Article
Nanoscience & Nanotechnology
Liqun Wang, Wenping Si, Yuhang Ye, Sihui Wang, Feng Hou, Xinggang Hou, Hongkun Cai, Shi Xue Dou, Ji Liang
Summary: The TiO2 nanotube array implanted with Cu ions and decorated with polymeric carbon nitride shows significantly improved performance in photoelectrochemical water splitting, thanks to the synergistic effect of Cu-ion implantation and PCN decoration.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Hojoong Choi, Sehun Seo, Chang Jae Yoon, Jae-Bin Ahn, Chan-Sol Kim, Yoonsung Jung, Yejoon Kim, Francesca Toma, Heejoo Kim, Sanghan Lee
Summary: Despite the achievements in the PEC performance of OHP-based photoelectrodes, scaling up from small-scale to large-scale systems remains a challenge due to resistive losses and intrinsic defects. This study suggests a scalable design for OHP-based PEC systems by modularization of optimized OHP photoelectrodes, achieving a high solar-to-hydrogen conversion efficiency of 10.4%. A proof-of-concept OHP module with 16 photoelectrodes achieves a photocurrent of 11.52 mA under natural sunlight without external bias, providing insights for the design of scalable OHP-based PEC systems for practical application and commercialization.
Article
Chemistry, Multidisciplinary
Sheng Ye, Wenwen Shi, Yong Liu, Dongfeng Li, Hang Yin, Haibo Chi, Yaling Luo, Na Ta, Fengtao Fan, Xiuli Wang, Can Li
Summary: This study achieved efficient unassisted overall water splitting by using a photoelectrochemical platform with multimediator modulation, increasing solar energy conversion efficiency. By assembling an integrated system composed of inorganic oxide-based photoanode and organic polymer-based photocathode, the efficiency of solar-to-hydrogen conversion was successfully improved.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Multidisciplinary
Chengming Zhang, Meng Wang, Kaiyue Gao, Haibao Zhu, Jie Ma, Xiaolong Fang, Xiufang Wang, Yi Ding
Summary: In this study, a novel strategy is developed to construct interfacial N-Cu-S bonds for efficient photoelectrochemical water splitting on SnS2 photoelectrodes. The results show that the interfacial bonds enhance oxygen evolution reaction kinetics, reduce surface overpotential, facilitate carrier separation, and provide a fast transmission channel for electrons.
Article
Chemistry, Multidisciplinary
Hongxia Qian, Zhifeng Liu, Zhengang Guo, Mengnan Ruan, Weiguo Yan
Summary: This study investigated the photoelectrochemical performance of ternary sulfide photoelectrodes with the same nanostructure and applied bidirectional p-n heterojunctions. The use of ZnIn2S4/CuInS2 and CuInS2/ZnIn2S4 as photoanode and photocathode in the unassisted tandem PEC cell device achieved a relatively high photocurrent density of 0.06 mA cm(-2), providing new ideas for the design and manufacture of high-efficiency unassisted tandem PEC cell devices.
CHEMICAL COMMUNICATIONS
(2021)
Article
Materials Science, Ceramics
Joao Victor Barbosa Moura, Antonio Amison Gomes de Souza, Paulo de Tarso Cavalcante Freire, Cleanio da Luz Lima, Thiago Mielle Brito Ferreira Oliveira
Summary: The study reported the structural, morphological, and optical characterization of sodium-cerium molybdate, highlighting its potential as a promising photoelectroactive material for water splitting. Experimental results showed significant photoelectroactivity of the material, with a remarkable increase in photocurrent density under irradiation. The material also exhibited high stability after on-off cycles, confirming its proper performance as a photoanode for water splitting.
