Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 6, Issue 31, Pages 15154-15161Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta05329d
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Funding
- National Science Foundation CAREER Award [DMR-1554918]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1554918] Funding Source: National Science Foundation
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We report the synthesis of a series of carbazole-triazine based donor-acceptor (D-A) POFs and their photocatalytic activities for aerobic oxidation reactions. The simultaneous introduction of a carbazole-based electron donor and a triazine-based electron acceptor in D-A POFs stabilizes the charge transfer state and enables an efficient triplet-triplet energy transfer to generate O-1(2). Meanwhile, systematic variation of the D-A distance results in the tunable photoredox properties and consequently the efficiency for generation of reactive oxygen species (ROSs). Upon visible light excitation, all three D-A POFs exhibit excellent capability to promote three aerobic oxidations: sulfide oxidation, oxidative amine coupling, and Mannich reactions. This systematic study validates the design principle of D-A POFs as high-performance photo-oxidation catalysts with wide substrate scope and excellent stability and recyclability.
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