Journal
ORGANIC LETTERS
Volume 20, Issue 8, Pages 2472-2476Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00836
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Funding
- National Science Foundation [CHE-1362964, CHE-1625963]
- National Institutes of Health [G12MD007591]
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Highly stereoselective 2-oxonia-Cope rearrangement reactions between newly designed bisvinylogous aldolation synthons and aldehydes, which can provide epsilon-hydroxy-alpha,beta,gamma,delta-unsaturated esters with excellent enantioselectivities, as well as with unprecedented E- and Z-selectivities without regioselectivity issues, are described.
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