Thermal and Mechanical Behavior of New Transparent Thermoplastic Polyurethane Elastomers Derived from Cycloaliphatic Diisocyanate

New transparent thermoplastic polyurethane elastomers (TPURs) with the hard-segment content of 50 mass % were synthesized by one-step melt polyaddition of 1,1 0 -methanediylbis (4-isocyanatocyclohexane), 2,2 0 -methylenebis[(4,1-phenylene)-methylenesulfanediyl] diethanol (diol E), 3-hydroxy-2-(hydroxymethyl)-2-methylpropanoic acid (DMPA), a poly(oxytetramethylene) diol of Mn = 1000 g/ mol (PTMO), or a poly(hexametylene carbonate) diol of Mn = 860 g/ mol (PHCD). Herein, I prepared TPURs in which 20, 40, and 60 mol % of diol E was replaced with DMPA, an ionic chain extender. The structure of polymers was examined by ATR-FTIR. Their thermal and mechanical behaviorswere determined bymeans of thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamicmechanical thermal analysis (DMTA), tensile tests, and Shore A/ D hardness. Their optical properties are described. Generally, the addition of carboxyl groups to the polymer resulted in decreases in their thermal stability, transparency, and refractive indexes. Furthermore, the use of different soft segments revealed significant differences in bothmechanical and thermal properties of the polymers obtained.