4.5 Article

Influence of reaction time on the structural, optical and electrical performance of copper antimony sulfide nanoparticles using solvothermal method

Journal

PHYSICA B-CONDENSED MATTER
Volume 537, Issue -, Pages 243-250

Publisher

ELSEVIER
DOI: 10.1016/j.physb.2018.02.030

Keywords

Chalcogenides; Nanostructured materials; Solvothermal; Structural properties; Optical properties; Electrical properties

Funding

  1. University Grants Commission of India [F1-17.1/2016-17/MANF-2015-17-KER-53161]
  2. Department of Electronics and Information Technology (Deity), Govt. of India

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The less toxic and cost effective ternary Cu-Sb-S nanoparticles and thin films were synthesized and deposited using solvothermal and drop casting method. The reactions were carried out at different timings as 12-48 h, in steps of 12 h using ethylene glycol as solvent and polyvinylpyrrolidone (PVP) as surfactant. Systematic analysis revealed that due to the influence of different reaction time, significant and unique changes were occurring on the crystal structure, optical and electrical properties of the material. The synthesized nanopowders and deposited films were characterized by means of X-ray diffraction, Raman analysis, field emission scanning electron microscope with energy dispersive spectrometer, UV-Vis-NIR diffuse reflectance spectroscopy and hall measurement. XRD results showed that as the time increases crystallinity improves and phase transformation from chalcostibite to tetrahedrite occurs. The Optical performance revealed that the bandgap of nanoparticles were in the range of 1.21-1.49 eV. Hall measurements showed that the deposited Cu12Sb4S13 and CuSbS2 films exhibited p-type conductivity with carrier concentration ranging from 10(16)-10(19) cm(-3), indicating a promising p-type absorber material for photovoltaic applications.

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