The Liebeskind-Srogl Cross-Coupling Reaction and its Synthetic Applications

C1′-Azacycloalkyl Hexahydrocannabinols

(2017) Thanh C. Ho et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Chemical Syntheses of the Furanosteroids (−)-Viridin and (−)-Viridiol

(2017) Matthew Del Bel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Copper-Promoted Hiyama-Type Carbon–­Carbon Cross-Coupling Reactions of Dihetaryl Disulfides as ­Electrophiles

(2017) Zheng-Jun Quan et al.   SYNLETT

A synthesis of biaryl ketones via the C–S bond cleavage of thiol ester by a Cu/Ag salt

(2017) Prasanjit Ghosh et al.   TETRAHEDRON LETTERS

Palladium-catalyzed C–S bond activation and functionalization of 3-sulfenylindoles and related electron-rich heteroarenes

(2017) Jianxiao Li et al.   Organic Chemistry Frontiers

Enantioselective Synthesis of (+)-Peganumine A

(2016) Cyril Piemontesi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrosulfurative C–N Cross-Coupling and Concomitant Oxidative Dehydrogenation for One-Step Synthesis of 2-Aryl(alkyl)aminopyrimidines from 3,4-Dihydropyrimidin-1H-2-thiones

(2016) Nguyen Huu Trong Phan et al.   ORGANIC LETTERS

Copper(I)-Promoted C–N Cross-Coupling of N-Heterocyclic Compounds with 1,2-Di(pyrimidin-2-yl) Disulfides

(2016) Zheng-Jun Quan et al.   SYNLETT

Sensing and discrimination of cyanide and hydrogen sulfide using an 8-alkenyl-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene derivative

(2016) E. Alvarado-Martínez et al.   RSC Advances

Chemo-Controlled Cross-Coupling of Di(hetero)aryl Disulfides with Grignard Reagents: CCvs.CS Bond Formation

(2015) Bao-Xin Du et al.   ADVANCED SYNTHESIS & CATALYSIS

Near-IR BODIPY Dyes à la Carte-Programmed Orthogonal Functionalization of Rationally Designed Building Blocks

(2015) Cesar F. A. Gómez-Durán et al.   CHEMISTRY-A EUROPEAN JOURNAL

New synthetic approach for the preparation of 2-aryl-thiazolo[4,5-b]pyridines via Liebeskind–Srogl reaction

(2015) Yang-Qiu Peng et al.   CHINESE CHEMICAL LETTERS

A Strategy for the Triarylation of Pyrrolo­pyrimidines by Using Microwave-Promoted Cross-Coupling Reactions

(2015) Vanessa Prieur et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Scope and Limitations of the Liebeskind–Srogl Cross-Coupling Reactions Involving the Biellmann BODIPY

(2015) Lourdes Betancourt-Mendiola et al.   JOURNAL OF ORGANIC CHEMISTRY

Liebeskind–Srogl cross-coupling on γ-carboxyl-γ-butyrolactone derivatives: application to the side chain of amphidinolides C and F

(2015) Johan Fenneteau et al.   TETRAHEDRON LETTERS

Wool-anchored Pd(OAc)2 complex: a highly active and reusable catalyst for desulfurative coupling reactions

(2015) Quanlu Yang et al.   Catalysis Science & Technology

Palladium-catalyzed desulfurative Sonogashira cross-coupling reaction of 3-cyano assisted thioamide-type quinolone derivatives with alkynes

(2015) You Wu et al.   RSC Advances

An efficient desulfitative C–C cross coupling of fused thiazolidine-2-thione with boronic acids and boronic acid pinacol esters: formation of fused thiazoles

(2015) Kandasamy Rajaguru et al.   RSC Advances

Chemoselective Carbon-Carbon Cross-CouplingviaPalladium-Catalyzed Copper-Mediated CS Cleavage of Disulfides

(2014) Zheng-Jun Quan et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Cholesterol Analogues Bearing BODIPY Fluorophores by Suzuki or Liebeskind-Srogl Cross-Coupling and Evaluation of Their Potential for Visualization of Cholesterol Pools

(2014) Zheng Liu et al.   CHEMBIOCHEM

A domino desulfurative coupling–acylation–hydration–Michael addition process for the synthesis of polysubstituted tetrahydro-4H-pyrido[1,2-a]pyrimidines

(2014) Zhong-Fei Yan et al.   CHEMICAL COMMUNICATIONS

Convenient Access to Carbohydrate-BODIPY Hybrids by Two Complementary Methods Involving One-Pot Assembly of “Clickable” BODIPY Dyes

(2014) Mayra R. Martinez-Gonzalez et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Soai Type 2-Arylpyrimidine-5-carbaldehydes through Desulfurative Cross-Coupling with Arylboronic Acids

(2014) Oleg V. Maltsev et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Chemoselective Synthesis of 4,5-Diarylpyrrolo[2,3-d]pyrimidines (6,7-Diaryl-7-deazapurines) by Consecutive Suzuki and Liebeskind-Srogl Cross-Couplings

