Article
Materials Science, Multidisciplinary
Takashi Tayama, Tatsuma D. Matsuda, Ryuji Higashinaka, Yuji Aoki
Summary: The Ising magnet SmPt2Si2 exhibits a variety of intriguing magnetic phenomena at low temperatures, including the presence of partially disordered ions, coexistence of cluster spin glass state with antiferromagnetic long-range order, and the absence of remanent magnetization in the isothermal magnetization process at 0.26 K.
Article
Chemistry, Multidisciplinary
Stefan Kraus, Alexander Herman, Felix Huttmann, Christian Kramer, Konstantin Amsharov, Shigeru Tsukamoto, Heiko Wende, Nicolae Atodiresei, Thomas Michely
Summary: The on-surface synthesis of the eight-membered sp(2) carbon-based ring cyclooctatetraene (C8H8, Cot) with ytterbium and thulium on graphene yields different products for the two lanthanides. Ytterbium synthesis results in long YbCot wires, while thulium synthesis produces repulsively interacting TmCot dots. The outcome of the reaction can be controlled by tuning the electron chemical potential in graphene.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Crystallography
Judith K. Clark, Chongin Pak, Huibo Cao, Michael Shatruk
Summary: MnBi2Se4 is a linear-chain antiferromagnet with dominant intrachain antiferromagnetic interactions, leading to spin frustration and antiferromagnetic ordering at 15 K due to interchain coupling. The antiferromagnetic ordered state exhibits an incommensurate helimagnetic structure with perpendicular Mn moments arranged in the chain propagation direction and a helix turn angle of 128 degrees. The magnetic properties of MnBi2Se4 are discussed in comparison to other linear-chain antiferromagnets based on ternary mixed-metal halides and chalcogenides.
Article
Chemistry, Physical
Xiang-Lin Huang, Sz-Chian Liou, Tan-Ju Yang, Hsin-An Chen, Hsiao-Wen Chen, Hsiang-Lin Liu, Wei-Tin Chen, Guo-Jiun Shu
Summary: Photocatalysis is a potential solution to energy shortage and greenhouse effect. CuFeO2 (CFO) is a material with a Delafossite structure and has been studied extensively. In this study, we successfully grew high-quality CFO single crystals using the optical floating-zone technique. CFO has a narrow band gap, high charge carrier mobility, and electrochemical stability. The magnetic phase transition and magnetic entropy change of CFO were also investigated.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
Hui Shen, Qingyuan Wu, Sami Malola, Ying-Zi Han, Zhen Xu, Ruixuan Qin, Xiongkai Tang, Yang-Bo Chen, Boon K. Teo, Hannu Hakkinen, Nanfeng Zheng
Summary: By studying the structure and surface modification of gold catalysts, we have discovered that the synergistic effect between the metallic core and the surface organometallic motifs can enhance catalytic reactions, bridging the gap between heterogeneous and homogeneous metal catalysis.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Nicolas Chrysochos, Christos P. Constantinides, Gregory M. Leitus, Andreas Kourtellaris, Daniel B. Lawson, Merce Deumal, Jordi Ribas-Arino, Maria Angels Carvajal, Georgia A. Zissimou, Constantinos Nicolaides, Theodossis Trypiniotis, Panayiotis A. Koutentis
Summary: 1,3-Diphenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl-6,7-dicarbonitrile is a stable electron-deficient organic radical that can be used as a building block in electronic and spintronic materials. Two polymorphs were identified, and one of them exhibits strong antiferromagnetic interactions.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Materials Science, Multidisciplinary
Preetha Saha, Depei Zhang, Seung-Hun Lee, Gia-Wei Chern
Summary: The study investigates the spin dynamics in a geometrically constrained kagome bilayer, analyzing the effects of thermal and dilution on the dynamical structure and discussing implications for glassy behaviors. The cooperative paramagnetic phase and magnon excitations are dominant in the low-frequency and long-wavelength dynamics, with a two-population picture providing understanding for the diluted system's properties. The presence of spin vacancies drives spin diffusion through zero-energy weather-vane modes, leading to exponential decay in autocorrelation, while diffusive dynamics of quasifree orphan spins exhibit longer-time power-law tails in the autocorrelation function.
