Article
Polymer Science
Mengyao Shang, Zhuyi Gao, Henglun Cheng, Chinan Wu, Baoqing Shentu
Summary: Thermal annealing was found to induce microstructure evolution and enhance properties of PBT/PP/CNTs nanocomposites. The volume resistivity was significantly reduced by seven orders of magnitude after annealing, leading to improved electrical conductivity. Additionally, the reconstructed CNTs networks during annealing contributed to enhanced flexural properties of the nanocomposites.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Polymer Science
Yang Zhang, Hao Xie, Xuan Zhang, Xianlong Zhang, Shaoyun Guo
Summary: This study investigated the selective distribution of fillers in multi-phase polymer blends for thermal management, showing that when BN fillers and polar dispersed phase were introduced into PE, a filler-coated shell was formed around the larger-sized dispersed phase, creating more thermal conductivity network. The thermal conductivity of PE/PA6/BN-two steps composites with 20 phr BN content was significantly higher than that of PE/PA6 composites, indicating the potential for improving the thermal conductivity of incompatible polymer blends through regulating the morphological structure of the dispersed phase.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Chunyue Hou, Junjie Wang, Peng Wang, Jiahui Cui, Shaojuan Wang, Rui Xin, Huihui Li, Xiaoli Sun, Zhongjie Ren, Shouke Yan
Summary: This study presents an epitaxy-directed self-assembly strategy that enables precise control over the pattern structures and crystal structures of copolymers and polymer blends by exploiting the specific crystallography registration between depositing crystalline polymers and underlying crystalline substrates.
Article
Chemistry, Multidisciplinary
Kui Wang, Xuefei Jin, Xiuhong He, Weijiang Huang, Qin Tian, Qiuping Fu, Wei Yan
Summary: Polymer blending has been widely used to fabricate polymeric films due to its superior properties. In this study, an aluminum phosphate-coated halloysite nanotube was fabricated and used to improve the performance of polyethylene oxide/poly(butylene adipate-co-terephthalate) blends. The mechanical and rheological properties of the films were systematically discussed.
Article
Polymer Science
Dong-Hua Xu, Fang Liu, Ge Pan, Zhi-Gang Zhao, Xue Yang, Heng-Chong Shi, Shi-Fang Luan
Summary: The study explored the effects of water on the structure and mechanical properties of TPU blends, observing both softening and hardening phenomena in wet samples compared to dry ones. The changes were attributed to alterations in the interface structure between hard and soft domains in TPU, involving plasticization of free water, weakening of original hydrogen bonds, and formation of new hydrogen bonds by carbonyl groups in TPU and water.
Article
Biochemistry & Molecular Biology
Satoshi Nogami, Kazunori Kadota, Hiromasa Uchiyama, Hiroshi Arima-Osonoi, Hiroki Iwase, Taiki Tominaga, Takeshi Yamada, Shin-ichi Takata, Mitsuhiro Shibayama, Yuichi Tozuka
Summary: The study investigated the thermal-and pH-dependent gelation behavior of gelatin/HPMCP blends using UV spectrophotometry, viscoelasticity, and DLS. Lisinopril release from the gels can be inhibited at low pH due to HPMCP aggregation. pH significantly affected the transparency of HPMCP systems and gelatin/HPMCP gels, with differences in viscoelastic patterns observed at different pH levels.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2021)
Article
Polymer Science
Vinicius M. Fraga, Isabela T. Lovi, Luis M. G. Abegao, Hugo J. N. P. D. Mello
Summary: The relationship between the sensitivity and correlation coefficient of potentiometric pH sensors and the structure-property relationship of polyaniline thin films was explored in this study. The effect of the deposition method on the sample's properties was evaluated. Galvanostatically electrodeposited films showed higher average sensitivity, 73.4 +/- 1.3 mV/pH, compared to spin-coated films, 59.2 +/- 2.5 mV/pH. The morphology and thickness of the electrodeposited films contributed to their higher sensitivity, while their oxidation state confirmed their sensing performance.
