4.2 Article Proceedings Paper

Preparation Assisted via Thermal Stress and Electrochemical Performance of Graphene Nano-Sheets as Anode Materials for Lithium-Ion Batteries

Journal

INTEGRATED FERROELECTRICS
Volume 160, Issue 1, Pages 27-37

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/10584587.2015.1033319

Keywords

Graphene nano-sheets; lithium-ion batteries; electrochemical performance; thermal stress assist

Funding

  1. National Natural Science Foundation of China [60976069]
  2. Natural Science Foundation of ShaanXi Province, China [2010JM6008]
  3. Special Fund of the Natural Science of ShaanXi Province Education Department, China [2013JK1093]
  4. Xi'an Scientific and Technological Project, China [CXY1008]

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Via a simple thermal stress assist process, the high-quality graphene was successfully obtained. The microstructure, morphology and the electrochemical performance of the as-prepared products were characterized by x-ray diffraction (XRD), field emission environment scanning electron microscope (SEM), Micro-Raman Spectroscopy System, element analysis system and LAND battery program-control test system respectively. The results show that the as-prepared products are uniform graphene nano-sheets (GNs) with large and smooth surface, and that the GNs, as an anode material for lithium-ion cell, exhibit good cyclic performance, which imply that the lithium ions and GNs have formed a relative stable structure to large degree. A possible form mechanism of the high-quality GNs is proposed.

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