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Luze Shen, Shicong Zhang, Haoran Ding, Fushuang Niu, Yanmeng Chu, Wenjun Wu, Yue Hu, Ke Hu, Jianli Hua
Summary: QAP-C8, a pure organic dye based on QA with octyl side chains as the donor and PDA as the acceptor, was successfully used in both the photoanode and photocathode of photoelectrochemical cells. A tandem device with QAP-C8 as the photosensitizer achieved overall water splitting without an external bias under neutral pH conditions, showing a STH of 0.11%.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Jihun Kang, Ki-Yong Yoon, Jae-Eun Lee, Juhyung Park, Sourav Chaule, Ji-Hyun Jang
Summary: For the first time, a simple in-situ phosphorus (P) doping strategy was used to improve the photoelectrochemical water splitting (PEC) performance of hematite. The introduction of FePO4 regions on the Ti-doped FeOOH surface and subsequent high-temperature annealing resulted in the fabrication of mesoporous P,Ti co-doped Fe2O3 nanorods. The resulting P,Ti-Fe2O3 photoanode exhibited significantly improved photo-current density, and with the deposition of the NiFeOx cocatalyst, it achieved excellent photocurrent density with a remarkable cathodic shift of the onset potential.
Article
Chemistry, Physical
David J. Lawrence, Brianna L. Smith, Cameron D. Collard, Keyton A. Elliott, Kyle L. Fakhoury, Jeffery D. Mangold, Anna N. Soyka
Summary: Monolithically-integrated tandem photoanodes were fabricated on substrates with epitaxial n-GaAs1-xPx grown on n(+)-GaAs wafers. Transparent, conducting SnO2:F provides protection and electrical connections for the PV cell, achieving unassisted solar water splitting with an efficiency approaching 2%.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Pan Wang, Zhifeng Liu, Dong Chen, Shaoce Zhang, Guozhen Fang, Changcun Han, Zhengwang Cheng, Zhengfu Tong
Summary: This study investigated the PEC performance of p and n-type Cu2O, exploring a dual-photoelectrode tandem PEC cell for the first time. By using electron capture and hole transfer layers, the photoelectrodes achieved better charge separation efficiency and faster charge transfer kinetics, leading to an unassisted photocurrent density of 0.09 mA/cm(2) after 1000 s of illumination. The research provides a novel platform for designing and fabricating various PEC energy conversion devices with excellent performance.
Article
Nanoscience & Nanotechnology
Svenja Baues, Heinrich Vocke, Lena Harms, Konstantin K. Ruecker, Michael Wark, Gunther Wittstock
Summary: Metal oxide libraries were generated for photoanodes for the oxygen evolution reaction (OER) through printing of metal salt solutions followed by calcination. The best performing composition was Cu48Ga3W49Ox. Characterization of the electrodes using various techniques was also conducted.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Chuanzhen Feng, Yu Wu, Yaling Fu, Huijuan Zhang, Yu Wang
Summary: This study proposes a gradient defect model confined in atomic layers to address the problem of severe recombination of photo-generated carriers in photoelectrochemical water splitting. By achieving bilateral gradient Cd doping in five-atomic-layer BiOI nanosheets, the energy levels are rearranged, resulting in distributed atomic homojunctions, which synergistically modulate carrier separation. The gradient Cd doping BiOI exhibits a charge separation efficiency of 78.1%, 12.0 and 7.9 times higher than pristine BiOI and uniform doping BiOI, respectively. Additionally, the record photocurrent density of 4.68 mA cm(-2) at 0 VRHE demonstrates the superior performance of the Cd-doped BiOI photocathode.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
S. R. Sitaaraman, Andrews Nirmala Grace, Raja Sellappan
Summary: In this study, a tandem cell consisting of a Mo-BiVO4/TiO2/FeOOH photoanode-Cu2O/TiO2/MoS2 photocathode was prepared for unassisted solar water splitting. The spin coated TiO2 protective layer demonstrated better stability and enhanced photoelectrochemical performance.