(2014) Matouš Krömer et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Studies toward the Development of Antiproliferative Neoclerodanes from Salvinorin A

(2014) Tamara Vasiljevik et al.   JOURNAL OF NATURAL PRODUCTS

Synthesis of Soai Aldehydes for Asymmetric Autocatalysis by Desulfurative Cross-Coupling

(2014) Oleg V. Maltsev et al.   ORGANIC LETTERS

Peganumine A, a β-Carboline Dimer with a New Octacyclic Scaffold from Peganum harmala

(2014) Kai-Bo Wang et al.   ORGANIC LETTERS

Pd(0)-Catalyzed Cu(I)-Thiophene-2-carboxylate-mediated Cross-Coupling of Heteroaromatic Thioethers and Boronic Acids-First Liebeskind-Srogl Reaction in Water

(2013) Moumita Koley et al.   JOURNAL OF HETEROCYCLIC CHEMISTRY

Synthesis and Anticancer Activity of All Known (−)-Agelastatin Alkaloids

(2013) Sunkyu Han et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed C–S Activation for [3 + 3] Annulation of 2-(Methylthio)benzofuran-3-carboxylates and 2-Hydroxyphenylboronic Acids: Synthesis of Coumestan Derivatives

(2013) Jingxin Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis, structural characterization, and spectroscopic properties of theortho,meta, andparaisomers of 8-(HOCH2-C6H4)-BODIPY and 8-(MeOC6H4)-BODIPY

(2013) Robinson I. Roacho et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Direct C–H sulfenylation of purines and deazapurines

(2013) Martin Klečka et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Carbocyclization of unsaturated thioesters under palladium catalysis

(2013) Arun P. Thottumkara et al.   Chemical Science

Synthesis of nitrodienes, nitrostyrenes, and nitrobiaryls through palladium-catalyzed couplings of β-nitrovinyl and o-nitroaryl thioethers

(2013) Gardner S. Creech et al.   Chemical Science

A Domino Desulfitative Coupling/Acylation/Hydration Process Cocatalyzed by Copper(I) and Palladium(II): Synthesis of Highly Substituted and Functionalized Pyrimidines

(2012) Zheng-Jun Quan et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition-metal mediated carbon–sulfur bond activation and transformations

(2012) Liandi Wang et al.   CHEMICAL SOCIETY REVIEWS

Access and Regioselective Transformations of 6-Substituted 4-Aryl-2,8-dichloropyrido[3,2-d]pyrimidine Compounds

(2012) Gwenaelle Bouscary-Desforges et al.   JOURNAL OF ORGANIC CHEMISTRY

Theoretical Study on CuCl-Catalyzed Coupling of Thiol Esters with Organostannane

(2012) Lingjun Liu et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Preparation of Imides via the Palladium-Catalyzed Coupling Reaction of Organoborons with Methyl N-[Methoxy(methylthio)methylene]carbamate as a One-Carbon Elongation Reaction

(2012) Takuhei Tomizawa et al.   ORGANIC LETTERS

A General Regioselective Synthesis of 2,4-Diarylpyrimidines from 2- Thiouracil through Two Orthogonal Cross-Coupling Reactions

(2012) Michal Hocek et al.   SYNLETT

Optimized Liebeskind–Srogl coupling reaction between dihydropyrimidines and tributyltin compounds

(2012) Qi Sun et al.   TETRAHEDRON LETTERS

Selective Magnesiation or Zincation of Highly Functionalized Alkenes and Cycloalkenes Using 2,2,6,6-Tetramethylpiperidyl Bases

(2011) Tomke Bresser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Magical Power of Transition Metals: Past, Present, and Future (Nobel Lecture)

(2011) Ei-ichi Negishi   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross-Coupling Reactions Of Organoboranes: An Easy Way To Construct CC Bonds (Nobel Lecture)

(2011) Akira Suzuki   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Induction Arising from Enantiomerically Enriched Carbon-13 Isotopomers and Highly Sensitive Chiral Discrimination by Asymmetric Autocatalysis

(2011) Tsuneomi Kawasaki et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Pd2+ and Cu2+ catalyzed oxidative cross-coupling of mercaptoacetylenes and arylboronic acids

(2011) Adam Henke et al.   CHEMICAL COMMUNICATIONS

Aerobic, Cu-catalyzed desulfitative C–C bond-forming reaction of ketene dithioacetals/vinylogous thioesters and arylboronic acids

(2011) Ying Dong et al.   CHEMICAL COMMUNICATIONS

Activation of “Inert” Alkenyl/Aryl CO Bond and Its Application in Cross-Coupling Reactions

(2011) Bi-Jie Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselective Synthesis of 2,8-Disubstituted 4-Aminopyrido[3,2-d]pyrimidine-6-carboxylic Acid Methyl Ester Compounds

(2011) Gwenaelle Bouscary-Desforges et al.   JOURNAL OF ORGANIC CHEMISTRY

An Expeditious Route toward Pyrazine-Containing Nucleoside Analogues

(2011) Sachin G. Modha et al.   JOURNAL OF ORGANIC CHEMISTRY

Mobilizing Cu(I) for Carbon−Carbon Bond Forming Catalysis in the Presence of Thiolate. Chemical Mimicking of Metallothioneins

