Visible-light-induced iminyl radical formation via electron-donor–acceptor complexes: a photocatalyst-free approach to phenanthridines and quinolines

Visible-light excitation of iminium ions enables the enantioselective catalytic β-alkylation of enals

(2017) Mattia Silvi et al.   Nature Chemistry

Radical Alkynyltrifluoromethylation of Alkenes Initiated by an Electron Donor–Acceptor Complex

(2017) Heng Jiang et al.   ORGANIC LETTERS

N-Radical Initiated Aminosulfonylation of Unactivated C(sp3)–H Bond through Insertion of Sulfur Dioxide

(2017) Yuewen Li et al.   ORGANIC LETTERS

Photoredox-Catalyzed Diamidation and Oxidative Amidation of Alkenes: Solvent-Enabled Synthesis of 1,2-Diamides and α-Amino Ketones

(2017) Qixue Qin et al.   ORGANIC LETTERS

Visible Light as a Sole Requirement for Intramolecular C(sp3)–H Imination

(2017) Jingjing Li et al.   ORGANIC LETTERS

Photochemical Generation of Nitrogen-Centered Amidyl, Hydrazonyl, and Imidyl Radicals: Methodology Developments and Catalytic Applications

(2017) Markus D. Kärkäs   ACS Catalysis

Visible light-induced tandem oxidative cyclization of 2-alkynylanilines with disulfides (diselenides) to 3-sulfenyl- and 3-selenylindoles under transition metal-free and photocatalyst-free conditions

(2017) Qing Shi et al.   Organic Chemistry Frontiers

Photochemical Stereocontrol Using Tandem Photoredox–Chiral Lewis Acid Catalysis

(2016) Tehshik P. Yoon   ACCOUNTS OF CHEMICAL RESEARCH

A General Approach to Catalytic Alkene Anti-Markovnikov Hydrofunctionalization Reactions via Acridinium Photoredox Catalysis

(2016) Kaila A. Margrey et al.   ACCOUNTS OF CHEMICAL RESEARCH

Photocatalyst-free hypervalent iodine reagent catalyzed decarboxylative acylarylation of acrylamides with α-oxocarboxylic acids driven by visible-light irradiation

(2016) Wangqin Ji et al.   CHEMICAL COMMUNICATIONS

Organic Photoredox Catalysis

(2016) Nathan A. Romero et al.   CHEMICAL REVIEWS

Dual Catalysis Strategies in Photochemical Synthesis

(2016) Kazimer L. Skubi et al.   CHEMICAL REVIEWS

Visible light photoredox-controlled reactions of N-radicals and radical ions

(2016) Jia-Rong Chen et al.   CHEMICAL SOCIETY REVIEWS

Visible-Light-Induced Direct Oxidative C−H Amidation of Heteroarenes with Sulfonamides

(2016) Kun Tong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism of the Stereoselective α-Alkylation of Aldehydes Driven by the Photochemical Activity of Enamines

(2016) Ana Bahamonde et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Photoredox Catalyzed Cyclization of O-(2,4-Dinitrophenyl)oximes to Phenanthridines

(2016) Xiubin Liu et al.   MOLECULES

Hydrotrifluoromethylation of Unactivated Alkenes and Alkynes Enabled by an Electron-Donor–Acceptor Complex of Togni’s Reagent with a Tertiary Amine

(2016) Yuanzheng Cheng et al.   ORGANIC LETTERS

Halogen-Bond-Promoted Double Radical Isocyanide Insertion under Visible-Light Irradiation: Synthesis of 2-Fluoroalkylated Quinoxalines

(2016) Xiaoyang Sun et al.   ORGANIC LETTERS

Organic Synthesis Enabled by Light-Irradiation of EDA Complexes: Theoretical Background and Synthetic Applications

(2016) Carolina G. S. Lima et al.   ACS Catalysis

Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization Reactions

(2015) Jacob Davies et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Promoted Iminyl-Radical Formation from Acyl Oximes: A Unified Approach to Pyridines, Quinolines, and Phenanthridines

(2015) Heng Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tris(trimethylsilyl)silane and visible-light irradiation: a new metal- and additive-free photochemical process for the synthesis of indoles and oxindoles

