4.8 Article

TiO2-Derived Titanate Nanotubes by Hydrothermal Process with Add Treatments and Their Microstructural Evaluation

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 2, Issue 9, Pages 2611-2616

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am1004442

Keywords

titanate; nanotubes; hydrothermal process; acid treatments; microstructure; XAFS

Funding

  1. Japan Society for the Promotion of Science [20047011]
  2. Grants-in-Aid for Scientific Research [20047011] Funding Source: KAKEN

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In this study, the effect of post acid treatments with HCl aqueous solutions after the hydrothermal process on the microstructure of TiO2-derived titanate nanotube was investigated. Especially, the relationship between local structural changes with the HCI treatment and their thermal stability were investigated by X-ray absorption fine structure (XAFS). Consequently, it revealed that the replacement of Na+ with H+ (proton exchange) in TiO2-derived titanate nanotubes was caused by the acid treatment with HCl aqueous solutions and the excess acid treatment led to the disordering. Moreover, it was confirmed that the minor change of TiOx polyhedra in TiO2-derived titanate nanotubes was also related with this disordering.

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