Review
Environmental Sciences
Hanyu Li, Yi Huang, Jianing Liu, Haoran Duan
Summary: This article reviews the current research status and influencing factors of hydrothermally synthesized titanate nanomaterials (TNMs) as adsorbents for heavy metals and radionuclides, including their structural changes, regenerability, and modification methods, and also highlights the efficient decontamination of pollutants through a synergistic effect of adsorption and photocatalysis by TNMs.
Article
Chemistry, Physical
Mohammad Qamar, Shabi Abbas Zaidi, Mohd Rafatullah, Mohammad Qutob, Sun-Jae Kim, Qasem A. Drmosh
Summary: The present study investigates the thermal stability and photocatalytic activity of TiO2-based nanotubes after post-hydrothermal treatment. It is found that post-hydrothermal heating improves the photocatalytic activity of the nanotubes by changing their phase structure and morphology. The holes and hydroxide ions are found to play a key role in the dye removal process. Additionally, the photocatalyst exhibits excellent stability and reusability.
Article
Chemistry, Inorganic & Nuclear
Caique Diego de Abreu Lima, Roniel dos Santos Sousa, Antonio Werbeson Miranda, Joao Victor Barbosa Moura, Gardenia de Sousa Pinheiro, Bartolomeu Cruz Viana, Iara Souza Lima, Thiago Mielle Brito Ferreira Oliveira, Oswaldo Baffa, Jefferson Ferraz Damasceno Felix Araujo, Cleanio da Luz Lima
Summary: This study investigated the synthesis, characterization, and thermal stability of pure and Al ion-exchange titanate nanotubes (Na2Ti3O7 and NaxAlyTi3O7, respectively). The results revealed the obtainment of sodium titanate and aluminum titanate nanotubes with different average lengths and diameters. The presence of Al ions in the crystal lattice affected the energy exchange between the unpaired species and the lattice. The thermal stability of sodium titanate nanotubes was influenced by sodium ions, while the incorporation of Al3+ ions into the nanotube lamellae decreased the thermal stability of aluminum titanate nanotubes.
SOLID STATE SCIENCES
(2023)
Article
Chemistry, Physical
N. A. Morozov, D. S. Ershov, N. V. Besprozvannykh, S. V. Mjakin, E. Yu. Brazovskaya, O. L. Galankina, A. V. Koroleva
Summary: This study proposes the modification of potassium titanate particles with magnesium in order to investigate their photocatalytic properties in the photodegradation reaction. The optimal amount of 4 at.% magnesium was found to result in the particles with the largest specific surface area and highest dye removal capacity.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Applied
Yinuo Zhang, Yibo Xin, Jialin Cao, Yaning Liu, Shuxiang Lv, Xiaoyuan Liao, Zhen Li, Yue Yao
Summary: Direct hydrothermal synthesized H-Titanate nanotube catalysts (H-TiNTs) were prepared and evaluated for the oxidation of dibenzothiophene (DBT) in model diesel. The effects of adding model components of 1-octylene, xylene, or cyclohexane in real diesel for sulfur removal were also evaluated. The results showed that the removal of DBT was maintained at nearly 100% under optimal conditions.
JOURNAL OF POROUS MATERIALS
(2023)
Article
Chemistry, Physical
Maria Jose Cortes Burgos, Italo Moglia, Simon Roa, Victor Fuenzalida
Summary: This work reports the effects of oleic acid as a surfactant on the growth properties of hydrothermally-synthesized BaTiO3 films by chemical modification of Ti sheets. The micro-structural properties and chemical composition were studied using XRD, XPS, and SEM. This study provides an interesting starting point for the future synthesis of nanostructured BaTiO3 thin films with optimized properties for potential applications in Flexible Capacitors (FCs).