Article
Chemistry, Multidisciplinary
Shuangyu Wu, Bowen Qin, Yaling Zhao, Xiaoying Zhang, Jingping Zhang
Summary: Five new nuclear coordination complexes based on a 2-hydroxymethylpyridine ligand have been synthesized, showing different structures and cluster alignments. By changing the metal source and solvent ratios, the magnetic properties of the complexes also vary from antiferromagnetic to weak ferromagnetic interactions.
CRYSTAL GROWTH & DESIGN
(2021)
Article
Chemistry, Inorganic & Nuclear
Dibya Jyoti Mondal, Arpan Mondal, Abhik Paul, Sanjit Konar
Summary: In this work, the authors demonstrate the experimental approach of tuning the spin-crossover (SCO) behavior in 2D Hofmann coordination polymers by controlling the spin-state cooperativity. The removal of solvent changes the spin-transition mechanism and enhances the hysteresis width. Structural analysis reveals changes in the crystal system, and the increased ligand-field strength and face-to-face interactions after desolvation are reflected in the highly cooperative SCO.
INORGANIC CHEMISTRY
(2022)
Article
Multidisciplinary Sciences
Xiaoyu Zhang, Ayhan Duzgun, Yuyang Lao, Shayaan Subzwari, Nicholas S. Bingham, Joseph Sklenar, Hilal Saglam, Justin Ramberger, Joseph T. Batley, Justin D. Watts, Daniel Bromley, Rajesh Chopdekar, Liam O'Brien, Chris Leighton, Cristiano Nisoli, Peter Schiffer
Summary: The study demonstrates that Boltzmann-distributed strings of local excitations can describe the topological physics of the Santa Fe geometry, which shows strong correlations and applies to classical systems. Experimental results show that the string length follows a simple Boltzmann distribution with an energy scale related to magnetic interactions and consistent with theoretical predictions.
NATURE COMMUNICATIONS
(2021)
Article
Biochemistry & Molecular Biology
Isabel Castro, M. Luisa Calatayud, Marta Orts-Arroyo, Nicolas Moliner, Nadia Marino, Francesc Lloret, Rafael Ruiz-Garcia, Giovanni De Munno, Miguel Julve
Summary: Two novel copper(II) complexes were synthesized using different ligands and oxalate as the polyatomic inverse coordination center. The magnetic properties of the complexes were investigated, revealing weak intrachain antiferromagnetic interactions in one complex and a combination of weak intramolecular ferromagnetic and strong antiferromagnetic couplings in the other. The distinct variations in magnetic coupling behavior are attributed to the different structural features of the complexes.
Article
Chemistry, Physical
Logesh Mathivathanan, Yiannis Sanakis, Raphael G. Raptis, Philippe Turek, Athanassios K. Boudalis
Summary: A 16-line pattern for the EPR spectrum has been predicted theoretically and studied in a triangular Cu-II species, revealing the impact of Dzyaloshinskii-Moriya interactions (DMI). The study also deconvolutes two slightly different cocrystallized magnetic species for the first time in this context.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Article
Chemistry, Inorganic & Nuclear
Qingbing Yuan, Zeming Huang, Weikang Wu, Dongjing Hong, Shan Zhu, Jieding Wei, Shuangliu Zhou, Shaowu Wang
Summary: Novel tetranuclear organocopper(I) clusters with excellent catalytic activities have been synthesized through reactions between Cu(I) halides and lithiated ligands. The structures of these clusters are stabilized by multiple Cu-Cu interactions, with halide anions bridged to the metal centers.
DALTON TRANSACTIONS
(2022)
Article
Materials Science, Multidisciplinary
E. Z. Zhang, Y. C. Deng, X. H. Liu, X. Z. Zhan, T. Zhu, K. Y. Wang
Summary: The study shows that the antiferromagnetic interfacial states can be effectively manipulated through SOT when the thickness of Ir-Mn or Co exceeds 4nm, leading to gradual switching of spins; additionally, in the Pt/Co/Ru/Ir-Mn system, the exchange coupling between Co and Ir-Mn can be influenced by the thickness of the Ru layer.
