Journal
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Volume 66, Issue -, Pages M325-U3789Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600536810006252
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- National Science Foundation
- American Chemical Society [PRF 44692.01-GB]
- Research Corporation [CC6755]
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The title compound, [Ru(NCCH3)(6)](CH6B11Br6)(2)center dot CH3CN, consists of the ' naked' ruthenium(II) cation surrounded by six acetonitrile molecules, each coordinated via the nitrogen atoms in a linear or nearly-linear fashion in a typical octahedral over-all arrangement. The cation is balanced by the two hexa-bromocarborane cage anionic fragments [CB11H6Br6]. Weak C-H center dot center dot center dot Br and B-H center dot center dot center dot Br interactions link neighboring anions.
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