Sequential growths of AlN and GaN layers on as-polished 6H-SiC(0001) substrates

Microstructures of surfaces and defects generated during initial and subsequent growths via metalorganic vapor-phase epitaxy of AlN(0001) films on 6H-SiC(0001) substrates and GaN(0001) films on AlN/SiC(0001) substrates have been investigated using atomic force microscopy and cross-sectional and plan-view transmission electron microscopy. Scratches present on the SiC surfaces did not appear to bias the nucleation of AlN. The lateral growth rate of AlN was greater than the vertical growth rate, leading to almost planar layers at 15 and 100 nm thicknesses. Partially coalesced islands were observed after nominally similar to 15 nm of growth. Increasing the thickness to 100 nm resulted in complete island coalescence, formation of undulating films from the polishing scratches in the SiC substrate, a surface microstructure containing steps, terraces and small pits, and a reduced dislocation density relative to the 15 nm layers. The AlN/SiC interfaces contained steps and complex dislocation networks. GaN islands nucleated and grew on the AIN films. Complete coalescence of these islands occurred at thicknesses less than 100 nm. Dislocation density in the GaN films was reduced by increasing the thickness of either the AlN and or the GaN. Arguments are developed to account for these observations. (C) 2009 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.