Salicylate-Directed C−O Bond Cleavage: Iron-Catalyzed Allylic Substitution with Grignard Reagents

Cyclic ureas (DMI, DMPU) as efficient, sustainable ligands in iron-catalyzed C(sp2)–C(sp3) coupling of aryl chlorides and tosylates

(2017) Elwira Bisz et al.   GREEN CHEMISTRY

DFT and AFIR Study on the Mechanism and the Origin of Enantioselectivity in Iron-Catalyzed Cross-Coupling Reactions

(2017) Akhilesh K. Sharma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Nakamura’s Bisphosphine-Iron-Catalyzed Asymmetric C(sp2)–C(sp3) Cross-Coupling Reaction: The Role of Spin in Controlling Arylation Pathways

(2017) Wes Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild sp2Carbon–Oxygen Bond Activation by an Isolable Ruthenium(II) Bis(dinitrogen) Complex: Experiment and Theory

(2017) Samantha Lau et al.   ORGANOMETALLICS

Ester-directed Ru-catalyzed C–O activation/C–C coupling reaction of ortho-methoxy naphthoates with organoboroneopentylates

(2016) Yigang Zhao et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Remote C−H alkylation and C−C bond cleavage enabled by an in situ generated palladacycle

(2016) Juntao Ye et al.   Nature Chemistry

Iron-catalyzed allylic substitution reactions of allylic ethers with Grignard reagents

(2016) Longying Qi et al.   TETRAHEDRON LETTERS

Low-valent titanium-catalyzed deprotection of allyl- and propargyl-carbamates to amines

(2016) Suchithra Madhavan et al.   TETRAHEDRON LETTERS

Active Species and Mechanistic Pathways in Iron-Catalyzed C–C Bond-Forming Cross-Coupling Reactions

(2016) Carlo Cassani et al.   ACS Catalysis

Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

(2016) Alois Fürstner   ACS Central Science

Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Benzylic Ethers and Esters

(2015) Emily J. Tollefson et al.   ACCOUNTS OF CHEMICAL RESEARCH

How Low Does Iron Go? Chasing the Active Species in Fe-Catalyzed Cross-Coupling Reactions

(2015) Robin B. Bedford   ACCOUNTS OF CHEMICAL RESEARCH

Exploration of Earth-Abundant Transition Metals (Fe, Co, and Ni) as Catalysts in Unreactive Chemical Bond Activations

(2015) Bo Su et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cross-Couplings Using Aryl Ethers via C–O Bond Activation Enabled by Nickel Catalysts

(2015) Mamoru Tobisu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nickel-Catalyzed Allylic Alkylation with Diarylmethane Pronucleophiles: Reaction Development and Mechanistic Insights

(2015) Sheng-Chun Sha et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron Catalysis in Organic Synthesis

(2015) Ingmar Bauer et al.   CHEMICAL REVIEWS

Transition metal-catalyzed allylic substitution reactions with unactivated allylic substrates

(2015) Nicholas A. Butt et al.   CHEMICAL SOCIETY REVIEWS

On the Radical Nature of Iron-Catalyzed Cross-Coupling Reactions

(2015) Anna Hedström et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regio- and Chemoselective Kumada–Tamao–Corriu Reaction of Aryl Alkyl Ethers Catalyzed by Chromium Under Mild Conditions

(2015) Xuefeng Cong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

(2014) Josep Cornella et al.   CHEMICAL SOCIETY REVIEWS

Activation of Aryl and Heteroaryl Halides by an Iron(I) Complex Generated in the Reduction of [Fe(acac)3] by PhMgBr: Electron Transfer versus Oxidative Addition

(2014) Guillaume Lefèvre et al.   CHEMISTRY-A EUROPEAN JOURNAL

Beyond Directed ortho Metalation: Ru-Catalyzed CAr–O Activation/Cross-Coupling Reaction by Amide Chelation

(2014) Yigang Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-catalyzed/mediated oxidative transformation of C–H bonds

