Article
Materials Science, Ceramics
Yulei Sui, Yueying Hao, Xiaoping Zhang, Jiangpeng Li, Gongyu Wen, Shengkui Zhong, Ziwei Zhang, Ling Wu
Summary: This study successfully synthesized V-substituted Na0.67Fe0.5Mn0.5O2 cathode material with improved electrochemical performance, and investigated the effects of V-substitution on its chemical composition, crystal structure and morphology, as well as the modification mechanisms on the enhanced electrochemical properties. The results showed that introducing V ions into the lattice of Na0.67Fe0.5Mn0.5O2 crystals significantly improved its rate capability and cycle stability, mainly due to the enhanced Na+ diffusion rate and structural reversibility.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Li-Feng Zhou, Xuan-Wen Gao, Tao Du, He Gong, Li-Ying Liu, Wen-Bin Luo
Summary: A novel phosphate ZnMn2(PO4)(2) coated by a thin carbon layer [ZnMn2(PO4)(2) @C] was synthesized and employed as cathode material for zinc ion batteries, showing excellent electrochemical performance with reversible specific capacity of 67 mA h g(-1) in aqueous system and 174 mA h g(-1) in nonaqueous system.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Electrochemistry
Jiajie Li, Quan Kuang, Gang Wang, Qiuchen Lu, Pan Jiang, Qinghua Fan, Youzhong Dong, Yanming Zhao
Summary: Expanding the selection of cathode materials is crucial for the development of aqueous zinc-ion batteries (AZIBs) to meet different application requirements. In this study, carbon-coated Na3Mn2(P2O7)(PO4) (NMPP@C) was synthesized using a liquid-phase method and freeze-drying process as an electrochemically active cathode material for AZIBs. After galvanostatic stimulation, the originally inactive NMPP@C cathode showed a peak capacity of 150 mAh g-1 and stabilized at 90 mAh g-1 with a discharge plateau at 1.45 V vs. Zn2+/Zn. The NMPP@C cathode underwent structural decomposition during the stimulation process, eventually generating alpha-MnO2 and Zn2P2O7·5H2O as electrochemical reaction agents.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Physical
Yujin Son, Dung The Nguyen, Youngil Lee
Summary: Fluorine-substituted LiFeBO3 with carbon coating (LFeBF/C) has been successfully demonstrated to enhance its electrochemical properties and stability in air, primarily due to the carbon layer promoting stability in air. The synergistic effects of fluorine substitution and carbon coating have been shown to improve the overall electrochemical performance.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Xiaoling Cui, Kuanyou Tuo, Hong Dong, Xiaolan Fu, Shimin Wang, Ningshuang Zhang, Liping Mao, Shiyou Li
Summary: The modification of phosphorus-doped carbon coating on LFMP improves electronic conductivity and ion transmission, forming a three-dimensional conductive channel and maintaining excellent electrochemical performance.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Multidisciplinary
Jie Feng, Shao-hua Luo, Jiachen Wang, Pengwei Li, Shengxue Yan, Junzhe Li, Peng-qing Hou, Qing Wang, Yahui Zhang, Xin Liu
Summary: In this study, a novel cobalt-free layered P2-type Na0.67Ni0.33Mn0.67O2 cathode material was designed and synthesized. The effect of Mg doping on the electrochemical performance and structural stability of the material was investigated, and it was found that Mg ion doping can effectively improve the electrochemical performance and structural stability of the material.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Article
Chemistry, Physical
Chengjie Yin, Jianhui Chen, Cheng-Ling Pan, Yusong Pan, Jinsong Hu
Summary: By using a carbon coating strategy, the performance of manganese oxide cathode in aqueous zinc-ion batteries has been successfully improved, achieving a higher specific capacity and satisfactory cyclic stability.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Materials Science, Ceramics
M. G. Moustafa, F. Elmasry
Summary: In this study, a developed In2O3-coated LiFePO4 cathode was successfully fabricated by the sol-gel technique. The electrochemical performance of the synthesized cathode was remarkably improved under the In2O3 coating layer, showing high discharge and charge capacities as well as enhanced coulombic efficiency. Furthermore, the cathode exhibited a high-capacity retention rate after multiple cycles.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2022)
