Review
Materials Science, Multidisciplinary
Xinwang Cao, Chang Ma, Lei Luo, Lei Chen, Hui Cheng, Raphael Simha Orenstein, Xiangwu Zhang
Summary: The addition of nanofiber materials to Li-ion batteries has been a significant advancement, as it provides unique structural features and enhances their electrochemical performance. This article discusses recent advancements in nanofiber materials for Li-ion batteries, including the synthesis, structure, and properties of nanofiber cathodes, anodes, separators, and electrolytes, as well as their applications. The challenges and prospects of nanofiber materials in Li-ion battery applications are also outlined.
ADVANCED FIBER MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Doo-Won Kim, So Yeun Kim, Kap Seung Yang
Summary: This study successfully synthesized a composite material consisting of graphene-wrapped niobium pentoxide and carbon nanofibers, which was used as a binder- and additive-free electrode for lithium-ion batteries. The composites exhibited outstanding electrochemical performances and are promising for application in next-generation high-performance lithium-ion batteries.
Article
Energy & Fuels
Ponnusamy Divya, Subramaniam Vadivel, Nunna Guru Prakash, Tae Jo Ko, Pitcheri Rosaiah
Summary: In this study, N-MnO carbon nanofibers composite was synthesized using electrospinning and employed as freestanding electrodes for lithium-ion batteries applications. The composite exhibited excellent discharge/charge capacity at a current density of 0.1 Ag-1, outperforming pure MnO, MnO2 electrodes. The outstanding performance can be attributed to good electrical conductivity, structural integrity, high surface area of CNFs, and good contact between CNFs and MnO NPs.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Review
Chemistry, Multidisciplinary
Jianing Lu, Zhi Zhang, Yifan Zheng, Yihua Gao
Summary: This review comprehensively summarizes recent progress in in situ transmission electron microscopy (TEM) investigations on the morphological, structural, and chemical evolutions of cathode materials, anode materials, and solid-electrolyte interface during the sodium storage of sodium-ion batteries (SIBs). The detailed relationship between the structure/composition of electrode materials and the electrochemical performance of SIBs has been clarified.
ADVANCED MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Jianing Lu, Zhi Zhang, Yifan Zheng, Yihua Gao
Summary: This review comprehensively summarizes the recent progress in in situ TEM investigations of sodium-ion batteries (SIBs), focusing on the morphological, structural, and chemical evolutions of cathode materials, anode materials, and solid-electrolyte interface during sodium storage. The detailed relationship between the structure/composition of electrode materials and the electrochemical performance of SIBs has been clarified. This review aims to provide insights for the effective selection and rational design of advanced electrode materials for high-performance SIBs.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Xiaodong Liu, Zhiqiang Wang, Yilin Niu, Chunyang Liu, Hongming Chen, Xianzhuo Ren, Zijin Liu, Woon-Ming Lau, Dan Zhou
Summary: Vanadium sesquioxide (V2O3) embedded in carbon nanofibers (V2O3@C NFs) was developed as a flexible and binder-free cathode material for aqueous zinc-ion batteries (AZIBs), exhibiting high initial capacity, excellent cycling stability, and enhanced rate capability. The unique structure of V2O3@C NFs, including nano-sized V2O3 crystals with a tunnel-like 3D phase structure uniformly distributed in N-doped carbon NFs, contributes to its superior electrochemical performance. The theoretical simulations based on first-principles calculations provide insights into efficient zinc storage mechanism, and the practical application potential of V2O3@C NFs as a cathode material for AZIBs was demonstrated through assembly of a full battery.
ACS APPLIED ENERGY MATERIALS
(2022)
Review
Chemistry, Physical
Xuewu Ou, Decai Gong, Chengjun Han, Zhong Liu, Yongbing Tang
Summary: The dual-ion battery (DIB) has gained significant attention as a novel cost-effective, high operating voltage, and environmentally friendly energy storage device. The electrolyte in DIBs plays a crucial role in determining the performance, capacity, and energy density of the battery. Rational design and optimization of anode materials are necessary to match the fast reaction kinetics at the cathode side in DIBs.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Dmitry Yarmolich, Yaroslav Odarchenko, Carmen Murphy, Enrico A. Petrucco, James Cookson, Dzianis Yarmolich, Teng Zhao, Hyun-Kyung Kim, R. Vasant Kumar, Rumen Tomov
Summary: Novel binder-free, high capacity carbon-based anodes were manufactured using Virtual Cathode Deposition technique, exhibiting excellent battery performance with high specific capacity and Coulombic efficiency. The unique structure of the coatings, including induced packing polymorphism and high surface area, plays a crucial role in enhancing the battery performance.
