Journal
CATALYSTS
Volume 8, Issue 5, Pages -Publisher
MDPI
DOI: 10.3390/catal8050186
Keywords
dehydrogenation; Cu/Ni/Mg/Al; hydrotalcite; ortho-phenylphenol
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Funding
- National Natural Science Foundation of China [21676231]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Qing Lan of Yangzhou University
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A series of copper containing catalysts were prepared by calcination of Cu/Ni/Mg/Al hydrotalcite-like precursors, using the coprecipitation method. The materials were characterized and show a well-crystallized layered structure of hydrotalcite with smaller Cu-0 particles. We also studied their catalytic performance for conversion of 2-(1-cyclohexenyl) cyclohexanone into o-phenylphenol. The catalysts containing Ni showed higher catalytic activity; the optimum stability occurred when the Ni2+:(Ni2+ + Cu2+) atomic ratio was 0.4. The combination of Cu and Ni can greatly improve the stability and activities of the catalyst.
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