Article
Chemistry, Physical
Dipanjan Maity, Keshab Karmakar, Debashish Pal, Soham Saha, Gobinda Gopal Khan, Kalyan Mandal
Summary: This work presents a one-dimensional n-ZnO/p-ZnCo2O4 nanoheterojunction photoanode with enhanced PEC water splitting activity and solar light-harvesting performance. The p-ZnCo2O4 acts as both a catalyst for improving charge separation efficiency and an OER catalyst.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Energy & Fuels
Pan Wang, Zhifeng Liu, Changcun Han, Yongjin Zou, Zhengfu Tong, Baohua Tan
Summary: In this study, a reasonable, simple, and low-cost strategy was developed to enhance the photoelectrochemical performance of Cu2O by decorating it with Cu and Al layers. The Cu/Al layers exhibited surface plasmon resonance effect and combined the high conductivity of Cu with the ability of Al to form a thin Al2O3 layer, which hindered Fermi-level pinning and accelerated the transfer of photoinduced electron-hole pairs. The Cu/Al/Cu2O photocathode showed a significantly higher photocurrent density compared to pure Cu2O, indicating the effectiveness of bimetallic loading in improving PEC water splitting. This study inspires further exploration of novel and effective bimetallic catalysts.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Chemistry, Physical
Yubin Chen, Hongyu Xia, Wenshuai Zhang, Wenyu Zheng, Xiaoyang Feng, Jiangang Jiang
Summary: This study successfully synthesized a hierarchical CZTS film with porous nanostructures, which showed much higher PEC property for water splitting compared to the dense CZTS film. The three merits of the porous hierarchical morphology are enhanced light absorption, improved charge separation and transfer, and enlarged electrochemically active surface area.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Applied
Yubin Chen, Hongyu Xia, Xiaoyang Feng, Ya Liu, Wenyu Zheng, Lijing Ma, Rui Li
Summary: A cross-linked porous Ta3N5 film was prepared via a simple solution combustion route, resulting in enhanced PEC performance. Loading Co(OH)2 cocatalyst further improved photocurrent density and solar to hydrogen efficiency. The study provides a new strategy to design efficient Ta3N5 photoelectrodes by controlling morphology and composition simultaneously.
JOURNAL OF ENERGY CHEMISTRY
(2021)
Article
Energy & Fuels
Ya Liu, Dan Lei, Xiaoqi Guo, Tengfei Ma, Feng Wang, Yubin Chen
Summary: This study investigates the production of gas and liquid products in large-scale electrochemical cells using silver and indium as representative electrocatalysts. It finds that gas production is more prone to blockage when scaling up the electrochemical cell, while liquid products do not face such issues.
Review
Chemistry, Multidisciplinary
Ya Liu, Shengjie Bai, Feng Wang, Yubin Chen
Summary: Photoelectrochemical solar fuel generation technology has rapidly improved in the past decade, with a shift from single photoelectrodes to tandem photoelectrochemical cells. The focus is on photocathodes, photoanodes, protective layers, and cocatalysts, with strategies proposed for unassisted solar fuel generation.
ENVIRONMENTAL CHEMISTRY LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Jiazhe Wu, Wenyu Zheng, Yubin Chen
Summary: This article reviews the major discoveries and current understanding of photocatalysis. By analogy with electrocatalysis, a new definition of photocatalysis is proposed.
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Menglong Wang, Shuai Xu, Zhaohui Zhou, Chung-Li Dong, Xu Guo, Jeng-Lung Chen, Yu-Cheng Huang, Shaohua Shen, Yubin Chen, Liejin Guo, Clemens Burda
Summary: Single-atom nickel catalysts prepared on red phosphorus using a reactive-group guided strategy exhibit elevated hydrogen evolution rate under visible-light irradiation due to their specific Janus structure.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Wenyu Zheng, Ya Liu, Shengjie Bai, Haoran Qiu, Jiazhe Wu, Yubin Chen
Summary: The role of hydrogen spillover in pH- and potential-dependent hydrogen evolution over NiCu bimetal catalyst was investigated through simulation. The study found that hydrogen spillover significantly improved current density under neutral condition at specific voltage range. Furthermore, the potential and pH were shown to influence the effect of hydrogen spillover on current density by altering surface reaction rates. This understanding contributes to developing advanced electrocatalytic systems for hydrogen production.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
Fei Lv, Zhixiao Qin, Jiazhe Wu, Lixia Pan, Longjie Liu, Yubin Chen, Yixin Zhao
Summary: Solar water splitting by photovoltaic electrolysis is a promising method for sustainable hydrogen production, but it currently requires multiple PV cells connected in series to meet the practical voltage requirements, which increases system complexity and resistance. By introducing a redox mediator, it is possible to construct a decoupled water electrolyzer that requires lower driving voltages, enabling single PV cell-driven water electrolysis.
