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Hexa-μ2-acetato-triaqua-μ3-oxido-triiron(III) nitrate acetic acid solvate

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE (2008)

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ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Volume 64, Issue -, Pages M989-U190

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INT UNION CRYSTALLOGRAPHY

DOI: 10.1107/S1600536808019806

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Abstract

The asymmetric unit of the title compound, [Fe-3(CH3COO)(6)-O( H2O)(3)]NO3 center dot CH3COOH, consists of a hexa-mu(2)-acetato-triaqua-mu(3)-oxo-triiron(III) macrocation, a nitrate ion and an acetic acid solvent molecule. In the cation, each Fe3+ ion is coordinated by four carboxylate O atoms, one central bridged O atom and one water molecule, resulting in distorted FeO6 octahedra. A network of O-H center dot center dot center dot O hydrogen bonds helps to establish the packing.

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The crystal structure of the cocrystal di-μ2-chlorido-octamethyl-di-μ3-oxido-bis(2,3,4,5-tetrafluorobenzoato-κ2O,O′)tetratin(IV)-octamethyl-di-μ3-oxido-bis(μ2-2,3,4,5-tetrafluorobenzoato-κ2O:O′)-bis(μ2-2,3,4,5-tetrafluorobenzoato-κ2O:O;O′)tetratin(IV) C58H54Cl2F24O16Sn8

Junshan Sun

Summary: The substance has a triclinic crystal structure with lattice parameters a=7.609 Å, b=13.938 Å, c=19.190 Å, and space group P(1) over bar (no. 2) at a temperature of 298 K.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES (2021)

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Article Crystallography

Hexa-μ-acetato-chlorido(μ-N,2-dioxodobenzene-1-carboximidato)-μ3-oxido-tetrairon(III)-water (1/1) and hexa-μ-acetato-(μ-N,2-dioxodobenzene-1-carboximidato) fluorido-μ3-oxido-tripyridinetetra-iron(III)-pyridine-water (1/1/0.24)

Cassandra L. Ward, Matthew J. Allen, Jacob C. Lutter

Summary: Two iron complexes with similar structures differ in space groups and crystal packing due to different interactions involving the halides. Each iron ion is coordinated differently with various numbers of oxygen and nitrogen atom donors, confirming trivalent iron ions. The hydroximate ligand binds to three iron ions using a fused chelate motif.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS (2021)

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Article Crystallography

Crystal structure of poly[dimethanol-κ1O-(μ2-(E)-2-((2-oxidobenzylidene)amino)acetato)-(μ3-(E)-2-((2-oxidobenzylidene)amino)acetato)dicadmium(II)], C20H22Cd2N2O8

Xiao-Yu Guo, Yun-Chao Liu, Peng-Hui Yin

Summary: The crystal structure of the compound belongs to the monoclinic system. The lattice parameters are a = 13.131(3) angstrom, b = 8.2018(16) angstrom, c = 20.973(4) angstrom, and β = 103.59(3) degrees. The volume is 2195.5(8) angstrom(3) and the unit cell contains 4 molecules. The R ( gt )(F) value is 0.0260 and the wR ( ref )(F (2)) value is 0.0609. The temperature is 293(2) K.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES (2022)

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Article Crystallography

Crystal structure of bis(2,5,5,7-tetramethyl-1,4-diazepane-1,4-diium) diaqua-bis(1,2-diaminopropane)copper(II) bis(μ6-oxido)tetrakis(μ3-oxido)-tetradecakis(μ2-oxido)-octaoxido-decavanadium(V) - water (1/4), C24H76CuN8V10O34

Yuan-Huan Deng, Qiong Wang

Summary: In this study, a new monoclinic crystal structure with the molecular formula C24H76CuN8V10O34 was reported. The unit cell parameters were determined to be a = 22.416(4) angstrom, b = 11.7003(18) angstrom, c = 20.079(3) angstrom, and β = 95.594(7)°, with a volume of 5241.2(14) angstrom^3.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES (2023)

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Article Crystallography

Crystal structure of bis(μ3-oxido)-bis(μ2-2-formylbenzoato-k2 O:O′)-bis(2-(dimethoxymethyl)-benzoato-κO)-oktakismethyl-tetratin(IV)

Zhongjun Gao, Haifeng Zhang

Summary: The substance is C44H56O16Sn4, belonging to the triclinic crystal system, with cell parameters of a = 9.129 Å, b = 11.826 Å, and c = 13.612 Å. The structure is stable with R-gt(F) = 0.0298 at 298 K.

