Journal
CRYSTALS
Volume 8, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/cryst8010037
Keywords
metal-organic framework; neutral N-donor framework; structural transformations
Funding
- CSIR
- IISER-Pune
- SERB [EMR/2016/000410]
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A novel three-dimensional two-fold interpenetrated bi-porous metal-organic framework IPM-325 (IPM: IISER Pune Materials) having pcu topology was synthesized at room temperature. Single crystal X-ray diffraction (SC-XRD) study revealed that the compound crystallizes in monoclinic lattice with molecular formula {[Zn(L)(2) (SiF6)] (CH2Cl2) xG}(n) where G = Guests). All metal centers were found to have octahedral geometry. From single crystal analysis it can be inferred that SiF62- anion play a vital role in extending the dimensionality of the framework by bridging between two metal centers. Interestingly, IPM-325 exhibited two-step structural transformation maintaining the crystallinity of the framework as characterized by powder X-ray diffraction (PXRD).
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