Article
Chemistry, Physical
Menghe Jiang, Ying Wang, Cuili Xiang, Yongjin Zou, Fen Xu, Lixian Sun, Dan Cai, Chua Yong Shen
Summary: In this study, MnxCoyO4 @MoS2 composites were obtained by coating flake MoS2 arrays on spherical MnxCoyO4 via hydrothermal and heat treatment methods. The MnxCoyO4 @MoS2 electrode material exhibited a specific capacitance of 1422 F g-1 at 1 A g-1 when x/y = 1:2, higher than that at x/y = 1:1 and 2:1. When assembled into an aqueous asymmetric supercapacitor, the proposed electrode material provided a specific capacitance of 131 F g-1 at 1 A g-1. After 5000 cycles, the electrode material showed a capacity retention of 85% and the device retained a specific power of 794 W kg-1 with 46.58 Wh kg-1. This electrode material design offers new ideas for the development of advanced electrodes.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Ying Xiao, Ge Ye, Mingjiang Xie, Yan Zhang, Jian Chen, Cheng Du, Liu Wan
Summary: A novel strategy is proposed to improve the energy density and cycling stability of transition metal metaphosphates (TMPOs) for supercapacitors. A core-shell heterostructure of cobalt nickel metaphosphate (Co0.2Ni0.8(PO3)2)@nickel diselenide (NiSe2) is constructed on carbon paper as a flexible electrode. The electrode exhibits a specific capacity of 219.4 mAh/g/0.414 mAh cm-2 at 1 A/g and good cycling stability with capacity retention of 90.7% after 5000 cycles, surpassing previously reported TMPO-based electrodes. An asymmetric supercapacitor (ASC) device assembled with this electrode achieves an energy density of 69.2 Wh kg-1 at 736.0 W kg-1 and maintains a capacity retention of 97.6% after 20,000 charge-discharge cycles.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Fangya Qi, Xiaoyi Lu, Yiqian Wang, Hongbo Zhang, Alex Trukhanov, Zhipeng Sun
Summary: The integrated electrode materials with core-shell structure show great potential in energy storage applications, offering excellent electrochemical performance and cycling stability.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Inorganic & Nuclear
Ye Tian, Zhigao Xue, Qingqing Zhao, Jie Guo, Kai Tao, Lei Han
Summary: In this study, hierarchical core-shell hollow Co3S4@NiCo2O4 nanosheet arrays were constructed on reduced graphene oxide/nickel foam (rGO/NF) through a metal-organic framework (MOF)-engaged strategy, which exhibited significantly improved specific capacitance, rate capability, and cycling durability compared with Co3S4/rGO/NF. Moreover, it was successfully applied in an asymmetric supercapacitor (ASC) with excellent energy density, cycling stability, and coulombic efficiency.
DALTON TRANSACTIONS
(2022)
Article
Energy & Fuels
Xiaobo Chen, Wei Wang, Xin Pan, Chengqun Qiu
Summary: The hierarchical core-shell nanowire arrays of MnCo2O4@CuCo2O4/CC composite material exhibit excellent performance at 1 A g(-1) and can be used for the preparation of flexible all-solid-state asymmetric supercapacitors, showing good cycling stability and flexibility.