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Article Crystallography

The crystal structure of poly[μ2-aqua- aqua-(μ3-(E)-2-(4-((2-carbamothioylhydrazineylidene)methyl)phenoxy)acetato-κ3O:S:S)sodium(I)], C10H14N3O5SNa

Xi-Shi Tai, Li-Hua Wang, Yu-Pei Xia

Summary: The compound C10H14N3O5SNa crystallizes in the triclinic system with the space group P (1) over bar (no. 2). The crystal unit cell parameters are a = 6.7015(5) angstrom, b = 7.5656(5) angstrom, c = 14.1332(8) angstrom, and β = 93.159(5) degrees. The volume of the unit cell is 654.71(8) angstrom-cubed, and there are 2 molecules in the unit cell. The R factor is 0.0357 and the weighted R factor is 0.0872 for F2. The temperature of the measurement is 273 K.

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Article Crystallography

The crystal structure of the cocrystal di-μ2-chlorido-tetramethyl-tetraphenyl-di-μ3-oxido-dichloridotetratin(IV) - diphenyl-methyl-chloridotin(IV)(1/2), C54H58Cl6O2Sn6

Beibei Xiao, Niping Xiang, Jiangxi Yu, Chengyong Wang, Bang Liu

Summary: This is a monoclinic crystal with the chemical formula of C54H58Cl6O2Sn6. Its space group is P2(1)/c (no. 14), and the cell parameters are a = 9.5793(13) Å, b = 26.161(4) Å, c = 13.1326(18) Å, β = 109.124(2)°. The volume is 3109.5(7) Å^3, and there are 2 molecules in the unit cell. The R-gt (F) value is 0.0337, wR(ref) (F-2) is 0.0763, and the temperature is 296(2) K.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES (2023)

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Article Crystallography

Mixed-valent Manganese Complex with a Schiff-base Having a Di-μ4-oxido-di-μ3-oxido-di-μ3-carboxylato-hexa-μ-carboxylato-bridged Mn2IIMn6III Core

Masahiro Mikuriya, Yoshiki Koyama, Chinatsu Kamioka, Ryoji Mitsuhashi, Motohiro Tsuboi

Summary: A crystal structure of a manganese complex with eight nuclei has been determined using X-ray diffraction method. The complex exhibits a unique chemical structure.

X-RAY STRUCTURE ANALYSIS ONLINE (2022)

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Article Crystallography

Synthesis and crystal structure of bis[μ-N,N-bis(2-aminoethyl)ethane-1,2-diamine]bis[N,N-bis(2-ammoethyl)ethane-1,2-thamine]-μ4-oxido-hexa-μ3-oxido-octa-μ2-oxido-tetraoxidotetranickel(II)hexatantalum(V) nonadecahydrate

Dana-Celine Krause, Christian Naether, Wolfgang Bensch

Summary: The reaction of K-8{Ta6O19}·16H2O with [Ni(tren)(H2O)Cl]Cl·H2O in different solvents resulted in the formation of single crystals of the title compound, which contains Lindqvist-type anion {Ta6O19}(8-) connected to two Ni-II cations through hydrogen bonding involving water molecules. The crystal structure showed slightly distorted octahedral coordination for the Ni-II cations, forming layers parallel to the b plane. On storage at room temperature, the compound decomposed due to the loss of crystal water molecules.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS (2021)

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Article Crystallography

Synthesis and structural characterization of hexa-μ2-chlorido-μ4-oxido-tetrakis{[4-(phenylethynyl)-pyridine-κN]copper(II)} dichloromethane monosolvate

