Journal
INORGANIC CHEMISTRY
Volume 54, Issue 22, Pages 10642-10647Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b01437
Keywords
-
Categories
Funding
- National Natural Science Foundation of China [21471032, 21422101, 21301029]
- Jiangsu Province NSF [BK20140056, BK20130600]
- Program for NCET
- Ph.D. Programs Foundation of Ministry of Education of China [20130092120013]
- Fundamental Research Funds for the Central Universities
- [2014CB848800]
Ask authors/readers for more resources
A new organic-inorganic hybrid switchable and tunable dielectric compound, [(CH3)(4)P](4)[Mn(SCN)(6)] (1), exhibits three distinct dielectric states above room temperature and undergoes two reversible solid-state phase transitions, including a structural phase transition at 330 K and a ferroelastic phase transition with the Aizu notation of mmmF2/m at 352 K The variable-temperature structural analyses disclose that the origin of the phase transitions and dielectric anomalies can be ascribed to the reorientation or motion of both the [(CH3)(4)P](+) cations and [Mn(SCN)(6)](4-) anions in solid-state crystals.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available