JOURNAL OF ENERGY STORAGE
(2021)
Article
Chemistry, Physical
Beirong Ye, Shuhao Xiao, Xianjun Cao, Junsong Chen, Aijun Zhou, Qiang Zhao, Wen Huang, Jinshu Wang
Summary: Interface engineering of core/shell structured NiTe@NiCoSe2 composite for supercapacitors enhances energy storage capability, with high-efficient synergistic effects among multicomponents and excellent stability with 96.6% capacitance retention after 10000 cycles.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Physical
Kai Zhang, Hong-Yan Zeng, Ming-Xin Wang, Hao-Bo Li, Wei Yan, Huan-Bin Wang, Zhen-Hua Tang
Summary: In this study, a 3D heterogeneous hierarchical core-shell NiCoMoS@NiCoAl hydrotalcite electrode material was prepared. It was found that coating NiCoAl-LDH on the NiCoMoS nanoneedles can improve interfacial charge transport and offer more active sites, leading to higher specific charge and better charge storage capacity. Furthermore, an asymmetric supercapacitor assembled with NiCoMoS2/1@LDH as the cathode and active carbon as the anode exhibited high energy density and excellent cycling performance.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Energy & Fuels
Shuai Wang, Cunhai Hu, Jiaheng Wang, Mingzhen Xie, Songyuan Wu, Linheng Zhao, Jiaxu Gong, Yatang Dai
Summary: Reasonable structural design is widely used to improve the performance of electrode materials. In this study, a coreshell structure with a unique appearance was designed, which showed high cycle stability and excellent capacity. DFT calculations revealed that the electronic structure at the heterogenous interface changed after compounding, leading to enhanced electron transfer and reaction rate.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Energy & Fuels
Xinrong Lv, Li Feng, Xiaoyun Lin, Yongnian Ni
Summary: A novel 3D MnNi2O4@MnNi2S4 core-shell nano array was grown on nickel foam via an in-situ growth method. The material exhibited a unique core-shell structure and provided abundant active sites for rapid electrochemical reactions, resulting in high specific capacitance and excellent electrochemical properties.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Chemistry, Physical
Lulu Gao, Yi Wang, Yuqing Liu, Lan Xu
Summary: In this study, core-shell supercapacitor electrodes with high performance were prepared using electrospinning, carbonation, nitrogen-doping, and chemical polymerization. The optimized parameters for the morphologies, structures, and electrochemical performance of the products were obtained by characterizing the effects of pore-forming agent content, N-doped amount, and polymerization temperature. The core-shell composite exhibited a high specific capacitance of 342.13 F g-1 at 1 A g-1, with only 4.6% attenuation after 1000 cycles, indicating excellent charge storage performance and cycle stability. Furthermore, a symmetrical supercapacitor fabricated with the best electrode demonstrated an energy density of 3.10 Wh kg-1 at a power density of 50 W kg-1, highlighting the potential of this method for developing multifunctional electrode materials for supercapacitors.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Energy & Fuels
Xinrong Lv, Lu Chen, Xiaoqin Min, Xiaoyun Lin, Yongnian Ni
Summary: A novel flower-like MnNi2O4-MnNi2S4 core@shell composite electrode with outstanding electrochemical performance has been successfully synthesized. The electrode exhibits high specific capacity and energy density, as well as good cycling performance. The core@shell structure of the electrode is expected to have significant potential for practical applications.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Chemistry, Physical
Zhiqiang Liu, Aihua Li, Yanling Qiu, Qingyu Zhao, Yuxue Zhong, Liang Cui, Wenrong Yang, Joselito M. Razal, Colin J. Barrow, Jingquan Liu
Summary: In this work, MgCo2O4@NiMn layered double hydroxide core-shell structured nanocomposites on Ni foam are synthesized and exhibit excellent electrochemical performance and potential applications in energy storage devices.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Nanoscience & Nanotechnology
Fangya Qi, Han Li, Fan Yang, Zhipeng Sun
Summary: The integrated electrode of core-shell structured NiCo2S4@TiO2 nanorod arrays/carbon cloth shows excellent specific capacitance and cycling stability, making it a promising candidate for electrode materials in energy storage devices. The core-shell structure provides abundant electroactive sites for redox reactions, convenient ion transport paths, and favorable structure stability, resulting in high performance. Additionally, the solid-state asymmetric supercapacitors assembled using this electrode exhibit a high energy density and outstanding cycling stability, showcasing the potential for practical applications.
Article
Biochemistry & Molecular Biology
Peizhi Fan, Jie Wang, Wenfei Ding, Lan Xu
Summary: The combination of multiple electrode materials and their reasonable structural design can lead to the preparation of composite electrodes with excellent performance. This study focuses on the hydrothermal growth of five transition metal sulfides on the surfaces of carbon nanofibers grown with Ni(OH)(2) and NiO (CHO) prepared by electrospinning, hydrothermal growth, and low-temperature carbonization. The CHO/NiS composite electrode exhibits optimal electrochemical properties, with a specific capacitance of up to 1717 F g(-1) (1 A g(-1)). The asymmetric supercapacitor assembled with CHO/NiS-3h as the positive electrode demonstrates the potential application of multistage core-shell composite materials in high-performance supercapacitors.