(2014) Fan Jia et al.   Organic Chemistry Frontiers

The Bidirectional Total Synthesis of Sampsonione P and Hyperibone I

(2013) Katharina Lindermayr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

X-ray Spectroscopic Verification of the Active Species in Iron-Catalyzed Cross-Coupling Reactions

(2013) Roland Schoch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Allylic Substitution for Construction of a Chiral Quaternary Carbon Possessing an Aryl Group

(2013) Chao Feng et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly practical iron-catalyzed C–O cleavage reactions

(2013) Dominik Gärtner et al.   Catalysis Science & Technology

Kumada–Tamao–Corriu cross-coupling reaction of O-based electrophiles with Grignard reagents via C–O bond activation

(2013) Wei-Na Li et al.   RSC Advances

Low Temperature Studies of Iron-Catalyzed Cross-Coupling of Alkyl Grignard Reagents with Aryl Electrophiles

(2012) Jonatan Kleimark et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition metal catalyzed nucleophilic allylic substitution: activation of allylic alcohols via π-allylic species

(2012) Basker Sundararaju et al.   CHEMICAL SOCIETY REVIEWS

Fe-Catalyzed Multicomponent Reactions: The Regioselective Alkoxy Allylation of Activated Olefins and its Application in Sequential Fe Catalysis

(2012) André P. Dieskau et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Progress in Nickel-Catalyzed Biaryl Coupling

(2012) Junichiro Yamaguchi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Allylic Alcohols: Sustainable Sources for Catalytic Enantioselective Alkylation Reactions

(2011) Marco Bandini   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Binuclear Fe-complexes as catalysts for the ligand-free regioselective allylic sulfenylation

(2011) Michael S. Holzwarth et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

(2011) Jimmie D. Weaver et al.   CHEMICAL REVIEWS

Iron-Catalyzed Coupling of Aryl Grignard Reagents with Alkyl Halides: A Competitive Hammett Study

(2011) Anna Hedström et al.   CHEMISTRY-A EUROPEAN JOURNAL

Activation of “Inert” Alkenyl/Aryl CO Bond and Its Application in Cross-Coupling Reactions

(2011) Bi-Jie Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Mild Ligand-Free Iron-Catalyzed Liberation of Alcohols from Allylcarbonates

(2011) André P. Dieskau et al.   ORGANIC LETTERS

Exploration of New C−O Electrophiles in Cross-Coupling Reactions

(2010) Da-Gang Yu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds

(2010) Brad M. Rosen et al.   CHEMICAL REVIEWS

Preformed π-Allyl Iron Complexes as Potent, Well-Defined Catalysts for the Allylic Substitution

(2009) Michael Holzwarth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coming of Age: Sustainable Iron-Catalyzed Cross-Coupling Reactions

(2009) Waldemar Maximilian Czaplik et al.   ChemSusChem

New General Method for Regio- and Stereoselective Allylic Substitution with Aryl and Alkenyl Coppers Derived from Grignard Reagents

(2009) Yohei Kiyotsuka et al.   JOURNAL OF ORGANIC CHEMISTRY

AllylicEthersas Educts for Suzuki−Miyaura Couplings in Water at Room Temperature

(2009) Takashi Nishikata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Promise and Challenge of Iron-Catalyzed Cross Coupling

(2008) Benjamin D. Sherry et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents

(2008) Syuzanna R. Harutyunyan et al.   CHEMICAL REVIEWS

Iron-catalysed carbon–heteroatom and heteroatom–heteroatom bond forming processes

(2008) Arkaitz Correa et al.   CHEMICAL SOCIETY REVIEWS

Picolinoxy Group, a New Leaving Group for anti SN2′ Selective Allylic Substitution with Aryl Anions Based on Grignard Reagents

(2008) Yohei Kiyotsuka et al.   ORGANIC LETTERS

Selective O-Deallylation of o-Allyloxyanisoles

(2008) Roberto Sanz et al.   SYNLETT

Ligand-Dependent Mechanistic Dichotomy in Iron-Catalyzed Allylic Substitutions: σ-Allyl versus π-Allyl Mechanism

(2007) Bernd Plietker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION