Journal
ACS CATALYSIS
Volume 8, Issue 2, Pages 1048-1051Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b04149
Keywords
hydrogenation; aldehydes; iron; pincer complexes; supported ionic liquid-phase
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Funding
- Austrian Science Fund (FWF) [M 2068-N28, P 28866-N34]
- Austrian Science Fund (FWF) [P28866, M2068] Funding Source: Austrian Science Fund (FWF)
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A base-tolerant supported ionic-liquid-phase (SILP) system containing a well-defined hydride Fe(II) PNP pincer complex has been prepared, structurally characterized, and used as catalyst in the hydrogenation of aldehydes to alcohols. The new SILP catalyst, with the optimum pore filling, was highly active exhibiting TONs and TOFs of up to 1000 and 4000 h(-1), respectively, under mild conditions (25 degrees C, 10-50 bar H-2 pressure) without significant leaching of both the complex and the IL.
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