4.6 Article

Self-Assembly of Free-Standing LiMn2O4-Graphene Flexible Film for High-Performance Rechargeable Hybrid Aqueous Battery

Journal

MATERIALS
Volume 11, Issue 7, Pages -

Publisher

MDPI
DOI: 10.3390/ma11071056

Keywords

LiMn2O4-graphene; flexible film; rechargeable hybrid aqueous batteries; electrochemical performance

Funding

  1. Natural Science Fund of Ankang University for high-level talents
  2. Subject Merging Fund of Ankang University for high-level talents [2016AYQDZR05, 2017AYJC01]
  3. Natural Science Fund of Education Department of Shaanxi Provincial Government [15JK1004]
  4. Natural Science Basic Research Plan in Shaanxi Province [2014JM2-2012]

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A novel LiMn2O4-graphene flexible film is successfully prepared by facile vacuum filtration technique.LiMn2O4 nanowires with diameters of 50-100 nm are distributed homogeneously on graphene sheet matrix. Used as cathode in rechargeable hybrid aqueous batteries, the LiMn2O4 -graphene film exhibits enhanced electrochemical performance in comparison to LiMn2O4-graphene powder. The LiMn2O4-graphene film shows stable 13.0 mAh g(-1) discharge capacity after 200 cycles at 1.0 C, benefitting from the presence of graphene with strong conductivity and large pore area in this free-standing film. This synthetic strategy for a free-standing film can provide a new avenue for other flexible materials and binder-free electrodes.

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