Journal
INORGANIC CHEMISTRY
Volume 54, Issue 23, Pages 11061-11063Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b02129
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Funding
- MEXT [25105537, 24108730, 21245016, 25288031, NPS13103]
- Grants-in-Aid for Scientific Research [25288031, 15H00757, 26620048, 24108730, 21245016, 26600026] Funding Source: KAKEN
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Oxidative electropolymeization of an axially bound, bithiophene pyridine complex of ruthenium(III) porphycene [Ru(TPrPc) (btp)(2)]PF6 (1) gives a submicrometer-thick, polymeric film on an ITO electrode with a crystalline morphology. The polymeric film, the first example of axially linked multimetalloporphycene coordination arrays, exhibits highly stable and reproducible electrochromic response with high electrochromic efficiency upon electrochemical control over the metal-centered electron transfer process (Ru-II/Ru-III).
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