Article
Chemistry, Multidisciplinary
James E. Tyrrell, Martyn G. Boutelle, Alasdair J. Campbell
Summary: OECTs have proven to be successful in transducing physiological information and measuring high-frequency signals, with significant improvements in key performance parameters like peak transconductance and response time.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Raufar Shameem, Lukas M. Bongartz, Anton Weissbach, Hans Kleemann, Karl Leo
Summary: The ability of organic electrochemical transistors (OECTs) to combine ionic and electronic transport with large volumetric capacitance makes them ideal for bioelectronic applications. The use of solid electrolytes based on ionic liquids extends their applicability and enables large-area printable production. However, OECTs with solid electrolytes often exhibit pronounced hysteresis in the transfer curve, which needs to be understood for accurate characterization and reliable applications.
APPLIED SCIENCES-BASEL
(2023)
Article
Chemistry, Physical
Florent Sahli, Nathanael Miaz, Niccolo Salsi, Cedric Bucher, Aymeric Schafflutzel, Quentin Guesnay, Leo Duchene, Bjorn Niesen, Christophe Ballif, Quentin Jeangros
Summary: Vapor-based processes show promise for depositing metal halide perovskite solar cells in industrial settings, allowing for uniform layer deposition over large areas and conformal layers on rough substrates. The development of a vapor transport deposition chamber helps control the complex sublimation of organic precursors, ensuring high-quality perovskite layers are produced. Small-scale methylammonium lead iodide solar cells are processed to validate the absorber quality produced by this method.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Reem B. Rashid, Austin M. Evans, Lyndon A. Hall, Raghunath R. Dasari, Emily K. Roesner, Seth R. Marder, Deanna M. D'Allesandro, William R. Dichtel, Jonathan Rivnay
Summary: Organic electrochemical transistors (OECTs) have great potential in bioelectronic sensing, circuits, and neuromorphic hardware. The use of organic mixed ionic/electronic conductors (OMIECs) as the active channel allows for precise control of electronic and ion transport. Two-dimensional polymers (2DPs) offer new opportunities to control OECT performance by providing well-defined channels for ion transport.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Anton Weissbach, Matteo Cucchi, Hsin Tseng, Karl Leo, Hans Kleemann
Summary: Organic electrochemical transistors (OECTs) are promising for bioelectronics and neuromorphic computing, but their integration into real-world applications is hindered by a lack of understanding of their complex operation. This study reveals a peculiar behavior of integrated OECTs in their electrolytic environment, called electrochemical electrode coupling (EEC), which significantly affects device and circuit performance. A physical model is developed to describe this effect and experimental data substantiate it, highlighting the crucial role of the gate electrode. The study also explores the impact of electrode/channel overlap on output saturation and demonstrates ways to minimize its detrimental effect on circuit performance.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Tung Nguyen-Dang, Sangmin Chae, Jirat Chatsirisupachai, Hiba Wakidi, Vinich Promarak, Yon Visell, Thuc-Quyen Nguyen
Summary: This study reports an organic reconfigurable logic gate based on dual-mode organic electrochemical transistors. The gate has a simple structure and design, low power consumption, and can operate in both depletion mode and enhancement mode. Mode switching is achieved by altering the polarity of the applied gate and drain voltages.
ADVANCED MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Tung Nguyen-Dang, Sangmin Chae, Kelsey Harrison, Luana C. Llanes, Ahra Yi, Hyo Jung Kim, Shantonu Biswas, Yon Visell, Guillermo C. Bazan, Thuc-Quyen Nguyen
Summary: A wet processing method for fabricating high-performance OECTs is reported, simplifying the fabrication process and enhancing the electrical properties of the active material. OECTs fabricated using this method have been demonstrated to be applicable for chemical sensors with good detection capabilities.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Yizhou Zhong, Anil Koklu, Diego Rosas Villalva, Yongcao Zhang, Luis Huerta Hernandez, Maximilian Moser, Rawad K. Hallani, Iain McCulloch, Derya Baran, Sahika Inal
Summary: Organic photodiodes (OPDs) have the potential to be used in flexible, lightweight, and miniaturized photodetectors for wearable applications. However, the current and light responsivity of OPDs are limited, and alternative methods are needed to enhance the signal response. In this study, a miniaturized organic electrochemical transistor (OECT) is integrated with an OPD module to harness the potential of OPDs in acquiring physiological signals. The integrated photodetector (IPD) system uses the light intensity to regulate the OPD voltage output, which in turn modulates the OECT channel current. The high transconductance of the OECT enables efficient voltage-to-current conversion, improving the signal-to-noise ratio at the sensing site. The IPD achieves significantly higher photocurrent and responsivity compared to the standalone OPD, highlighting its potential as a wearable biosensor for detecting weak light-based signals from living systems.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Sanggil Han, Anastasios G. Polyravas, Shofarul Wustoni, Sahika Inal, George G. Malliaras
Summary: Organic electrochemical transistors (OECTs) are widely used as amplifying transducers of biological signals due to their high transconductance and biocompatibility. This work highlights the impact of small local gate electrodes and narrow interconnects on the performance of OECTs, showing a decrease in maximum transconductance and an increase in gate voltage required. Additionally, coating the gate electrode with a thick conducting polymer is shown to improve performance, guiding the development of efficient OECTs on implantable probes.