Article
Polymer Science
Christopher Ellingford, Paresh Kumar Samantaray, Stefano Farris, Tony McNally, Bowen Tan, Zhaoyang Sun, Weijie Huang, Yang Ji, Chaoying Wan
Summary: In this study, PGA was modified by blending with PBAT and EMA-GMA, resulting in improved mechanical properties, oxygen and water vapor barrier performance. The compatibilized PGA/PBAT blends with high thermal stability are suitable for high temperature or hot food packaging.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Thermodynamics
Dongmei Liu, Huifeng Bo, Ye Lin, Deyang Li, Zhanxin Zhang, Sijia Li
Summary: In this study, a DPD simulation was used to investigate the interfacial structure and tension of polymer blends with different copolymer chemical composition distributions. The results showed that the chain length of the diblock copolymer is the most important factor affecting the compatibilization efficiency, and the symmetric block copolymer AB is more effective in reducing the interfacial tension.
FLUID PHASE EQUILIBRIA
(2023)
Article
Polymer Science
Tatiana Ushakova, Elena Starchak, Vadim Krasheninnikov, Maxim Shcherbina, Sergey Gostev, Ludmila Novokshonova
Summary: The morphology and viscoelastic behavior of a wide range of in-reactor blends based on ultrahigh molecular weight polyethylene were investigated to understand the relationships between the structure and properties of polyolefin materials. Linear dependences of alpha-relaxation temperature on the lamella sizes in crystalline phase and beta-relaxation temperature on the density of butyl branches in copolymer fractions were found. The mechanisms of the processes of alpha- and beta-relaxations in the in-reactor blends with different microstructure polymer fractions were discussed.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Polymer Science
Ilhem Charfeddine, Jean-Charles Majeste, Christian Carrot, Olivier Lhost
Summary: This paper focuses on calculating the interfacial tension of two systems: low-density polyethylene with isotactic polypropylene and high-density polyethylene with syndiotactic polypropylene. Three methods are compared: Palierne's model, Gramespacher and Meissner's model, and ab-initio calculation, showing the effectiveness of the latter model for the studied systems.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Review
Engineering, Biomedical
Yu Zhao, Zhi Shou Zhu, Juan Guan, Su Jun Wu
Summary: Hydrogels are versatile materials in biomedical engineering with applications similar to wet tissues. Silk fibroin (SF) is a natural polymer with biocompatibility and tunable biodegradation, but its poor mechanical performance hinders its structural applications. Researchers are exploring strategies to enhance the strength of SF-based hydrogels for biomedical uses.
ACTA BIOMATERIALIA
(2021)
Article
Polymer Science
Jang-Gun Lee, Jin-Oh Jeong, Sung-In Jeong, Jong-Seok Park
Summary: Crosslinking of polyolefin-based polymers can improve their thermal and mechanical properties, and polymer blending can further enhance these properties, making the material suitable for various applications. In this study, HDPE/EVA/PU blends were prepared by radiation crosslinking to improve the thermal and mechanical properties of HDPE, demonstrating better thermal stability, strength, and abrasion resistance than non-crosslinked HDPE.
Article
Chemistry, Inorganic & Nuclear
Evgeny Gerber, Anna Yu. Romanchuk, Stephan Weiss, Stephen Bauters, Bianca Schacherl, Tonya Vitova, Rene Huebner, Salim Shams Aldin Azzam, Dirk Detollenaere, Dipanjan Banerjee, Sergei M. Butorin, Stepan N. Kalmykov, Kristina O. Kvashnina
Summary: Highly crystalline UO2 nanoparticles with sizes of 2-3 nm were produced by fast chemical deposition under reducing conditions. Despite being initially in U(IV) oxidation state, the nanoparticles oxidize to U4O9 over time and under X-ray beam. This oxidation process is accompanied by growth in size to 6 nm. The properties of UO2 nanoparticles are compared to PuO2, ThO2, and CeO2 nanoparticles in terms of both differences and similarities.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Multidisciplinary
Mostafa Ameen, Mohamed Elwageeh, Ahmed Abdelaziz, Stefano Bondua, Mohamed Elkarmoty
Summary: This paper investigates the relationship between Mode I fracture toughness (KIC) and rock brittleness using regression analysis. The results show that strength-based indices are good predictors of KIC, while elastic-based indices are not. The sensitivity of the correlation between KIC and strength-based indices to rock type and test method is also highlighted. A brittleness index that combines strength and pre-peak elastic parameters is found to be the best predictor of KIC.
