Journal
INORGANICA CHIMICA ACTA
Volume 436, Issue -, Pages 1-6Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2015.07.025
Keywords
Guest molecules; Metal-organic framework; Nanomaterials; Zinc(II) oxide
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Funding
- University of Tehran [01/1/389845]
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A new nanoporous metal-organic framework Zn-2(NDC)(2)(DMF)(2)(H2O)(4) (1 center dot DMF center dot H2O) [H2NDC = 2,6-naphthalene dicarboxylic acid and DMF = N,N'-dimethylformamide], with guest water molecules has been synthesized and characterized. This MOF is made up of a stacked arrangement of four-connected layers. Stacked arrangement of layers results in formation of nanoporous channels. The thermal stabilities of 1 center dot DMF center dot H2O and 1 center dot DMF were studied by TGA (thermo gravimetric analyses). The host and the apohost frameworks of 1 center dot DMF center dot H2O, 1 center dot DMF and 1 were used for preparation of ZnO nanomaterials. With calcination of the host framework of 1 center dot DMF center dot H2O, ZnO nanoparticles can be fabricated. By the same process on the apohost frameworks of 1 center dot DMF and 1, agglomerated nanoparticles of ZnO were formed. (C) 2015 Elsevier B.V. All rights reserved.
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