Journal
ACTA MATERIALIA
Volume 61, Issue 1, Pages 310-320Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2012.09.061
Keywords
Mechanical alloying (MA); High-energy milling (HEM); Phase formation; Modeling
Ask authors/readers for more resources
The phase formation of carbides and borides during high-energy ball milling has been investigated by measuring the gas temperature inside the vial and by X-ray diffraction studies of specimens taken at different stages of the milling process. The formation mechanism changes from a gradual process to an instantaneous, explosion-like reaction with increasing milling intensity and enthalpy of product formation. Finally, a model was developed to describe the milling process, and to determine the peak temperatures that are reached in the powder particles during ball collisions as well as the microstructure evolution. Using an effective coefficient of diffusion and calculating the evolution of the continuously growing diffusion layer, it was possible to determine whether and when rapid phase formation occurs. The model was tested by reproducing the milling times needed for rapid phase formation inside the mill. (C) 2012 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available