Article
Chemistry, Inorganic & Nuclear
Xiaobo Chen, Jianghao Cai
Summary: In this study, hierarchical polyaniline-coated ZnCo2O4 nanobelts were synthesized and investigated as a supercapacitor material, showing remarkable specific capacitance and cycling performance. An asymmetric supercapacitor was constructed using the obtained electrode and active carbon, achieving high specific energy and capacitance retention.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Multidisciplinary
Xin Shi, Jin Wang, Fan Yang, Xiaoqing Liu, Yanxia Yu, Xihong Lu
Summary: By using acetone as an electrolyte additive, an electrical double layer (EDL) reconstruction strategy is proposed to solve the dendrite growth and side reactions issues in Zn deposition, improving the depth of discharge. Experimental and theoretical simulation results show that the adsorption priority of acetone creates a water-poor inner Helmholtz layer, while the hydrogen bonding effect between acetone and water weakens the Zn2+ solvation. This rearrangement of ions/molecules in EDL suppresses hydrogen evolution, promotes the Zn2+ diffusion kinetics, and guides homogeneous Zn nucleation and growth.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Electrochemistry
Yi Wang, Yanxia Yu, Xihong Lu
Summary: In this study, low-cost Bi2O2CO3 nanoflakes were prepared using a simple precipitate strategy for rechargeable aqueous alkaline zinc batteries. The as-prepared material exhibited high areal capacity, excellent rate capability, and long cycling life. The energy storage mechanism was found to be predominantly contributed by the reversible conversion reaction between Bi and Bi2O3 in the KOH aqueous electrolyte. This work is of great importance for the construction of advanced materials in alkaline energy-storage devices.
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Tzu-Hao Lu, Chenghui Zeng, Haozhe Zhang, Xin Shi, Yanxia Yu, Xihong Lu
Summary: A oxygen defects-rich manganese oxide (MnO2-x) is reported as a host material for ammonium ions (NH4+) storage, which exhibits improved electric conductivity and low interface activation energy due to the oxygen defects. The electrochemical reaction mechanism is confirmed through ex situ XPS and FT-IR, demonstrating the insertion and extraction of NH4+ in MnO2-x via hydrogen bond formation/breaking. As a result, MnO2-x delivers a high capacity of 109.9 mAh g(-1) at 0.5 A g(-1) current density and retains 24 mAh g(-1) after 1000 cycles at 4 A g(-1) current density, outperforming the pristine MnO2 sample.
Article
Chemistry, Physical
Xin Shi, Hao Liu, Diyu Xu, Yanxia Yu, Xihong Lu
Summary: By using ethylene glycol as an electrolyte additive to modulate the H-bond network, the issue of side reactions in aqueous ammonium-ion batteries has been resolved, resulting in high-performance batteries.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Chemistry, Physical
Jinjun He, Yanxia Yu, Chenghui Zeng, Fan Yang, Haibo Wu, Zujin Yang, Xihong Lu
Summary: In this study, Fe decorated cobalt oxide (CFO) nanosheet arrays with exceptional electrochemical properties were synthesized via a one-step solve-thermal reaction. The introduction of Fe enhanced the adsorption for OH- and improved the electrical conductivity and surface wettability, resulting in high capacity, excellent rate performance and high durability for the CFO material.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Multidisciplinary
Diyu Xu, Jinhao Xie, Lijun Zhou, Fan Yang, Yi Wang, Zujin Yang, Fuxin Wang, Haozhe Zhang, Xihong Lu
Summary: Investigating dendrite-free stripping/plating anodes is crucial for advancing practical applications of aqueous alkaline batteries. This work presents a highly reversible Sn anode by constructing a nondense copper layer as a stannophile and hydrogen evolution inhibitor to adjust the tendency of competing reactions on Sn foil surface. The redox reaction of Sn is significantly boosted, resulting in outstanding cycling stability and a demonstrated Sn//Ni(OH)2 battery device.
Article
Chemistry, Multidisciplinary
Liang Cao, Zichen Len, Xin Xu, Zongquan Chen, Lijun Zhou, Hongbo Geng, Xihong Lu
Summary: Through molecular structure engineering, Fe0.4Ni0.6S solid solution demonstrates ultrafast and long-life potassium storage, with improved electrical conductivity and structure durability. This innovative strategy opens avenues for high-quality metal chalcogenides in future advanced PIBs.
Review
Chemistry, Multidisciplinary
Xianshuo Cao, Minxing Li, Qiyu Liu, Jingjing Zhao, Xihong Lu, Jianwei Wang
Summary: The rapid development of nanomedicine and nanobiotechnology has led to the emergence of sonodynamic therapy (SDT), a noninvasive treatment modality for cancer. Inorganic sonosensitizers, such as noble metal-based, transition metal-based, carbon-based, and silicon-based sonosensitizers, show excellent stability, controllable morphology, and multifunctionality, expanding their application in SDT. This review discusses the possible mechanisms of SDT, summarizes recent advances in inorganic sonosensitizers, and outlines strategies for optimizing therapeutic efficiency.