CHEMICAL PHYSICS LETTERS
(2022)
Article
Chemistry, Inorganic & Nuclear
Huiqi Zheng, Jin Chen, Meidan Que, Tai Yang, Zhikang Liu, Weihua Cai, Lingfu Yang, Xinwei Liu, Yanjun Li, Xiaofeng Yang, Yuzhao Ma, Gangqiang Zhu
Summary: The coupling of the piezoelectric effect and photocatalytic process promoted the separation of photogenerated carriers, thus increasing the piezo-photocatalytic activity. BaTiO3 nanoparticles were prepared on the Ti3C2Tx surface, and the obtained BaTiO3/Ti3C2Tx piezo-photocatalysts exhibited rapid electron transfer and a wide visible light response range. These results demonstrate that coupling piezoelectric and photocatalytic properties has broad application prospects in water pollution control.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Energy & Fuels
Shuolin Zhou, Min Long, Lu Wu, Min Lei, JunZhuo Bai, Keying Huang, XianXiang Liu, Dulin Yin
Summary: Covalently bonded sulfamic acid on the titanate nanotubes showed high catalytic activity and good recyclability for the esterification reaction.
BIOMASS CONVERSION AND BIOREFINERY
(2022)
Article
Food Science & Technology
Qin Wei, Yubao Guo, Kang Tu, Xiuling Zhu, Dan Xie, Xinyu Liu
Summary: The effects of ascorbic acid treatment alone and in combination with degreasing or hydrothermal treatment on improving the poor mouthfeel and low digestibility of brown rice were studied. The results showed that combining degreasing with ascorbic acid hydrothermal treatment significantly improved the texture of cooked brown rice, reducing hardness and chewiness to the level of polished rice, increasing stickiness, and enhancing sensory score and in vitro digestibility. The study also found that treated brown rice had reduced relative crystallinity and water contact angle, and increased water uptake. Scanning electron microscope showed starch granule separation in cooked brown rice grain. The improved eating quality and digestibility of brown rice is beneficial for consumer acceptance and human health.
Article
Engineering, Environmental
Fei Pan, Haodong Ji, Penghui Du, Taobo Huang, Chong Wang, Wen Liu
Summary: This study successfully degraded and mineralized CBZ using AMnTi composite material, increasing the degradation rate of CBZ. The high catalytic activity of AMnTi is attributed to its unique structure, leading to efficient charge transfer and catalytic activation through Mn-O-Ti linkage, and a Mn-Ti cycle mediating catalytic activation of PMS was discovered. Both hydroxyl and sulfate radicals played key roles in CBZ degradation.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Yuqian Huang, Rongfeng Tang, Peng Xiao, Bo Che, Yan Wang, Huihui Gao, Gang Wang, Changfei Zhu, Tao Chen
Summary: In this study, a new in situ sulfuration method was developed to prepare high-efficiency Sb2S3 solar cells by introducing tartaric acid additive into the hydrothermal deposition process. This method not only simplifies the sulfuration process, but also improves the crystallinity and defect property of the film.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Nanoscience & Nanotechnology
James Morel, Oliver Mcneilly, Sarah Grundy, Toby Brown, Cindy Gunawan, Rose Amal, Jason Scott
Summary: Bioinspired nanotopography fabricated on titanium surfaces can address postoperative infections in orthopedics. This study introduces a method to create surface nanostructures at lower temperatures, which exhibit comparable antimicrobial properties to high-temperature surfaces. These findings provide valuable insight into the application of low-temperature etching protocols in large-scale manufacturing settings.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Nanoscience & Nanotechnology
James Morel, Oliver Mcneilly, Sarah Grundy, Toby Brown, Cindy Gunawan, Rose Amal, Jason Scott
Summary: Bioinspired nanotopography fabricated on titanium surfaces can effectively address postoperative infections in orthopedics. By using relatively lower synthesis temperatures, comparable physicochemical properties and antimicrobial capability can be achieved. The study demonstrates the potential of low-temperature hydrothermal synthesis for large-scale manufacturing.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Materials Science, Multidisciplinary
Qiu-Hong Yuan, Lin Liao, Guo-Hua Zhou, Zheng-Yun Liu
Summary: Liquid mixing combined with the stirring casting method is effective in fabricating Mg-CNTs composites with significant improvements in mechanical properties, attributed to the uniform dispersion of CNTs and strong interfacial bonds with the Mg matrix.
Review
Engineering, Environmental
Oraleou Sangue Djandja, Lin-Xin Yin, Zhi-Cong Wang, Pei-Gao Duan
Summary: This article systematically reviews recent findings on hydrothermal treatments of Municipal Sewage Sludge, highlighting the related chemical reactions and the impact of reaction parameters. Suggestions are made for optimizing the applications of end products, and potential challenges for future hydrothermal treatments are discussed.
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2021)