(2011) Zhihui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enigmol: A Novel Sphingolipid Analogue with Anticancer Activity against Cancer Cell Lines and In vivo Models for Intestinal and Prostate Cancer

(2011) H. Symolon et al.   MOLECULAR CANCER THERAPEUTICS

Regio- and Stereoselective Synthesis of Multisubstituted Olefins and Conjugate Dienes by Using α-Oxo Ketene Dithioacetals as the Building Blocks

(2011) Weiwei Jin et al.   ORGANIC LETTERS

The efficient synthesis of 2-arylpyrimidine acyclic nucleoside phosphonates using Liebeskind–Srogl cross-coupling reaction

(2011) Petra Břehová et al.   TETRAHEDRON

8-Alkenylborondipyrromethene dyes. General synthesis, optical properties, and preliminary study of their reactivity

(2011) Ismael J. Arroyo et al.   TETRAHEDRON

Synthesis of medium-sized carbocyclic ketones via the intramolecular B-alkyl Liebeskind–Srogl coupling reaction

(2011) Kazuhiro Tsuna et al.   TETRAHEDRON LETTERS

Novel Synthesis and Biological Evaluation of Enigmols as Therapeutic Agents for Treating Prostate Cancer

(2011) Ethel C. Garnier-Amblard et al.   ACS Medicinal Chemistry Letters

A concise summary of experimental facts about the Soai reaction

(2010) Timo Gehring et al.   CHIRALITY

AMP-Activated Protein Kinase (AMPK) Activation by Benzofurans and Coumestans Isolated fromErythrina abyssinica

(2010) Phi-Hung Nguyen et al.   JOURNAL OF NATURAL PRODUCTS

Desulfitative Cross-Coupling of Protecting Group-Free 2-Thiouracil Derivatives with Organostannanes

(2010) Qi Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Bisolefination of C−C Triple Bonds: A Facile Method for the Synthesis of Naphthalene Derivatives

(2010) Chao Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Liebeskind–Srogl cross coupling mediated synthesis of verbenachalcone

(2010) Srinivasa Reddy Dandepally et al.   TETRAHEDRON LETTERS

A Copper-Catalyzed, pH-Neutral Construction of High-Enantiopurity Peptidyl Ketones from PeptidicS-Acylthiosalicylamides in Air at Room Temperature

(2009) Lanny S. Liebeskind et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0)-Catalyzed, Copper(I)-Mediated Coupling of Cyclic Thioamides with Alkenylboronic Acids, Organostannanes, and Siloxanes

(2009) Nuzhat Arshad et al.   JOURNAL OF ORGANIC CHEMISTRY

Mild Room-Temperature Palladium-Catalyzed C3-Arylation of 2(1H)-Pyrazinones via a Desulfitative Kumada-Type Cross-Coupling Reaction†

(2009) Vaibhav P. Mehta et al.   JOURNAL OF ORGANIC CHEMISTRY

Novelmeso-Polyarylamine-BODIPY Hybrids: Synthesis and Study of Their Optical Properties

(2009) Erik Lager et al.   JOURNAL OF ORGANIC CHEMISTRY

Toward the Total Synthesis of Goniodomin A, An Actin-Targeting Marine Polyether Macrolide: Convergent Synthesis of the C15−C36 Segment

(2009) Tomoyuki Saito et al.   ORGANIC LETTERS

On the Mechanism of Palladium(0) Catalyzed, Copper(I) Carboxylate Mediated Thioorganic−Boronic Acid Desulfitative Coupling. A Noninnocent Role for the Carboxylate Ligand

(2009) Djamaladdin G. Musaev et al.   ORGANOMETALLICS

Palladium-Catalyzed Desulfitative CC Cross-Coupling Reaction of (Hetero)Aryl Thioesters and Thioethers with Arylsiloxanes

(2008) Vaibhav Pravinchandra Mehta et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed CC Coupling of Thiol Esters and Boronic Acids under Aerobic Conditions

(2008) Hana Prokopcová et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Liebeskind-Srogl CC Cross-Coupling Reaction

(2008) Hana Prokopcová et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

3- and 5-Functionalized BODIPYs via the Liebeskind-Srogl reaction

(2008) Junyan Han et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

The First Palladium-Catalyzed Desulfitative Sonogashira-Type Cross-Coupling of (Hetero)aryl Thioethers with Terminal Alkynes

(2008) Vaibhav Pravinchandra Mehta et al.   ORGANIC LETTERS

Synthesis of High Enantiopurity N-Protected α-Amino Ketones by Thiol Ester−Organostannane Cross-Coupling Using pH-Neutral Conditions

(2008) Hao Li et al.   ORGANIC LETTERS

Assignment of the Absolute Configuration of Goniodomin A by NMR Spectroscopy and Synthesis of Model Compounds

(2008) Yoshiyuki Takeda et al.   ORGANIC LETTERS