☆ 4.7 Article

Design Criteria for High-Temperature Single-Molecule Magnets

INORGANIC CHEMISTRY (2015)

Journal

INORGANIC CHEMISTRY

Volume 54, Issue 5, Pages 2097-2099

Publisher

AMER CHEMICAL SOC

DOI: 10.1021/acs.inorgchem.5b00089

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Categories

Chemistry, Inorganic & Nuclear

Funding

University of Manchester

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Abstract

Design criteria to obtain slow magnetic relaxation are theoretically investigated for two-coordinate complexes of Dy-III. It is shown that large energy barriers to magnetic relaxation, U-eff, can ,be achieved in the absence of near-linearity and generally that any two-coordinate complex of Dy-III is an attractive synthetic target that may possess U-eff > 1000 cm(-1). These large U-eff values are immediately diminished if axial ligation is disrupted by solvent coordination.

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