ADVANCED MATERIALS TECHNOLOGIES
(2021)
Article
Chemistry, Multidisciplinary
Carlo Bruno, Eleonora Ussano, Gianni Barucca, Davide Vanossi, Giovanni Valenti, Edward A. Jackson, Andrea Goldoni, Lucio Litti, Simona Fermani, Luca Pasquali, Moreno Meneghetti, Claudio Fontanesi, Lawrence T. Scott, Francesco Paolucci, Massimo Marcaccio
Summary: The presence of non-hexagonal rings in graphene leads to rippled graphene layers with valuable properties. An electrochemical method using corannulene polycondensation can produce egg-box shaped nanographene structures, demonstrating wavy graphene-like structures with conducting properties.
Article
Chemistry, Multidisciplinary
Zhenye Zhan, Dongxu Lin, Juntao Cai, Yueheng Lu, Aidi Chen, Tiankai Zhang, Ke Chen, Pengyi Liu, Xiaomu Wang, Weiguang Xie
Summary: This study presents a new type of perovskite photodiode-blocking diode crossbar array by vapor deposition method, which achieves excellent suppression of optoelectrical crosstalk among pixels and fast response time for real-time image acquisition. The imaging sensor demonstrates a large linear dynamic range and weak light sensitivity.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Youngseok Kim, Gunwoo Kim, Bowen Ding, Dahyun Jeong, Inho Lee, Sungjun Park, Bumjoon J. Kim, Iain McCulloch, Martin Heeney, Myung-Han Yoon
Summary: Organic mixed ionic-electronic conductors have great potential as implantable electrodes and active channels for circuit architectures. This study designs high-performance electrochemical diodes and elucidates the underlying mechanism and material requirements. The broad impact of organic electrochemical diodes is demonstrated.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Yazhou Wang, Anil Koklu, Yizhou Zhong, Tianrui Chang, Keying Guo, Chao Zhao, Tania Cecilia Hidalgo Castillo, Zhonggao Bu, Chengyi Xiao, Wan Yue, Wei Ma, Sahika Inal
Summary: This study demonstrates the synthesis of lactone-based n-type conjugated polymers using green aldol polymerization, which exhibit high performance in organic electrochemical transistors (OECTs) with high mobility-capacitance product, excellent mobility, low threshold voltage, and fast switching speed. The study also shows the applications of this n-type OECT in artificial synapse and detection of α-synuclein, a potential biomarker of Parkinson's disease. The research provides diverse form factors of devices for exploration in other application areas.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Ulrika Boda, Ioannis Petsagkourakis, Valerio Beni, Peter Andersson Ersman, Klas Tybrandt
Summary: The challenge of high-performance fully printed stretchable OECTs is addressed by developing fully screen-printed stretchable OECTs. Three stretchable functional screen-printing inks are developed, enabling the fabrication of OECTs. The stretchable OECTs show good characteristics and can withstand high strains. An electrochromic smart pixel is demonstrated by connecting a stretchable OECT to a stretchable electrochromic display. The development of screen-printed stretchable electrochemical devices, particularly OECTs, is believed to pave the way for their use in wearable applications and commercial products.
ADVANCED MATERIALS TECHNOLOGIES
(2023)
Article
Nanoscience & Nanotechnology
Junghyun Lee, Shrirang Chhatre, Peter Sitarik, Yuhang Wu, Quintin Baugh, David C. Martin
Summary: This study investigates the electrochemical fabrication and characterization of OECTs using PEDOT with different counterion salts. The results show that the characteristic dimensions of PEDOT films can be controlled by total charge density, and the choice of counterion affects the smoothness of the films.
ACS APPLIED MATERIALS & INTERFACES
(2022)