Article
Materials Science, Multidisciplinary
Lei Qiu, Ka Shen
Summary: In this paper, the properties of spin waves propagating within magnetic domain walls in a synthetic antiferromagnetic bilayer structure are investigated by micromagnetic simulation. The results demonstrate a giant nonreciprocity in frequency, which can be efficiently controlled by an external magnetic field in terms of both magnitude and sign. The unidirectional excitation of hybridized domain-wall spin waves by a nanostripline antenna is also demonstrated.
Article
Chemistry, Multidisciplinary
Michela Romanini, YiXu Wang, Kubra Gurpinar, Gladys Ornelas, Pol Lloveras, Yan Zhang, Wenkai Zheng, Maria Barrio, Araceli Aznar, Adria Gracia-Condal, Baris Emre, Orhan Atakol, Catalin Popescu, Hu Zhang, Yi Long, Luis Balicas, Josep Lluis Tamarit, Antoni Planes, Michael Shatruk, Lluis Manosa
Summary: The research reports a giant barocaloric effect in a molecular material FBT, with a transition metal complex switching between high-spin and low-spin states. The material shows high susceptibility to pressure and a large barocaloric effect, with high values of isothermal entropy change and adiabatic temperature change.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Inorganic & Nuclear
Sebastian A. Stoian, Mahsa Moshari, Eleftherios Ferentinos, Alexios Grigoropoulos, J. Krzystek, Joshua Telser, Panayotis Kyritsis
Summary: In this study, the electronic structures of two pseudotetrahedral Fe-II complexes were assessed using high-frequency EPR and Mossbauer spectroscopies. The analysis revealed a S = 2 ground state with predominant d(x2-y2) character in the orbital ground states. Theoretical analysis suggested that ligand spin-orbit coupling plays a marginal role, while d(x2-y2)(β) -> d(xy)(β) excitations have a dominant impact on the zero-field splitting (zfs) parameters of both complexes. Furthermore, differences in zfs between the two complexes were attributed to the energies of d(x2-y2)(β) -> d(xz)(β) transitions.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Miguel Gakiya-Teruya, Xuanyuan Jiang, Duy Le, Okten Ungor, Abdullah J. Durrani, John J. Koptur-Palenchar, Jun Jiang, Tao Jiang, Mark W. Meisel, Hai-Ping Cheng, Xiao-Guang Zhang, Xiao-Xiao Zhang, Talat S. Rahman, Arthur F. Hebard, Michael Shatruk
Summary: The mononuclear complex exhibits a hysteretic spin transition and light-induced excited spinstate trapping at lower temperatures, despite being readily sublimable due to its asymmetric molecular shape. This behavior is attributed to the efficient design strategy of asymmetric molecular shapes in achieving sublimable complexes with strongly cooperative spin transitions.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Materials Science, Multidisciplinary
S. Sharma, A. E. Kovalev, D. J. Rebar, D. Mann, V Yannello, M. Shatruk, A. Suslov, J. H. Smith, T. Siegrist
Summary: This study investigated the magnetostriction of polycrystalline AlFe2B2 using an x-ray diffraction instrument, revealing an anisotropic change in lattice parameters with magnetic field variation. The volume magnetostriction was found to decrease with decreasing temperature and change sign at the Curie temperature. The experimental results were consistent with density functional theory calculations and a simplified Landau model for magnetostriction.