Article
Chemistry, Physical
Yang Zhang, Can Cui, Jie Liu, Yiying Bei, Yingying Li, Zheng Song, Yaxin Feng, Heng Xu, Suhuan Tian, Ye Song, Fengsheng Li
Summary: This study introduces a strategy of co-modification with Nb doping and LiBO2 coating to improve the electrochemical performance of LiNixCoyMn1-x-yO2 (NCM) materials. Experimental results demonstrate that this co-modification method can effectively stabilize the internal structure, reduce cation mixing, and improve the cycling stability of the materials.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Wenyu Zhao, Qingquan Kong, Xiaoqiang Wu, Xuguang An, Jing Zhang, Xiaonan Liu, Weitang Yao
Summary: This study aims to improve the cathode of aqueous zinc-ion batteries (ZIBs) by coating epsilon-MnO2 with a carbon layer. The coating effectively mitigates Mn2+ dissolution and side reactions, resulting in a significant improvement in specific capacity and capacity retention.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Lingjiang Kou, Yong Wang, Jiajia Song, Taotao Ai, Koji Kajiyoshi, Panya Wattanapaphawong, Jintao Wang
Summary: Developing structurally controlled electrodes has gained attention due to the morphology's influence on electrochemical performance. Mn-decorated (NH4)(2)V10O25 center dot 8H(2)O materials with cauliflower-like, tremella-like, and purslane-like structures were synthesized. The materials with different morphologies displayed superior electrochemical performances as cathode materials for aqueous ZIBs. Tremella-like NVOH showed the highest rate capability of 159 mA h g(-1) at 500 mA g(-1) and long-term stability (85% retention after 500 cycles at 500 mA g(-1)). This study is significant for developing high-capacity and long-cycle-life cathode electrodes for practical rechargeable aqueous ZIBs.
REACTION CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Physical
Qiang Fu, Jiaqi Wang, Angelina Sarapulova, Lihua Zhu, Alexander Missyul, Edmund Welter, Xianlin Luo, Ziming Ding, Michael Knapp, Helmut Ehrenberg, Sonia Dsoke
Summary: The electrochemical performance and reaction mechanism of orthorhombic V2O5 in 1 M ZnSO4 aqueous electrolyte were studied. V2O5 nanowires showed an initial discharge and charge capacity at a current density of 50 mA g(-1), but experienced quick capacity fading during cycling. Interestingly, V2O5 demonstrated a higher discharge capacity at 200 mA g(-1) after 10 cycles, possibly due to different activation processes and degrees of side reactions under different current densities.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Physical
Jiawei Zheng, Jianwen Yang, Jinmei Wu, Shengxian Li, Mengwen Wang, Bin Huang, Yanwei Li, Shunhua Xiao, Qing Zhu
Summary: Cathode materials LiFe0.5Mn0.5-xYxPO4@C (x = 0, 0.005, 0.01, 0.02, and 0.03) were synthesized and characterized. Y3+ doping led to volume shrinkage, carbon coating, and improved particle size and dispersion. The preferred LiFe0.5Mn0.49Y0.01PO4@C sample exhibited enhanced electrochemical performance with decreased polarization and improved ion diffusion.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Electrochemistry
Anish Raj Kathribail, Arlavinda Rezqita, Daniel Lager, Raad Hamid, Yuri Surace, Maitane Berecibar, Joeri Van Mierlo, Annick Hubin, Marcus Jahn, Juergen Kahr
Summary: Coating conducting polymers onto active cathode materials has been shown to improve electrochemical performance and cycling stability, particularly in nickel-rich NMC622. The impact of heat treatment on the performance was studied systematically, with a heat treatment at 400 degrees C leading to enhanced reversibility and capacity retention, resulting in nearly 50% increase in discharge capacity for carbon coated NMC at 10C compared to uncoated samples. This study highlights the synergistic effects of a furfuryl polymer coating and subsequent calcination on improving the electrochemical performance of nickel-rich NMC622.
