Journal
SYNTHESIS-STUTTGART
Volume 50, Issue 16, Pages 3059-3086Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1610021
Keywords
furans; oxidation; rearrangement; natural products; total synthesis
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Funding
- Russian Science Foundation [17-73-10349]
- Russian Science Foundation [17-73-10349] Funding Source: Russian Science Foundation
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Recent developments on the transformations of furans under oxidative conditions toward the total synthesis of complex natural compounds are discussed. Reactions and methods are classified according to the type of oxidant used. Comparisons are then made between all the strategies to provide a comprehensive overview. This review covers the most prominent work published from 2011 until 2017. 1 Introduction 2 Reagents and Methods for Oxidation of the Furan Ring 2.1 Singlet Oxygen 2.2 Peroxides and Hydroperoxides 2.3 Quinones 2.4 Halogen-Based Oxidants 2.5 Chromium-Based Oxidants 3 The Achmatowicz Reaction 3.1 Halogen-Based Oxidants 3.2 Hydroperoxides 3.3 Enzymatic Oxidation 4 Conclusion
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