4.8 Article

Topological Engineering of Glass for Modulating Chemical State of Dopants

Journal

ADVANCED MATERIALS
Volume 26, Issue 47, Pages 7966-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201403256

Keywords

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Funding

  1. National Natural Science Foundation of China [51102209, 51132004]
  2. Chinese Program for New Century Excellent Talents in University [NCET-13-0221]
  3. Guangdong Natural Science Funds for Distinguished Young Scholar [S2013050014549]
  4. Fundamental Research Funds for the Central University
  5. Scientific Research Foundation for Returned Overseas Chinese Scholars, State Education Ministry
  6. Grants-in-Aid for Scientific Research [25410236] Funding Source: KAKEN

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A novel approach to modulating the chemical state of dopants by engineering the topological features of a glass matrix is presented. The method allows selective stabilization of dopants on a wide range of length scales, from dispersed ions to aggregated clusters to nanoparticles, leading to various intriguing optical phenomena, such as great emission enhancement and ultra-broadband optical amplification.

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