PHYSICAL REVIEW MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Thilini K. Ekanayaka, Ping Wang, Saeed Yazdani, Jared Paul Phillips, Esha Mishra, Ashley S. Dale, Alpha T. N'Diaye, Christoph Klewe, Padraic Shafer, John Freeland, Robert Streubel, James Paris Wampler, Vivien Zapf, Ruihua Cheng, Michael Shatruk, Peter A. Dowben
Summary: The [Co(SQ)(2)(4-CN-py)(2)] complex shows dynamic effects at various temperatures, with the orbital moment exhibiting a nonzero critical field for net alignment of magnetic moments, in contrast to the spin moment behavior.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Eranga H. Gamage, Judith K. Clark, Maher Yazback, Hai-Ping Cheng, Michael Shatruk, Kirill Kovnir
Summary: A novel transition metal chalcohalide with a complex structure and strong antiferromagnetic interactions has been synthesized, serving as a key component for the synthesis of magnetically frustrated systems.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Physical
Luis A. Saucedo, Judith K. Clark, J. S. Raaj Vellore Winfred, Geoffrey F. Strouse, Michael Shatruk
Summary: The influence of Cu doping on the structural and magnetic properties of Fe3Se4 ferrimagnet was investigated, and it was found that Cu doping can significantly increase the coercivity of the material, although only a limited amount of Cu entered the Fe3Se4 structure. Samples prepared by solvothermal method showed higher lattice strain compared to those prepared by high-temperature annealing, leading to larger coercive fields.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Physics, Applied
Juan Macy, Danilo Ratkovski, Purnima P. Balakrishnan, Mara Strungaru, Yu-Che Chiu, Aikaterini Flessa Savvidou, Alex Moon, Wenkai Zheng, Ashley Weiland, Gregory T. McCandless, Julia Y. Chan, Govind S. Kumar, Michael Shatruk, Alexander J. Grutter, Julie A. Borchers, William D. Ratcliff, Eun Sang Choi, Elton J. G. Santos, Luis Balicas
Summary: The anomalous Hall and thermal Hall coefficients of the itinerant ferromagnet Fe3-xGeTe2 show anomalies consistent with a topological transition that may deviate from the Wiedemann-Franz law. However, within the experimental accuracy, these coefficients are found to satisfy the WF law under specific conditions. Chiral spin structures associated with Bloch domain walls are proposed to lead to a novel type of topological transport in the absence of interaction between magnetic field and electrical or thermal currents.
APPLIED PHYSICS REVIEWS
(2021)
Article
Nanoscience & Nanotechnology
Dallas K. Mann, Aida M. Diez, Junyuan Xu, Oleg I. Lebedev, Yury V. Kolen'ko, Michael Shatruk
Summary: This study investigates LaCo2P2 as an electrocatalytic material for oxygen evolution reaction (OER) under alkaline and acidic conditions. The results show that LaCo2P2 exhibits good electrocatalytic performance and stability under alkaline conditions, but deteriorates rapidly under acidic conditions.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Inorganic & Nuclear
Zachary P. Tener, Vincent Yannello, V. Ovidiu Garlea, Saul H. Lapidus, Philip Yox, Kirill Kovnir, Sebastian A. Stoian, Michael Shatruk
Summary: This study focuses on the synthesis and properties of a series of CuFe2-xCoxGe2 solid solutions. With the increase of Co content, the unit cell volume decreases in an anisotropic manner, and has an influence on the magnetic behavior.
INORGANIC CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Govind Sasi Kumar, Yan Xin, J. S. Raaj Vellore Winfred, Judith K. Clark, Michael Shatruk
Summary: In this study, we successfully exfoliated bulk layered-structure semiconductor MnIn2Se4 to nanoscale thick sheets using liquid-phase exfoliation method. The nanosheets obtained have controlled thickness in the range of tens of nanometers. Compared to the bulk material, the photoluminescence properties and magnetic behavior of the nanosheets have shown changes. These results indicate the potential of liquid-phase exfoliation technique for van-der-Waals materials with several-atom-thick layers.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Inorganic & Nuclear
Mousumi Dutta, Shubham Bisht, Prabir Ghosh, Alexandra Ioana Chilug, Dallas Mann, Cristian Enachescu, Michael Shatruk, Pradip Chakraborty
Summary: Structural studies have been conducted on dehydrated coordination networks to investigate the high-symmetry cubic structure and spin-crossover behavior of the [NixCo1-x(bpy)(3)][LiCr(ox)(3)] series.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Zheng Zhou, Zheng Wei, Xuelin Yao, Xiao-Ye Wang, Klaus Muellen, Minyoung Jo, Michael Shatruk, Marina A. Petrukhina
Summary: Discotic polycyclic aromatics have been chemically reduced to afford triply reduced HBC-based products, which have been structurally characterized. The presence of potassium ions binding to the central rings of HBC core is confirmed, and the coordination and crystal packing are affected by the bulky substituents. The magnetic properties of the triradical in the solid state have also been investigated.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Chemistry, Multidisciplinary
Okten Ungor, Eun Sang Choi, Michael Shatruk
Summary: The study investigates the properties of materials formed by co-crystallization of complexes containing Fe(ii) ions with TCNQ radical anions, including semiconducting behavior, spin transition, and temperature-induced excited spin-state trapping effect. Furthermore, a series of semiconducting complexes exhibiting LS behavior are obtained by using different ligands to improve the structural stability of these complexes.