Review
Chemistry, Multidisciplinary
Luojiang Zhang, Haitao Wang, Xiaoming Zhang, Yongbing Tang
Summary: Dual-ion batteries (DIBs) show potential for high-efficiency energy storage beyond lithium-ion batteries due to advantages like high working voltage, material availability, low cost, and excellent safety. However, challenges remain in terms of limited capacity and cyclic stability, driving the need for suitable electrode materials and electrolytes with reversible capacities and oxidative stability for further development.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Jie Dang, Ruiyu Zhu, Shengqiang Zhang, Lijie Yang, Xin Chen, Hui Wang, Xiaojie Liu
Summary: In this study, a bean pod-like free-standing membrane was designed to address the challenge of large volume change in SbSn alloy anode materials for sodium-ion batteries. The synergistic carbon matrix not only improved conductivity and flexibility, but also provided buffer space to alleviate volume change. The resulting membrane anode showed excellent electrochemical performance in terms of specific capacity and coulombic efficiency.
Article
Energy & Fuels
Shunchang Li, Xin Guo, Lili Zhao, Fuhua Chen, Xueying Wang, Ying Chu, Weihua Wan, Yongping Zhu
Summary: This article presents the fabrication of nanofiber clusters of NiCo2O4-decorated 3D graphene@Nickel foam (NCO@3DGNF) as a potential anode material for high-energy-density lithium-ion batteries (LIBs). When used as a binder-free electrode, the NCO@3DGNF nanocomposite exhibits high discharge capacity, good reversibility, and excellent rate performance. The hierarchical porous structure of the material enhances electrolyte penetration, rapid electron transport, and strain buffering during lithiation.
Article
Chemistry, Multidisciplinary
Ling Wang, Changzheng Lin, Tingyi Liang, Ning Wang, Jiangtao Feng, Wei Yan
Summary: A novel composite material of NiSe2 nanoparticles encapsulated in N-doped TiN/carbon nanofibers with in-situ grown carbon nanotubes was prepared. The composite material exhibited excellent sodium-ion storage performance, attributed to the fast sodium-ion diffusion and transfer rate and the pseudocapacitance dominated charge storage mechanism.
MATERIALS TODAY CHEMISTRY
(2022)
Article
Engineering, Environmental
Jing Xia, Xin Zhang, Yongan Yang, Xi Wang, Jiannian Yao
Summary: This study proposes a method using titanium (IV) isopropoxide as a coupling agent to enhance the thermotolerant and mechanical properties of nanofibers, leading to the preparation of a porous Sb2S3/TiO2/C nanofiber membrane with good flexibility. Without the need for slurry coating processes, the porous Sb2S3/TiO2/C nanofiber membranes can be cut into electrodes and directly assembled into lithium-ion half-cells or full-cells.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Hongming Chen, Yan Li, Ruiqi Liu, Busheng Zhang, Zhiqiang Han, Woon-Ming Lau, Yao Lu, Xiaodan Wang, Mingshan Wang, Dan Zhou
Summary: Transition metal sulfides (TMSs) are promising anode materials for sodium-ion batteries due to their high theoretical capacity. However, the Na-storage performance of TMSs is unsatisfactory due to structural degeneration caused by volume change during the redox process. In this study, a flexible and binder-free anode material of porous CoS1.097@carbon nanofibers was successfully synthesized. The unique structure of porous CoS1.097@carbon nanofibers can provide sufficient active sites, promote ion diffusion, alleviate volume variation, and maintain structural stability, resulting in high initial discharge capacity, enhanced rate capability, and long-term cycling life. The research also provides insights into the intrinsic diffusion and electrochemical storage behavior of Na+ ions. This work offers a facile approach for the synthesis of flexible and binder-free TMSs-based anode materials and promotes the practical application of wearable sodium-ion batteries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Lifeng Zhang, Yifei Song, Yue Hu, Huan Ruan, Jiaxi Bai, Shuai Li, Yi Liu, Shouwu Guo
Summary: The flexible Sb/Sb2O3-C nanofibers films were successfully fabricated using a combination of electrospinning technique and carbonization, showing promising potential as binder-free anodes for SIBs with high capacity and long cycle life.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Multidisciplinary
Xuan Wu, Ming Liu, Cheng Zheng, Yingying Wang, Yujing Zheng, Yuna Qian, Zhiyong Liao, Guoyong Fang, Jianliang Shen
Summary: A handedness controllable circularly polarized luminescence (CPL) system was successfully constructed by tuning the supramolecular self-assembly. The planar structure of the solvent N,N-dimethylformamide co-assembled with CPT-A, resulting in a change in the glum from -0.0082 to +0.0085 with increasing water content. In the non-planar solvent hexafluoroisopropanol, the glum was amplified to 0.034 with increasing water content. Moreover, CPT-A could react with glutathione to make the anticancer drug CPT more toxic to cancer cells.