Article
Materials Science, Ceramics
Haili Sun, Zhiyi Li, Wei Wei, Fengxia Liu, Xiaofei Xu, Zhijun Liu
Summary: In this study, a pure-phase LiCoPO4 with core-shell structure was successfully synthesized by oleylamine-assisted ethanol solvothermal method. The LiCoPO4 prepared under the solvothermal reaction time of 12 h showed good crystallization properties and morphology characteristics, with a carbon layer thickness of about 6 nm on the surface. It exhibited the largest initial discharge capacity, best performance, and cycle stability among the tested samples.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Analytical
Fang Zhang, Wanfeng Li, Xingde Xiang, Molong Sun
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2017)
Article
Electrochemistry
Wanfeng Li, Fang Zhang, Xingde Xiang, Xiucheng Zhang
Article
Electrochemistry
Xin Wan, Kelu Liu, Ping Lei, Wenting Zheng, Xingde Xiang, Molong Sun
Article
Chemistry, Physical
Kelu Liu, Ping Lei, Xin Wan, Wenting Zheng, Xingde Xiang
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2018)
Article
Chemistry, Analytical
Dongxue Luo, Ping Lei, Yunxuan Huang, Guorong Tian, Xingde Xiang
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2019)
Article
Chemistry, Analytical
Ping Lei, Shujin Li, Dongxue Luo, Yunxuan Huang, Guorong Tian, Xingde Xiang
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2019)
Article
Energy & Fuels
Yunxuan Huang, Xin Wan, Dongxue Luo, Guorong Tian, Xingde Xiang, Molong Sun
Article
Chemistry, Physical
Dongxue Luo, Ping Lei, Guorong Tian, Yunxuan Huang, Xuefei Ren, Xingde Xiang
JOURNAL OF PHYSICAL CHEMISTRY C
(2020)
Article
Chemistry, Physical
Wenting Zheng, Ping Lei, Dongxue Luo, Yunxuan Huang, Guorong Tian, Xingde Xiang
SOLID STATE IONICS
(2020)
Article
Electrochemistry
Xiaochen Lin, Xuefei Ren, Lin Cong, Yue Liu, Xingde Xiang
Summary: A carbon-coated sodium vanadium/manganese phosphate was reported as an enhanced cathode for sodium-ion batteries, showing higher practical capacity and good cycling stability compared to traditional materials. The material underwent a reversible multi-electron reaction mechanism during sodium extraction/insertion process.
Article
Engineering, Chemical
Meiling Lu, Ting Li, Xiaoqiang Yang, Yue Liu, Xingde Xiang
Summary: A novel liquid-phase reaction strategy is reported to enhance the redox reversibility and cycling stability of carbon-coated NaTi2(PO4)(3) nanocrystals (C-NTP). The material exhibits a mesoporous carbon-coating structure and delivers outstanding electrochemical performance, including a high reversible capacity of 114.5 mAh·g(-1) at 100 mA·g(-1) and an impressive capacity retention of 82.1% after 1000 cycles at 1000 mA·g(-1). The enhanced redox reversibility and cycling stability are attributed to the unique carbon-coating structure that improves the material's reaction kinetics and structural stability.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Chemistry, Inorganic & Nuclear
Xin Wan, Dongxue Luo, Ping Lei, Yunxuan Huang, Xingde Xiang, Molong Sun
INORGANIC CHEMISTRY FRONTIERS
(2019)
Article
Chemistry, Multidisciplinary
Ping Lei, Kelu Liu, Xin Wan, Dongxue Luo, Xingde Xiang
CHEMICAL COMMUNICATIONS
(2019)
Review
Chemistry, Multidisciplinary
Xiang Xingde, Lu Yanying, Chen Jun
ACTA CHIMICA SINICA
(2017)