4.7 Article

Stress-induced structural changes in La-doped BiFeO3-PbTiO3 high-temperature piezoceramics

Journal

ACTA MATERIALIA
Volume 58, Issue 18, Pages 5962-5971

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2010.07.012

Keywords

Piezoelectricity; Ferroelectncity; Neutron diffraction

Funding

  1. Deutsche Forschungsgemeinschaft [RO 954/20]
  2. US National Science Foundation [DMR-0746902]
  3. US Department of the Army [W911NF-09-1-0435]
  4. US Department of Energy [DE-AC05-00OR22725]
  5. Division of Scientific User Facilities, DOE Office of Basic Energy Science
  6. Direct For Mathematical & Physical Scien
  7. Division Of Materials Research [0746902] Funding Source: National Science Foundation

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High-temperature piezoelectric polycrystalline ceramics of the system (1 - x)(Bi1-yLay)FeO3-xPbTiO(3) (BF-PT), which are mixed phase in their consolidated state, have been investigated by in situ neutron diffraction during the application of uniaxial compressive stress. It is suggested that the achievable strain in BF-PT is largely generated by straining of the rhombohedral phase. The results of the neutron diffraction measurements are compared and discussed with respect to the measured macroscopic ferroelastic constitutive behavior for various compositions of BF-PT. (C) 2010 Acta Materialia Inc. Published by Elsevier Ltd All rights reserved.

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