Journal
SOFT MATTER
Volume 14, Issue 22, Pages 4551-4557Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8sm00545a
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Funding
- Leopoldina Fellowship Programme, German National Academy of Sciences Leopoldina [LPDS 2017-02]
- Deutsche Forschungsgemeinschaft-CONICET [Mu1674/15-1]
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The preparation of nanoparticles and their targeted connection with other functional units is one key challenge in developing nanoscale devices. Herein, we report an experimental strategy toward the development of anisotropic nanoparticle architectures. Our approach is based on phase separation of binary mixed polymer brushes on gold nanoparticle surfaces leading to Janus-type structures, as revealed by scanning transmission electron microscopy and electron energy-loss spectroscopy and, additionally, corroborated by computer simulation. We show that such structures can be used for the site-selective functionalization with additional nanosized entities.
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