APPLIED SCIENCES-BASEL
(2023)
Article
Chemistry, Physical
Zhixiang Li, Jieqing Shen, Lijun Ye, Kangyuan Xie, Jichun You, Yongjin Li
APPLIED SURFACE SCIENCE
(2019)
Article
Polymer Science
Qi Jiao, Jieqing Shen, Lijun Ye, Yongjin Li, Hualin Chen
Article
Nanoscience & Nanotechnology
Jie Liu, Lijun Ye, Sanghyuk Wooh, Michael Kappl, Werner Steffen, Hans-Juergen Butt
ACS APPLIED MATERIALS & INTERFACES
(2019)
Article
Chemistry, Multidisciplinary
Jennifer Schultze, Apostolos Vagias, Lijun Ye, Ephraim Prantl, Valentina Breising, Andreas Best, Kaloian Koynov, Carlos M. Marques, Hans-Juergen Butt
Article
Polymer Science
Lijun Ye, Fei Chen, Jie Liu, Aiting Gao, Gunnar Kircher, Wendong Liu, Michael Kappl, Seraphine Wegner, Hans-Juergen Butt, Werner Steffen
MACROMOLECULAR RAPID COMMUNICATIONS
(2019)
Article
Polymer Science
Kangyuan Xie, Jieqing Shen, Lijun Ye, Zhiyong Liu, Yongjin Li
Article
Chemistry, Multidisciplinary
Aiting Gao, Jie Liu, Lijun Ye, Clarissa Schoenecker, Michael Kappl, Hans-Juergen Butt, Werner Steffen
Article
Chemistry, Multidisciplinary
Jie Liu, Lijun Ye, Yuling Sun, Minghan Hu, Fei Chen, Seraphine Wegner, Volker Mailaender, Werner Steffen, Michael Kappl, Hans-Juergen Butt
ADVANCED MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Lijun Ye, Haichao Ji, Jie Liu, Chien-Hua Tu, Michael Kappl, Kaloian Koynov, Johannes Vogt, Hans-Juergen Butt
Summary: CNT-hydrogel composites are able to promote neuronal differentiation and maturation, while maintaining neuronal homeostasis and network activity.
ADVANCED MATERIALS
(2021)
Article
Materials Science, Composites
Huan Cao, Lijun Ye, Yucong Jin, Jiayao Wang, Jiahui Hong, Yongjin Li
Summary: This study investigates the effects of flow during injection molding on the structural development of thermally conductive networks in PP/FG composites, revealing the asymmetric response of fillers and the resulting discrepancy in thermal conductivity at different ends of the composite.
COMPOSITES SCIENCE AND TECHNOLOGY
(2022)
Article
Materials Science, Composites
Lijun Ye, Chenming Chen, Yixi Bian, Yongjin Li
Summary: In this study, a segregation structure was prepared in polymer composites derived from double-percolating structured polymer composites of two elastomers and CNTs. The segregated structure reduced the percolation threshold of CNTs while maintaining the stretchability of the elastomeric matrix. The composites exhibited improved sensitivity and a linear piezoresistive response under low mechanical strains, making them suitable for detecting gentle touching, dropping impact, and human body motions.
COMPOSITES SCIENCE AND TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Jie Liu, Yuling Sun, Rui Ma, Xiaoteng Zhou, Lijun Ye, Volker Mailaender, Werner Steffen, Michael Kappl, Hans-Jurgen Butt
Summary: Researchers have developed a superhydrophobic textile coated with a hybrid coating of titanium dioxide and polydimethylsiloxane, which exhibits low adhesion, excellent heat resistance, and flame-retardant properties.
Article
Chemistry, Physical
Jiahui Shi, Yuxin Ye, Ning Luo, Liang Zhang, Jiayao Wang, Taotao Lin, Jing Yang, Lijun Ye, Yongjin Li, Jichun You
Summary: Substrate-independent and robust coatings with desired functions are in high demand, but their fabrication and fundamental theory remain challenging due to conflicting requirements on surface free energy (SFE) at different interfaces. A novel strategy based on counterion exchange has been developed to tailor SFE continuously and reversibly. PVDF-g-IL coating with hierarchical surface roughness was fabricated and exhibited excellent bondability and robustness. Controlled counterion exchange was used to tune SFE at the top interface, enabling super-hydrophilic/super-hydrophobic properties and tunable adsorption at multiple interfaces.
