Journal
INORGANIC CHEMISTRY
Volume 54, Issue 13, Pages 6081-6083Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b00917
Keywords
-
Categories
Funding
- NSFC [21390392, 21371169, 21131006]
- Youth Innovation Promotion Association CAS
Ask authors/readers for more resources
Two 3D lanthanide frameworks, [Ln(7)(DPA)(5)(NA)(3)(mu(3)-OH)(8)(H2O)(3)]center dot 2.5H(2)O [H(2)DPA = diphenic acid; HNA = nicotinic acid; Ln = Gd (1), Dy (2)], were synthesized and structurally characterized. They were rarely seen examples of 3D frameworks constructed from heptanudear trigonal-antiprismatic lanthanide dusters with mixed H(2)DPA and HNA ligands. Both 1 and 2 show typical antiferromagnetic interactions. Additionally, complex 1 possesses a large magnetocaloric effect of 34.15 J kg(-1) K-1.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