CHINESE CHEMICAL LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Luqi Wang, Li Song, Zhenyu Yang, Yu-Ming Chang, Feng Hu, Lei Li, Linlin Li, Han-Yi Chen, Shengjie Peng
Summary: This study reports a facile in situ growth strategy for the synthesis of tightly connected 2D/2D heterostructures by coupling MXene with CoBDC nanosheets. The optimized CoBDC/MXene exhibits superior hydrogen evolution reaction activity.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Physical
Hui Wang, Yanan Hao, Yajie Sun, Jiayue Pan, Feng Hu, Dan Kai, Shengjie Peng
Summary: Metal-support interaction is used to control the selectivity of electrochemical CO2 reduction reaction (CO2RR). In this study, Cu metal nanoparticle catalysts of different sizes were prepared and encapsulated in Zn, N-doped carbon supports to investigate the size effect on CO2RR reactivity. The results show that the size of Cu crystallites affects the performance of CO2RR, which is attributed to the interaction between metal nanoparticles and their supporting matrix.
Article
Chemistry, Multidisciplinary
Hanzhi Yu, Shangqian Zhu, Yixin Hao, Yu-Ming Chang, Linlin Li, Jun Ma, Han-Yi Chen, Minhua Shao, Shengjie Peng
Summary: In this study, hierarchical Fe doped cobalt selenide coupled with FeCo layered double hydroxide (Fe-Co0.85Se/FeCo LDH) array was designed as a self-supported superior bifunctional heterojunction electrode for efficient urea oxidation reaction (UOR) and hydrogen evolution reaction (HER) under high current density. The unique heterostructure improved reaction kinetics and intrinsic activity through electron transfer and interface interactions. The interfacial bonding of the heterojunction induced adjustable electronic environment for water decomposition of HER and stabilizing intermediates in UOR, leading to a low potential for hydrogen generation.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Sheng Zhao, Lijie Yin, Liming Deng, Junnan Song, Yu-Ming Chang, Feng Hu, Hui Wang, Han-Yi Chen, Linlin Li, Shengjie Peng
Summary: This study demonstrates the importance of rational heterointerface engineering for superior and robust hydrogen evolution reaction (HER). By constructing organic-inorganic hybrid heterojunctions, the researchers achieve strong electron coupling and optimal electronic structure for efficient HER. The resulting hybrid material exhibits low overpotentials and robust stability, making it a promising electrocatalyst.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Linlin Li, Yanchen Ma, Fangyan Cui, Yan Li, Deshuang Yu, Xintong Lian, Yuxiang Hu, Hongyi Li, Shengjie Peng
Summary: Due to the unique electronic structure of aluminum ions (Al3+), traditional electrodes usually exhibit slow kinetic process and inferior rechargeable aluminum batteries (RABs) performance. To solve this problem, a Se2.9S5.1-based cathode with sufficient valence electronic energy overlap with Al3+ and easily accessible structure is developed. This cathode exhibits high capacity, high rate-capacity, robust stability, and enhanced flexibility, and the mechanism of SexSy in RABs is also explored.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Xiaoli Wu, Sheng Zhao, Lijie Yin, Luqi Wang, Linlin Li, Feng Hu, Shengjie Peng
Summary: Amorphous CoNiS nanosheets are synthesized on nickel foam (NF) through a facile structure evolution strategy and demonstrate advanced performance in water splitting at high current densities. This is attributed to the sufficient active sites exposed by the flexible amorphous configuration. The hydrophilicity and aerophobicity of a-CoNiS/NF promote surface wettability and avoid bubble aggregation, facilitating mass transfer and achieving low overpotentials for hydrogen and oxygen evolution reactions under alkaline conditions.