Article
Chemistry, Inorganic & Nuclear
Masoume Malmir, Majid M. Heravi, Zahra Yekke-Ghasemi, Masoud Mirzaei
Summary: In this study, a tri-component composite consisting of Fe3O4 nanoparticles, Keggin-type polyoxometalate, and graphene oxide was prepared and investigated as a catalyst for the oxidation of sulfides to sulfoxides. The catalyst showed excellent stability, high yields, and recyclability, making it a promising choice for organic-inorganic hybrid catalytic reactions conducted under mild conditions.
Article
Chemistry, Inorganic & Nuclear
Samuel D. Juarez-Escamilla, Sriloy Dey, Bruno Donnadieu, T. Keith Hollis
Summary: In this study, a bidentate Mo complex was synthesized using metalation and transmetalation methodology. The synthesis was optimized to achieve a high yield. The crystal structure of the bidentate complex was determined. Additionally, alternative forms of ligands were discovered in the reaction.
Article
Chemistry, Inorganic & Nuclear
Mohamed H. Abdel-Rhman, Ghada Samir, Mostafa A. Hussien, Nasser M. Hosny
Summary: This study investigated the dissolution performance of hydrazine carbonate solution on zirconium dibutyl phosphate (Zr-DBP), and found that hydrazine carbonate solution could promote the dissolution of Zr-DBP. The effects of dissolution temperature and hydrogen peroxide concentration on the dissolution efficiency were also explored, and the corrosion effect on stainless steel by hydrazine carbonate solution was studied.
Article
Chemistry, Inorganic & Nuclear
Qiaofang Fu, Fangyu Tan, Wu Ying
Summary: This study successfully prepared vermiculite/g-C3N4/TiO2 composites and found that under specific conditions, the composites exhibited excellent degradation effects, with a high degradation rate for methylene blue. Additionally, the composites were able to enhance surface area, reduce carrier loading rate, improve light energy utilization, and enhance durability.
Article
Chemistry, Inorganic & Nuclear
Annabelle G. W. Hodson, Robert T. Mason
Summary: Functionalised polystyrene resins have been found to be efficient catalysts in the synthesis of specific complexes, with the conversion rate controlled by the polymer structure. The addition of amines or amino acids can further yield substituted 13-butadienyl complexes, which have been analyzed by NMR.
Article
Chemistry, Inorganic & Nuclear
C. Kavitha, S. Anbarasan, P. Subramaniam
Summary: The sulfoxidation of PMAAs by the oxo(salen)chromium(V) complex in aqueous acetonitrile medium was studied. The rate of the reaction is influenced by the polarity of the medium and the substituents on PMAA, with electron donating substituents accelerating the reaction and electron withdrawing substituents retarding the reaction.
Article
Chemistry, Inorganic & Nuclear
Qiang-Qiang Liu, Mithun Kumar Ghosh, Shu-Lan Cai, Xiao-Hong Liu, Lu Lu, Mohd. Muddassir, Tanmay Kumar Ghorai, Jun Wang
Summary: Three newly developed coordination polymers (CPs) with semiconducting properties were synthesized using hydrothermal methods. These CPs exhibit superior photocatalytic activity and can degrade organic pollutants effectively.
