4.8 Article

Sol-Gel Derived Transparent Zirconium-Phenyl Siloxane Hybrid for Robust High Refractive Index LED Encapsulant

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 6, Issue 5, Pages 3115-3121

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am500315y

Keywords

LED encapsulant; zirconium oligosiloxane; thermal stability; hybrid material; packaging; optical applications

Funding

  1. National Research Foundation of Korea (NRF)
  2. Korea government (MSIP) [NRF-2013R1A2A2A05005911]

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We report a zirconium-phenyl siloxane hybrid material (ZPH) that can be used as a robust LED encapsulant. The ZPH encapsulant was fabricated via hydrosilylation-curing of sol-gel derived multifunctional (vinyl- and hydride-functions) siloxane resins containing phenyl-groups and Zr-O-Si heterometallic phase for achieving a high refractive index (n approximate to 1.58). In thermal aging, the ZPH LED encapsulant exhibited superior performances with a high optical transparency (similar to 88% at 450 nm) and exhibited high thermal stability (no yellowing at 180 degrees C for 1008 h), compared to a commercial LED encapsulant (OE-6630, Dow Corning Corporation). This suggests potential for ZPH to be a robust LED encapsulant.

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