Journal
ORGANIC LETTERS
Volume 20, Issue 15, Pages 4471-4474Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01760
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Funding
- NSFC [21632003, 21572087]
- Key Program of Gansu Province [17ZD2GC011]
- 111 Project from the MOE of P. R. China
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Direct visible-light-mediated aminofluorination of styrenes has been developed with high regioselectivity. Shelf stable N-Ts-protected 1-aminopyridine salt was used as the nitrogen-radical precursor, and the commercially available hydrogen fluoride-pyridine was used as the nucleophilic fluoride source. The synthesis of an analogue of LY503430 was performed to demonstrate the synthetic value of this strategy.
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