4.0 Article

trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ2N3,O4]iron(II)

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INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600536809027457

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Funding

  1. National Natural Science Foundation of China [20771094, 20671083]
  2. Science and Technology Key Task of Henan Province [0524270061]
  3. China Postdoctoral Science Foundation [20070410877]

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In the title complex, [Fe(C10H6N3O4)(2)(H2O)(2)], the Fe-II atom is located on an inversion centre and is trans-coordinated by two N,O-bidentate 5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylate ligands and two water molecules, defining a distorted octahedral environment. A two-dimensional network of N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds extending parallel to (110) helps to stabilize the crystal packing.

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