Journal
ORGANIC LETTERS
Volume 20, Issue 5, Pages 1426-1429Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00204
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Funding
- National Natural Science Foundation of China [201632003]
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Manganese-catalyzed C-2-H enaminylation of 1-(pyrimidin-2-y1)-1H-indoles with ketenimines is reported. The reaction provided 2-enaminylated indole derivatives in moderate to excellent yields with a broad substrate scope. A migration of the directing group pyrimidinyl occurred during this process. The synthesized 2-enaminyl indoles could be conveniently converted into 5-ary1-7H-benzo[c]carbazol-6-amines.
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