Article
Chemistry, Multidisciplinary
Xuewen Zheng, Fei Lv, Xuan Liu, Zhihao Zheng, Yubin Chen
Summary: By using the potassium ion battery material K0.5MnO2-Ti as a mediator, the H-2 and O-2 evolution in alkaline water electrolysis were effectively decoupled, achieving membrane-free pathway for H-2 production.
CHEMICAL COMMUNICATIONS
(2023)
Article
Engineering, Chemical
Menglong Wang, Shuai Xu, Zhichao Ge, Yuliang Li, Zhaohui Zhou, Yubin Chen
Summary: In this study, a solid-state Z-scheme photocatalytic system was constructed using carbon nitride, metallic NixP, and crystalline red phosphorus as the reduction sites, electron mediator, and oxidation sites respectively. The effective spatial separation of light-induced charges and the suitable energy band alignment enhanced the photocatalytic hydrogen production rate. Additionally, the generation of hydrogen peroxide instead of oxygen from water oxidation resolved the separation and safety issues, enabling the feasible application of photocatalytic hydrogen production.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Biotechnology & Applied Microbiology
Sahar Heidari, Lixia Pan, Jiazhe Wu, Longjie Liu, Wenshuai Zhang, Rui Li, Yubin Chen
Summary: This study investigates the influence of heat treatment on the performance of CZTS nanocrystal films for PEC water reduction. It is found that at low temperatures, the surfactant PVP in the films cannot be completely decomposed, leading to increased film resistance and hindered PEC process. At high temperatures, SnSx impurities are generated, which reduces the PEC performance. The best PEC water reduction activity is achieved at 385℃ for 10 minutes.
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
(2023)
Article
Chemistry, Physical
Jiazhe Wu, Xiaoya Xu, Xu Guo, Wensheng Xie, Lixia Pan, Yubin Chen
Summary: A polypyrrole (PPy) layer was coated on BiVO4 film to enhance carrier kinetics and improve the water oxidation property. The PPy layer elevated the temperature and acted as a charge transfer channel, leading to significantly improved performance.
JOURNAL OF CHEMICAL PHYSICS
(2023)
Article
Materials Science, Multidisciplinary
Zhichao Ge, Menglong Wang, Rui Li, Xiaodan Jin, Yubin Chen
Summary: Loading suitable cocatalysts can enhance photocatalytic activity by accelerating charge separation and facilitating interfacial redox reactions. In this study, MoP nanoparticles were synthesized and assembled with red phosphorus (RP) to construct the MoP/RP coupled photocatalyst. The composite photocatalyst achieved pure water splitting and showed enhanced hydrogen production activity under both full-arc and visible-light irradiation. The improved performance was attributed to the intimate contact between MoP and RP, which facilitated spatial separation of carriers and surface reactions. Moreover, the oxidation of water into H2O2 provided a value-added product and facilitated the separation of photocatalytic products for practical application.
Article
Engineering, Chemical
Menglong Wang, Shuai Xu, Zhichao Ge, Yuliang Li, Zhaohui Zhou, Yubin Chen
Summary: In this study, a solid-state Z-scheme photocatalytic system was built using carbon nitride (CN), metallic NixP, and crystalline red phosphorus (RP) as reduction sites, an electron mediator, and oxidation sites, respectively. The photocatalyst was capable of absorbing light up to 600 nm, enabling water splitting under broad-spectrum illumination. The effective spatial separation of light-induced charges, facilitated by the close contact between the NixP mediator and photocatalyst components as well as the suitable energy band alignment, significantly enhanced the photocatalytic hydrogen production rate. Additionally, the generation of hydrogen peroxide instead of oxygen from water oxidation addressed the separation and safety issues of synchronous hydrogen and oxygen production, promoting the practical application of photocatalytic hydrogen production.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Chemistry, Multidisciplinary
Jiazhe Wu, Fei Lv, Lixia Pan, Yubin Chen
Summary: This study presents a decoupled water electrolysis system that utilizes a proton exchange membrane electrolysis cell (PEMEC) for high-pressure H2 generation and an H-cell for low-pressure O2 generation. By employing a VO2+/VO2+ redox couple as the mediator, the system successfully produces high-pressure H2 without H2-O2 mixing at a pressure of 35 MPa. The research demonstrates the feasibility of the decoupled water electrolysis system for high-pressure H2 production by PEM water electrolysis.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)