Journal
INORGANIC CHEMISTRY
Volume 54, Issue 21, Pages 10108-10110Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b01859
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Funding
- Xinjiang Program of Cultivation ofYoung Innovative Technical Talents [2014731029]
- Western Light Foundation of CAS [XBBS201318]
- National Natural Science Foundation of China [51402352, 51425206]
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Two new noncentrosymmetric compounds, Na4MgM2Se6 (I, M = Si; II, M = Ge), that contain special ethane-like [M2Se6](6) units were reported for the first time. Remarkably, they exhibit high laser-damage thresholds [9 (I) and 7 (II) x benchmark AgGaS2] and moderate second-harmonic-generation responses with type I phase matching.
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