Article
Chemistry, Inorganic & Nuclear
Mehrnaz Aliahmadi, Ali Nemati Kharat, Jan Janczak
Summary: This study proposes a method for synthesizing allyl alcohol using cost-effective and renewable bio-resource glycerol. By utilizing catalysts, alcohol as a solvent, and a reducing agent, allyl alcohol with an efficiency of 100% was obtained. The structures of the newly synthesized complexes were determined using X-ray single crystallography.
Article
Chemistry, Inorganic & Nuclear
Ji-Yan Gao, Nan Zhang, Dong-Sheng Huang, Xiang-Rong Liu, Zai-Wen Yang, Shun-Sheng Zhao
Summary: Two new transition metal complexes I and II were synthesized and characterized. The complexes exhibited strong thermal stabilities and showed effective binding to CT-DNA and BSA. Complex II exhibited stronger inhibition activity against P. aeruginosa than gentamicin sulfate. These complexes have potential applications in drug research.
Article
Chemistry, Inorganic & Nuclear
Rishabh Ujjval, Hilal Ahmad Khan, Chinnappan Sivasankar, Natesan Thirupathi
Summary: In this study, a rigid 2-aminobenzimidazole type guanidine and its platinum complexes were synthesized through a series of reactions and characterized by various physical and chemical methods. The reaction mechanism was also explained through DFT calculations.
Article
Chemistry, Inorganic & Nuclear
Marcelo Carpes Nunes, Thais Zaboenco, Vinicius Kemper Melara, Gabriel Barros Baptistella, Andre Luiz Barboza Formiga, Andersson Barison, Fabio Souza Nunes
Summary: A new luminescent molecular thermometer has been developed, which uses the spin-crossover equilibrium of a nickelcyclen derivative to measure temperature. The sensor shows high sensitivity and accuracy.
Article
Chemistry, Inorganic & Nuclear
Yuyu Shan, Zhenqin Zhao, Xia Zhang, Zhan Wu, Xiu-Ling Li
Summary: In this study, a new bridging ligand was synthesized through refluxing, and two mononuclear Cu(I) complexes and two trinuclear Cu(I)-Eu(III) complexes were obtained through self-assembly. The Cu(I) antenna chromophores successfully transferred energy to the Eu(III) centers, achieving sensitized Eu(III) luminescence.
Article
Chemistry, Inorganic & Nuclear
Gabriela Sanchez-Lecuona, Mayra C. Vazquez-Nunez, Bruno Donnadieu, Miguel A. Munoz-Hernandez, Virginia Montiel-Palma
Summary: The reaction of RuHCl(PPh3)3 with GaMe3 has been studied and the obtained complexes were analyzed in detail. The results indicate the formation of a Ru-Ga bond, suggesting the generation of an in situ formed ambiphilic phosphinogallyl ligand. This is of significance for understanding the interaction between metal-halogen bonds and metal-small molecule bonds.
Article
Chemistry, Inorganic & Nuclear
Sevil Sener, Nursel Acar, Fatih Dumludag
Summary: The synthesis, characterization, spectroscopic and bonding features of a new Co (II) phthalocyanine compound containing two thiocarbohydrazone groups were explained. The compound showed semiconductor properties and potential as a temperature sensor.
Article
Chemistry, Inorganic & Nuclear
Ledja B. O. Davi, Aryanna S. P. N. Costa, Mariana S. Silva, Adriana S. Ribeiro, Cintya D. A. E. S. Barbosa, Julio C. S. Da Silva, Dimas J. P. Lima, Daniela S. Anunciacao
Summary: In this study, a dansyl derivative sensor called o-PDDS was prepared and used for the detection of Al3+ ions in water. The o-PDDS sensor exhibited high sensitivity and linear response towards Al3+ ions. Experimental and computational studies confirmed a 1:1 stoichiometry ratio between o-PDDS and Al3+ ions. Real sample analysis demonstrated the selectivity and detection performance of the sensor, indicating its potential for field use.