Article
Electrochemistry
Yachen He, Hongwei Tang, Yifeng Huang, Kaihao Chen, Guangxia Wang, Dezhou Zheng, Wei Xu, Fuxin Wang, Xihong Lu
Summary: Through morphological engineering and valence modulation, we successfully enhanced the zinc ion storage capability of commercial MoO3 powder. The uniform MoO3 with low-valence-state Mo (denoted as MoO3-x) nanoparticles, synthesized by a simple solvothermal method with ethylene glycol as a reductant, exhibited superior performance in electrical conductivity, Zn2+ diffusion rate, and active sites. The Zn//MoO3-x battery achieved a significantly higher capacity of 144 mAh g-1 at 2 A g-1 compared to the Zn//MoO3 battery (only 17 mAh g-1). Additionally, the Zn//MoO3-x battery demonstrated an excellent energy density of 146 Wh kg-1 and good cycling stability with a capacity loss of only 0.07% per cycle over 500 cycles. This work provides an appealing approach to enhance the electrochemical properties of molybdenum-based materials and may lead to the design of advanced cathode materials for AZIBs.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Physical
Defeng Liu, Wei Xu, Dezhou Zheng, Yi Wang, Fuxin Wang, Lijun Zhou, Zanxiang Nie, Xihong Lu
Summary: Doping sulfur into NiCo2O4 (S-NCO) is an effective approach to improve the discharge capacity and cycling durability of alkaline Ni//Zn batteries, due to its higher electric conductivity and faster reaction kinetics. The S-NCO//Zn battery exhibits a higher areal capacity (0.721 mAh cm(-2) at 1 mA cm(-2)), no capacity attenuation after 4000 cycles, and a satisfactory coulombic efficiency of approximately 100%. Moreover, the S-NCO material shows excellent flexibility with stable electrochemical performance under various conditions.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Multidisciplinary
Jinjun He, Xin Shi, Qiyu Liu, Haibo Wu, Yanxia Yu, Xihong Lu, Zujin Yang
Summary: Heterostructured Ni3S2/Ni(OH)2 nanosheets with excellent electrochemical performance were synthesized using a facile chemical etching strategy. Compared to Ni3S2, the heterostructured nanosheet cathode showed improved OH- adsorption and diffusion ability, resulting in increased capacity and rate capability. The assembled battery demonstrated high capacity, excellent rate performance, and cycling stability, with a prominent energy density.
Article
Chemistry, Physical
Qiyu Liu, Haozhe Zhang, Jinhao Xie, Fan Yang, Zujin Yang, Xiaoqing Liu, Haibo Wu, Qi Liu, Xihong Lu
Summary: The coordination environment of antimony (Sb) is regulated by introducing high-affinity chloride ligands, which enables high-kinetic and reversible Sb stripping/plating behavior.
Article
Chemistry, Multidisciplinary
Zifan Wang, Mingjie Wei, Qiyu Liu, Xihong Lu, Jianhua Zhou, Jianwei Wang
Summary: An oxygen defect-modulated zinc oxide sonosensitizer is designed to enhance ultrasound energy absorption and suppress recombination of ultrasound-initiated electrons and holes, thus increasing reactive oxygen species yield. It achieves a high tumor inhibition efficiency of 79.9%, showing potential for sonodynamic cancer therapy.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Changsheng Liu, Yan Zhang, Liang Yang, Caizhuang Wang, Xihong Lu, Shiwei Lin
Summary: Natural gas hydrates have attracted attention as a potential alternative energy source, but there is no consensus on their formation mechanism. This paper proposes a method for promoting the rapid formation of gas hydrates by rupturing methane nanobubbles, creating high temperature and pressure conditions for methane-water mixing. Molecular dynamics simulations confirm the formation of gas hydrates through this method. The rupture of methane nanobubbles induced by shock waves leads to increased molecular motion, resulting in extreme local temperature and pressure, facilitating rapid hydrate formation.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Yachen He, Weiwei Xue, Yifeng Huang, Hongwei Tang, Guangxia Wang, Dezhou Zheng, Wei Xu, Fuxin Wang, Xihong Lu
Summary: Nanosized MoO3-x@PPy materials are synthesized to improve the capacity and cycle life of MoO3 as cathode material for aqueous zinc ion batteries. The MoO3-x@PPy cathode exhibits a high reversible capacity and good cycling life, outperforming the original commercial MoO3 sample. The Zn//MoO3-x@PPy battery achieves higher energy density and power density.