Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 5, Issue 22, Pages 11494-11497Publisher
AMER CHEMICAL SOC
DOI: 10.1021/am4024884
Keywords
phosphamide; solid electrolyte interface (SEI); safety; lithium-ion batteries
Funding
- National Basic Research Program of China (973 program) [2011CB935903]
- National Natural Science Foundation of China [21233004, 21021002]
Ask authors/readers for more resources
In this communication, a novel electrolyte additive, N,N-diallyic-diethyoxyl phosphamide (DADEPA), is described for the first time to improve the thermal stability of lithiated graphite anode in Li-ion batteries. The differential scanning calorimetry (DSC) measurement demonstrated that when the graphite was lithiated in the 5% DADEPA-containing electrolyte, the heat generation decreased sharply by half as compared with the reference, whereas the onset temperature for the main exothermic process was postponed by 20 degrees C. Electrochemical and XPS analyses indicated that the distinctive improvement in thermal safety came from a new interfacial chemistry, in which phosphorus-containing ingredients was embedded during the initial forming of the interphase.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available