APPLIED SURFACE SCIENCE
(2023)
Article
Materials Science, Composites
Yucong Jin, Lijun Ye, Yuchi Chai, Jiahui Hong, Yongjin Li
Summary: This study explored the possibility of tailoring the filler arrangement and through-plane thermal conductivity (A perpendicular to) of polymer composites with asymmetric fillers using nonconductive hollow glass microspheres (HG mu S). It was found that by replacing 3 wt% of flake graphite (FG) platelets with HG mu S, the A perpendicular to of ultrahigh-filled polyamide 6/FG composites increased by 27%. This increase was attributed to the reduced structural anisotropy of the FG network and a synergistic effect achieved by combining HG mu S and alumina microspheres.
COMPOSITES SCIENCE AND TECHNOLOGY
(2023)
Article
Polymer Science
Li-Jun Ye, Jie-Qing Shen, Kang-Yuan Xie, Zhi-Xiang Li, Yong-Jin Li
CHINESE JOURNAL OF POLYMER SCIENCE
(2018)
Article
Polymer Science
Yuanzhang Jiang, Xuyi Wang, Yanting Han, Dakai Gong, Yingchun Gu, Lin Tan
Summary: In this study, FeCl3 and poly(acrylic acid) (PAA) were doped into waterborne polyurethanes (WPUs) to create multifunctional materials with self-healing and antimicrobial properties. WPU/Fe/PAA-5.5, containing 5.5 wt % PAA, exhibited excellent mechanical properties, strong self-healing capabilities, and an impressive antimicrobial rate of over 90%. These supramolecular films were also highly recyclable through hot-pressing.
Article
Polymer Science
Longyu Tian, Min Wang, Guangming Liao, Baoliang Liu, Sujuan Zhang, Yucheng Sun, Zhen Meng, Jintao Zhang, Zaijun Lu
Summary: Two kinds of benzoxazine monomers were synthesized and used to prepare polybenzoxazine anion exchange membranes (AEMs) with quaternary ammonium functionalization. The LQPBZ AEM exhibited better ion conductivity and alkaline stability.
Article
Polymer Science
Claire A. Lemarchand
Summary: This study investigates the shock behavior of three different polymers through molecular dynamics simulations. The results reveal specificities in the shock behavior of polymers, including deviations from the linear relation between shock velocity and particle velocity, as well as differences in shear stress relaxation behind the shock front. It is found that the deviation of the Hugoniot locus is related to the change in the relative contribution of bonding and non-bonding potential energies, while polymers with higher glass transition temperatures exhibit slower shear stress relaxation.
Article
Polymer Science
Zengquan Liu, Xiaochun Yin, He Zhang, Shuo Gao, Qinglin Kuang, Yanhong Feng
Summary: A powder solid-state extension (PSSE) technology was proposed to address the high melt viscosity issue of UHMWPE. By uniaxial extension and sintering in the solid state, a highly self-reinforced material was prepared. X-ray diffraction and scattering techniques were used to study the structural evolution during the PSSE process, and a solid-phase induced transformation model was established.
Article
Polymer Science
Zhike Li, Anyu Luo, Rui Zhou, Xin Li, Haiyan Li
Summary: A novel high temperature resistance IL@SiO2 nanocapsules were successfully prepared and their friction and wear properties in PA6 composites were studied. The addition of IL@SiO2 nanocapsules reduced the friction coefficient and wear rate without affecting the mechanical properties of PA6. The synergy between the IL core and SiO2 wall in the nanocapsules improved the self-lubricating performance of the PA6 composites.
Article
Polymer Science
Xin Liu, Xuhong Guo, Qi Liao
Summary: In this study, an algorithm for accurately estimating viscosity is developed using molecular dynamics simulations and the Green-Kubo formula. This algorithm can be applied to complex systems with long correlations, such as macromolecular and biological simulation systems.
