Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 5, Issue 10, Pages 1664-1669Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo00163d
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Funding
- National Basic Research Program of China [2015CB856600]
- National Natural Science Foundation of China [21572252]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000, QYZDY-SSW-SLH012]
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A palladium-catalyzed intermolecular dearomatic allenylation of hydrocycloalk[b]indoles with 2,3-allenyl carbonates has been developed, providing access to functionalized allenes containing an indoline unit under optimized conditions. Both terminal and non-terminal allenes could react smoothly with an exclusive chemoselectivity and good yields by applying different reaction parameters.
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