Rayya A. Al Balushi, Muhammad S. Khan, Md Serajul Haque Faizi, Ashanul Haque, Kieran Molloy, Paul R. Raithby

Summary: The crystal structure of the compound [Cu4Cl6O(C13H9N)4]·CH2Cl2 features a Cu-4 tetrahedron core with copper(II) cations coordinated to central O atom, chlorido ligands, and the 4-phenylethynylpyridine ligand. Intermolecular interactions such as C-H···Cl, C-H···π, and π-π contribute to linking the molecules and forming a three-dimensional network. Hirshfeld surface analysis indicates that packing arrangement is mainly influenced by H···H and C···H/H···C interactions.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS (2021)

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Hexa-μ2-acetato-triaqua-μ3-oxido-triiron(III) nitrate acetic acid solvate

Journal

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Publisher

INT UNION CRYSTALLOGRAPHY

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The crystal structure of the cocrystal di-μ2-chlorido-octamethyl-di-μ3-oxido-bis(2,3,4,5-tetrafluorobenzoato-κ2O,O′)tetratin(IV)-octamethyl-di-μ3-oxido-bis(μ2-2,3,4,5-tetrafluorobenzoato-κ2O:O′)-bis(μ2-2,3,4,5-tetrafluorobenzoato-κ2O:O;O′)tetratin(IV) C58H54Cl2F24O16Sn8

Hexa-μ-acetato-chlorido(μ-N,2-dioxodobenzene-1-carboximidato)-μ3-oxido-tetrairon(III)-water (1/1) and hexa-μ-acetato-(μ-N,2-dioxodobenzene-1-carboximidato) fluorido-μ3-oxido-tripyridinetetra-iron(III)-pyridine-water (1/1/0.24)

Crystal structure of poly[dimethanol-κ1O-(μ2-(E)-2-((2-oxidobenzylidene)amino)acetato)-(μ3-(E)-2-((2-oxidobenzylidene)amino)acetato)dicadmium(II)], C20H22Cd2N2O8

Crystal structure of bis(2,5,5,7-tetramethyl-1,4-diazepane-1,4-diium) diaqua-bis(1,2-diaminopropane)copper(II) bis(μ6-oxido)tetrakis(μ3-oxido)-tetradecakis(μ2-oxido)-octaoxido-decavanadium(V) - water (1/4), C24H76CuN8V10O34

Crystal structure of bis(μ3-oxido)-bis(μ2-2-formylbenzoato-k2 O:O′)-bis(2-(dimethoxymethyl)-benzoato-κO)-oktakismethyl-tetratin(IV)

The crystal structure of poly[μ2-aqua- aqua-(μ3-(E)-2-(4-((2-carbamothioylhydrazineylidene)methyl)phenoxy)acetato-κ3O:S:S)sodium(I)], C10H14N3O5SNa

The crystal structure of the cocrystal di-μ2-chlorido-tetramethyl-tetraphenyl-di-μ3-oxido-dichloridotetratin(IV) - diphenyl-methyl-chloridotin(IV)(1/2), C54H58Cl6O2Sn6

Mixed-valent Manganese Complex with a Schiff-base Having a Di-μ4-oxido-di-μ3-oxido-di-μ3-carboxylato-hexa-μ-carboxylato-bridged Mn2IIMn6III Core

Synthesis and crystal structure of bis[μ-N,N-bis(2-aminoethyl)ethane-1,2-diamine]bis[N,N-bis(2-ammoethyl)ethane-1,2-thamine]-μ4-oxido-hexa-μ3-oxido-octa-μ2-oxido-tetraoxidotetranickel(II)hexatantalum(V) nonadecahydrate

Synthesis and structural characterization of hexa-μ2-chlorido-μ4-oxido-tetrakis{[4-(phenylethynyl)-pyridine-κN]copper(II)} dichloromethane monosolvate

Hexa-μ2-acetato-triaqua-μ3-oxido-triiron(III) nitrate acetic acid solvate

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