(2015) Gustavo Piva da Silva et al.   CHEMICAL COMMUNICATIONS

Direct Aromatic CH Trifluoromethylation via an Electron-Donor-Acceptor Complex

(2015) Yuanzheng Cheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Organocatalytic Alkylation of Aldehydes and Enals Driven by the Direct Photoexcitation of Enamines

(2015) Mattia Silvi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-light-promoted chloramination of olefins with N-chlorosulfonamide as both nitrogen and chlorine sources

(2015) Qixue Qin et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Direct Synthesis of Nitriles from Aldehydes Using an O-Benzoyl Hydroxylamine (BHA) as the Nitrogen Source

(2015) Xiao-De An et al.   ORGANIC LETTERS

Visible-Light-Promoted Remote C(sp3)–H Amidation and Chlorination

(2015) Qixue Qin et al.   ORGANIC LETTERS

Visible-Light-Promoted and One-Pot Synthesis of Phenanthridines and Quinolines from Aldehydes and O-Acyl Hydroxylamine

(2015) Xiao-De An et al.   ORGANIC LETTERS

Computational Study with DFT and Kinetic Models on the Mechanism of Photoinitiated Aromatic Perfluoroalkylations

(2015) Victor M. Fernández-Alvarez et al.   ORGANIC LETTERS

Visible-light-promoted and photocatalyst-free trifluoromethylation of enamides

(2015) Hao Wang et al.   Science China-Chemistry

Photochemical direct perfluoroalkylation of phenols

(2015) Giacomo Filippini et al.   TETRAHEDRON

Metal-Free CH Bond Activation of Branched Aldehydes with a Hypervalent Iodine(III) Catalyst under Visible-Light Photolysis: Successful Trapping with Electron-Deficient Olefins

(2014) Shin A. Moteki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Photochemical Aromatic Perfluoroalkylation of α-Cyano Arylacetates

(2014) Manuel Nappi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light Promoted Catalyst-Free Imidation of Arenes and Heteroarenes

(2014) Lu Song et al.   CHEMISTRY-A EUROPEAN JOURNAL

Site-Selective Aliphatic C–H Bromination Using N-Bromoamides and Visible Light

(2014) Valerie A. Schmidt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The electron is a catalyst

(2014) Armido Studer et al.   Nature Chemistry

Visible-Light-Promoted Redox Neutral C–H Amidation of Heteroarenes with Hydroxylamine Derivatives

(2014) Qixue Qin et al.   ORGANIC LETTERS

Gold Catalysis Coupled with Visible Light Stimulation: Syntheses of Functionalized Indoles

(2014) Shunyou Cai et al.   ORGANIC LETTERS

Enantioselective direct α-alkylation of cyclic ketones by means of photo-organocatalysis

(2014) Elena Arceo et al.   Chemical Science

Method of Continuous Variations: Applications of Job Plots to the Study of Molecular Associations in Organometallic Chemistry

(2013) Joseph S. Renny et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

6-Trifluoromethyl-Phenanthridines through Radical Trifluoromethylation of Isonitriles

(2013) Bo Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Visible Light-mediated Direct Arylation of Arenes and Heteroarenes Using Diaryliodonium Salts in the Presence and Absence of a Photocatalyst

(2013) Mamoru Tobisu et al.   CHEMISTRY LETTERS

Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction

(2013) Eric J. Popczun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemical activity of a key donor–acceptor complex can drive stereoselective catalytic α-alkylation of aldehydes

(2013) Elena Arceo et al.   Nature Chemistry

Synthetic applications of photoredox catalysis with visible light

(2013) Yumeng Xi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Control of Charge Transfer in Donor/Acceptor Metal–Organic Frameworks

(2012) Hitoshi Miyasaka   ACCOUNTS OF CHEMICAL RESEARCH

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalysis and CH Activation Meet Radical- and Electron-Transfer Reactions

(2011) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unusual ipso Substitution of Diaryliodonium Bromides Initiated by a Single-Electron-Transfer Oxidizing Process

(2010) Toshifumi Dohi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Fresh Look at Electron-Transfer Mechanisms via the Donor/Acceptor Bindings in the Critical Encounter Complex

(2008) Sergiy V. Rosokha et al.   ACCOUNTS OF CHEMICAL RESEARCH