Journal
SCIENTIFIC REPORTS
Volume 8, Issue -, Pages -Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/s41598-018-23927-w
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Funding
- National Natural Science Foundation of China [51771173, 21273199, 51131005, 21403194]
- Doctoral Research Foundation of Binzhou University [2017Y01]
- Major Project of Binzhou University [2017ZDL02]
- Scientific Research Fund of Binzhou University [BZXYZZJJ201604]
- National Training Programs of Innovation and Entrepreneurship [201710449016]
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The initial corrosion process of copper and the corrosion resistance mechanism of Benzotriazole under chloride-containing thin electrolyte layer (TEL) was investigated. After theoretical calculation and experimental characterization, the forming process of [Cu(I)BTA](n) film was chemically adsorbed on copper surface by Cu-N bond tightly; corrosion rate increased as TEL thickness decreased. Whilst, energy distribution plot of electrochemical noise provided the validity of corrosion type, and the purported corrosion energy (E-c) deduced from electrochemical noise was approximately proportion to corrosion rate (1/R-ct) with and without the anticorrosion film, which denoted the feasibility to determine corrosion rate by nondestructive on-line monitoring electrochemical noise progress.
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