Journal
INORGANIC CHEMISTRY
Volume 54, Issue 18, Pages 8884-8886Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b01651
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Funding
- National Natural Science Foundation of China [21463020, 21365016, 21173168]
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A novel two-dimensional (2D) coordination polymer, [Co(ppad)(2)](n) (1), resulted from the assembly of Co-II ions based on a versatile ligand termed N-3-(3-p-yridoyl)-3-pyridinecarboxamidrazone. Alternating/direct-current magnetic studies of compound 1 indicate that the spatially separated high-spin Co-II ions act as single-ion magnets (SIMs). The present work represents the first case of a 2D Co-II-based SIM composed of a monocomponent organic spacer.
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