Article
Polymer Science
Hao Pu, Yun-Lei Hou, Jing -Zhou Chen, Dong -Lin Zhao
Summary: The use of modified graphene improves the interfacial adherence of carbon fibers to epoxy resin, resulting in enhanced interfacial and bending properties of CF and matrix in CF/EP composites, as well as increased interlaminar shear strength and flexural strength.
Article
Polymer Science
Wei-Chung Ke, Jin-Wei Lin, Manohar Reddy Busireddy, Yueh-Hsing Lee, Jiun-Tai Chen, Chain-Shu Hsu
Summary: This study introduces a crosslinkable monomer, TAIC, to synthesize three crosslinked polyimide films, which exhibit improved thermal, mechanical, and dielectric properties. The introduction of TAIC enhances the tensile strength, reduces the dielectric constant and dielectric loss, and decreases the coefficient of thermal expansion of the polyimide films.
Article
Polymer Science
Alex Kwasi Kumi, Ruiling Fan, Ye Chen, Yumei Zhang
Summary: The difference in leaching of amylopectin from cellulose/amylopectin/1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) blends during regeneration in water and aqueous ethanol has been studied. Molecular dynamics simulations showed that the dissolution and regeneration mechanisms of amylopectin in [Bmim][Cl] are similar to cellulose in ionic liquids. Water regeneration leads to weak electrostatic interactions, resulting in high leaching of amylopectin. In contrast, ethanol-water interactions enhance electrostatic interactions among amylopectin chains, limiting amylopectin leaching in aqueous ethanol.
Article
Polymer Science
Xi Zeng, Junwei Zhou, Junbiao Peng, Chunsheng Zhang, Danling Wang, Yihu Song, Qiang Zheng
Summary: This study utilizes an oligomer deep eutectic solvent (DES) based on polyethylene glycol to regulate the vulcanization kinetics of rubber. The results show that the DES can accelerate vulcanization at low temperatures without affecting the crosslinking density and Mullins effect.
Article
Polymer Science
Qianqian Yue, Yongfei Peng, Xingjian Liu, Aihua He, Huarong Nie
Summary: The addition of metal deactivators can effectively suppress the aging of TBIR, prolong its lifespan, and have no negative effects on its physical and processing properties. These research findings are of great importance for improving the stability and aging resistance of polymers.
Article
Polymer Science
J. Gomez-Caturla, J. Ivorra-Martinez, R. Tejada-Oliveros, V Moreno, D. Garcia-Garcia, R. Balart
Summary: This work focuses on the development of environmentally friendly PLA formulations by using different esters derived from geraniol as plasticizers. The results show that these esters have good compatibility with PLA, and they can effectively enhance the elongation and plasticity of PLA, reduce its glass transition temperature, and slightly improve its water absorption capabilities.
Article
Polymer Science
Dandan Li, Zhaohui Lu, Zhao Ke, Ke Xu, Fengna Dai, Youhai Yu, Guangtao Qian, Chunhai Chen
Summary: In this study, cross-linked PI aerogel membranes with low dielectric constant and high moisture resistance were prepared by co-polymerization and scraping coating technology. The incorporation of fluorinated blocks and benzimidazole ring structures resulted in novel PI aerogel membranes with fascinating dielectric properties and outstanding moisture resistance.
Article
Polymer Science
Zhaoyang Chu, Qing Zhang, Haihua Luo, Han Zhou, Fapei Zhang, Wei Chen, Wenhua Zhang
Summary: Multi-physical fields solution processing strategy is a universal and facile method for preparing various conjugated polymer films and high-performance devices. In this study, we employed a combined microfluidic flow and ultrasonication strategy (FU) for processing CP solutions, and found a pronounced synergetic effect in promoting the pre-ordering of chains in solution. The conformation order and anisotropy of the solution were revealed through various characterizations. A non-classical nucleation model for polymer crystallization in non-equilibrium solution processing was confirmed. The roles of microfluidic flow and ultrasonication in chain aggregation and crystallization were addressed through multi-physical simulations. Compared to pristine solutions, the FU strategy showed improved solution anisotropy and crystallization kinetics, resulting in higher crystallinity in films and increased mobilities in OFET devices. The FU processing strategy provides a universal approach for regulating chain conformation and aggregation in conjugated polymer solutions.