanning calorimetry (DSC) were used to characterize the structure and detect phase transformations of polycrystalline (+)-decursinol. The crystal system of decursinol was determined to be orthorhombic with a space group P212121 using PXRD. DSC analysis showed two polymorphic phase transitions at approximately 64°C and 68°C, and a melting peak at an extrapolated onset temperature of approximately 177°C.
THERMOCHIMICA ACTA
(2022)
Article
Biochemistry & Molecular Biology
Maria Francesca Colella, Nadia Marino, Cesare Oliviero Rossi, Lucia Seta, Paolino Caputo, Giuseppina De Luca
Summary: The food industry has been researching vegetable fats and oils with specific mechanical properties and lipidic composition to ensure healthy products for consumers. This study demonstrates that the regiosomerism of fatty acids within TriAcylGlycerols (TAG) moieties significantly affects their properties and human digestion. By manipulating the distribution of fatty acids in natural cocoa butter, the obtained vegetable fats show improved chemical-physical features. Experimental investigations including DSC, rheological testing, PXRD, and NMR spectroscopy were conducted to understand the factors responsible for these characteristics.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Biophysics
David Chapron, Jean-Philippe Michel, Philippe Fontaine, Jeremy Godard, Frederique Bregier, Vincent Sol, Veronique Rosilio
Summary: This study investigates the suitability of photosensitizer PN grafted with lipid chains to form nano assemblies or mixed lipid vesicles for photodynamic therapy. The results show that PN-C-18 conjugates can control the thermodynamic and structural properties of mixtures, leading to the disintegration of vesicles due to pi-pi interactions between PN molecules.
COLLOIDS AND SURFACES B-BIOINTERFACES
(2023)
Article
Engineering, Chemical
Yongxiang Wu, Nguyen Thi Hong Nhung, Deqian Zeng, Nengneng Luo, Akira Otsuki, Gjergj Dodbiba, Toyohisa Fujita
Summary: This study proposed a novel method for synthesizing flower-like vaterite calcium carbonate using nanobubble-containing ethanol and water mixed solution as the solvent and discussed the formation mechanism of vaterite with different shapes. The synthesized vaterite has significant practical interest in the integrated treatment of wastewater contaminated by heavy metals with effective Cd(II) removal, providing a promising field for studying heavy metal and pollutant adsorption in the liquid phase.
ADVANCED POWDER TECHNOLOGY
(2024)
Article
Engineering, Chemical
Jian Gong, Lipo Cheng, Ming Liu, Jie Jiang, Xiaoduo Ou
Summary: This study investigates the effects of particle shape on the collapse of granular columns using the discrete element method. The results show that particle shape has a significant impact on deposition morphology, energy evolution, and mechanical coordination number. Sphericity and angularity are identified as the most important macroscale factors, while roughness has a weaker microscale influence.
ADVANCED POWDER TECHNOLOGY
(2024)