CHINESE CHEMICAL LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Yixin Hao, Deshuang Yu, Shangqian Zhu, Chun-Han Kuo, Yu-Ming Chang, Luqi Wang, Han-Yi Chen, Minhua Shao, Shengjie Peng
Summary: An efficient catalyst comprised of highly dispersed FeNi oxide heterojunctions anchored on nickel foam is synthesized using an ultrafast solution combustion strategy. This catalyst exhibits excellent stability and activity at large current densities for anodic organic upgrading, and achieves high faradaic efficiency in methanol electrooxidation.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Aoming Huang, Yuhan Wu, Hongjiao Huang, Chunsheng Li, Yan Sun, Linlin Li, Shengjie Peng
Summary: A 3D host made of lithiophilic Mo2C clusters-embedded carbon nanofibers (Mo2C@CNF) is developed as an ideal candidate for next-generation high-energy lithium batteries. The Mo2C@CNF composite provides numerous nucleation sites for lithium deposition and exhibits a lower nucleation overpotential compared to MoO2. Moreover, it enables the formation of a stable solid electrolyte interphase layer and enhances the Coulombic efficiency, resulting in excellent electrochemical performance and cycling stability.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Hongjiao Huang, Aoming Huang, Di Liu, Wentao Han, Chun-Han Kuo, Han-Yi Chen, Linlin Li, Hui Pan, Shengjie Peng
Summary: In this study, oxygen vacancy-rich porous perovskite oxide (CaMnO3) nanofibers coated with reduced graphene oxide (rGO) were developed as the air electrode catalyst for low-temperature and knittable Zn-air batteries. The V-CMO/rGO exhibited top-level oxygen reduction reaction (ORR) activity among perovskite oxides and showed impressive kinetics under low temperature. The V-CMO/rGO demonstrated high peak power density of 56 mW cm(-2) and long cycle life of over 80 h at a low temperature of -40°C.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Sheng Zhao, Yue Wang, Yixin Hao, Lijie Yin, Chun-Han Kuo, Han-Yi Chen, Linlin Li, Shengjie Peng
Summary: This study focuses on the design of catalysts for the neutral oxygen evolution reaction (OER). By constructing a built-in electric field to regulate electron distribution, the optimized Ni-FeWO4@WO3/NF self-supporting electrode exhibits low overpotential and stable operation in neutral media.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Luqi Wang, Zipeng Xu, Chun-Han Kuo, Jian Peng, Feng Hu, Linlin Li, Han-Yi Chen, Jiazhao Wang, Shengjie Peng
Summary: A general strategy is proposed to use the metalloid properties of supports to trap and stabilize single-atoms with low-valence states. This work offers new guidance for the precise construction of highly active single-atom catalysts (SACs). The representative Ru-WCx exhibits superior mass activities for the hydrogen oxidation and evolution reactions. Evaluation: 8/10.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Inorganic & Nuclear
Ye Wang, Yixin Hao, Luqi Wang, Chunsheng Li, Jianwei Ren, Yan Sun, Feng Hu, Linlin Li, Shengjie Peng
Summary: Dispersing electron-rich ruthenium dioxide on metal-deficient TiO2 as a catalyst for the oxygen evolution reaction in acidic media improves the kinetics of the reaction and achieves excellent activity. The combination with defective support triggers charge transfer and optimizes the adsorption/desorption process, leading to a lower overpotential compared to commercial ruthenium dioxide. This study provides a potential strategy for the development of low-cost noble metal catalysts.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Multidisciplinary
Liming Deng, Sung-Fu Hung, Sheng Zhao, Wen-Jing Zeng, Zih-Yi Lin, Feng Hu, Yaoyi Xie, Lijie Yin, Linlin Li, Shengjie Peng
Summary: This study investigates the dynamic structural transformation induced by MXene for cobalt-based electrocatalysts containing various oxyanions during the hydrogen evolution reaction (HER) activation process. The in situ coordination of borate induces the formation of asymmetric active centers, enhancing the HER activity. Theoretical calculations reveal that the transfer of electrons from Co sites to coordinated oxyanions modulates the electron density of active sites, reducing the energy barrier for water dissociation and hydrogen adsorption.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Leonid Filatov, Pavel Vishniakov, Ilya Ezhov, Ivan Gorbov, Denis Nazarov, Denis Olkhovskii, Rajesh Kumar, Shengjie Peng, Gang He, Vladislav Chernyavsky, Marina Gushchina, Maxim Maximov
Summary: This article investigates the impact of atomic layer deposition method on the growth of carbon nanotubes, and found that the initial NiO layer thickness plays a significant role in achieving intensive growth of carbon nanotubes.